• Title/Summary/Keyword: Chemical Sensors

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A Convergency Study on the Gas Turbine Rotation Axis Temperature Sensor for Power Plants (발전소용 가스터빈 회전축 온도 센서 융합연구)

  • Lee, Jeongl-Ick;Na, Gi-Soo
    • Journal of the Korea Convergence Society
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    • v.10 no.12
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    • pp.293-298
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    • 2019
  • The global market for temperature sensors for power plants is estimated at around 35 billion won, of which South Korea relies on imported products for more than 95 percent. This study is that a temperature measurement device for gas turbine rotators for power plants and can be applied to more than 800 of 100 MW gas turbine generators operating in Korea. This study has improved durability by changing the shape of the measuring part, structure of the connecting part, and material changes, and is a component technology applicable to other measuring devices such as humidity, gas and hydraulic pressure used in precision chemical process and plant export industry. As a result of this study, temperature sensors designed as three types of sensors for measuring the temperature of the gas turbine for power plants met Class 1 temperature accuracy in the range of 0℃ to 300℃, and improved durability significantly compared to similar products.

CO2 Sensing Properties of SnO2-Cr2O3 Composite Nanofibers Via Electrospinning Method (전기방사법으로 합성된 SnO2-Cr2O3 복합나노섬유의 이산화탄소 가스감응 특성)

  • Lee, Jae-Hyoung;Kim, Jae-Hun;Kim, Jin-Young;Kim, Sang Sub
    • Journal of the Korean institute of surface engineering
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    • v.50 no.4
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    • pp.289-295
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    • 2017
  • Detection of $CO_2$ gas in both indoor and outdoor atmospheres is now becoming an important issue because of greenhouse effect and climate crisis. In this study, gas sensors based on $SnO_2-Cr_2O_3$ composite nanofibers were fabricated by the electrospinning method to detect $CO_2$ gas. The gas sensors showed a response to ppm level of $CO_2$ gas from room temperature to $200^{\circ}C$ while the highest response was observed at $150^{\circ}C$. The gas response is enhanced by the catalytic property of $Cr_2O_3$. Selective $CO_2$ detection is obtained through the chemical reaction of $Cr_2O_3$ to chromium carbonate. All the results suggest the $SnO_2-Cr_2O_3$ composite material is promising for the use of $CO_2$ gas sensors.

Evaluation of Thermally Oxidized Soybean Oil Using Carbon Nanotube Sensor (탄소나노튜브를 이용한 대두유의 가열산화 특성평가)

  • Lee, Eun-Ji;Lim, Seung-Yong;Fai, Vincent Lau Chun;Ju, Byeong-Kwon;Oh, Sang-Suk
    • Korean Journal of Food Science and Technology
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    • v.44 no.4
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    • pp.472-477
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    • 2012
  • As people are being exposed to many types of fast food, rancid oil is a factor affecting public health. Monitoring of rancidity in frying oils needs to be done adequately. The chemical methods that are currently used require long periods of time and expertise. The development of a device that quickly and easily measures rancidity would be helpful to manage rancidity in frying oils adequately. Due to the fact that carbon nanotube (CNT) is sensitive to acid value, we used CNT as a sensing material for detecting oil rancidity. Polyethylenimine (PEI) was coated on CNT for stable measurements. Experiments were conducted at $100^{\circ}C$ after samples were cooled from $180^{\circ}C$. The results showed a strong correlation between acid values and resistances using CNT sensors. As the acid value of oils increased, the resistance of CNT sensors increased. Development of sensors using CNT may make it possible to determine the rancidity of frying oils in real-time and on site.

Development of SAW Gas Sensor for Monitoring SOx Gas (SOx 가스감지용 SAW 가스 센서 개발)

  • Lee, Chan-Woo;Roh, Yong-Rae;Chung, Jong-Shik;Baik, Sung-Gi
    • Journal of Sensor Science and Technology
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    • v.5 no.3
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    • pp.41-48
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    • 1996
  • We developed SAW gas sensor for monitoring SOx gas with high sensitivity. It was fabricated as a microsensor for detecting SOx gas by depositing sensing material on SAW device. As a detecting layer material, CdS was selected. Deposition of CdS in the form of thin films was carried out by the ultrasonic spray pyrolysis method using ultrasonic spray nozzle. Thin films with the uniform and large surface area for sensors were deposited. The stable pyrolysis environment provided by uniform and fine droplets formed by spray nozzle made it possible to obtain thin films with excellent quality. The minimum grain size of the CdS thin films was about 50 nm when deposited at $300^{\circ}C$. SAW gas sensors showed reasonable sensitivity and reproducibility. Further studies are required to investigate the interference of other gases to SOx gas detection.

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A Study on the Implementation of SAW ID Reader Platform (SAW ID리더 플랫폼 구현에 관한 연구)

  • Yu, Ho-Jun;Kim, Young-Kil
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.12 no.4
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    • pp.766-771
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    • 2008
  • As the practical range of SAW Device extended into various fields including physical sensor, chemical sensor and ID Tag, the platform for various SAW Devices is required more than ever. While SAW ID or Sensors advanced remarkably, the development of platform which applies to SAW Sensor left much to be desired. Therefore this paper represents the SAW platform in order to use SAW ID such as ID Tag or Sensors more conveniently. The SAW platform consists of a RF module which can recognize SAW ID and a main module which has a hish performance processor in order to process the response signal of SAW ID. The main module which has a high performance processor is designed by GUI environmental type to ensure that users are able to use the platform more easily. In this paper, the SAW platform, which is based on ARM9 core processor, used Windows Embedded CE 6.0 OS which brings friendly interface to users. Also the developers can make less effort to design various applications with sensors.

Study of Humidity Sensing Properties Related to Metal Content of Aerosol Deposited Ceramic/Metal Composite Films (에어로졸 증착한 세라믹/금속 복합막의 금속 함량에 따른 습도 감지 특성 연구)

  • Kim, Ik-Soo;Koo, Sang-Mo;Park, Chulhwan;Shin, Weon Ho;Lee, Dong-Won;Oh, Jong-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.5
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    • pp.314-320
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    • 2021
  • Controlling ambient humid condition through high performance humidity sensors has become important for various fields, including industrial process, food storage, and the preservation of historic remains. Although aerosol deposited humidity sensors using ceramic BaTiO3 (BT) material have been widely studied because of their longtime stability, there remain critical disadvantages, such as low sensitivity, low linearity, and slow response/recovery time in case of the sensors fabricated at room temperature. To achieve superior humidity sensing properties even at room temperature condition, BT-Cu composite films utilizing aerosol deposition (AD) process have been proposed based on the percolation theory. The BT-Cu composite films showed gradually improved sensing properties until the Cu concentration reached 15 wt% in the composite film. However, the excessive Cu (above 30 wt%) containing BT-Cu composite films showed a rapid decrease of the sensing properties. The results of observed surface morphology of the AD fabricated composite films, to figure out the metal filler effect, showed correlation between surface topography as well as size and the amount of open pores according to the metal filler content. Overall, it is very important not only dielectric constant of the humidity sensing films but also microstructures, because they affect either the variation range of capacitance by ambient humidity or adsorption/desorption of ambient humidity onto/from the humidity sensing films.

The fabrication and sensing characteristics of conducting polymer sensors for Measurement of VOCs (Volatile organic compounds) gas (휘발성 유기 화합물 가스 측정을 위한 전도성 고분자 센서의 제조(製造) 및 감응(感應) 특성(特性))

  • Paik, J.H.;Hwang, H.R.;Roh, J.G.;Huh, J.S.;Lee, D.D.;Lim, J.O.;Byun, H.G.
    • Journal of Sensor Science and Technology
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    • v.10 no.2
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    • pp.125-133
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    • 2001
  • Conducting polymer sensors show high sensitivity when exposed to volatile organic compounds gases at room temperature. The 8 sensor array using by polypyrrole and polyaniline has been fabricated by chemical polymerization for measuring sensing characteristics of VOCs gases. Conducting polymer was polymerized by using distilled pyrrole, aniline as a monomer and ammonium persulfate (APS) as an oxidant and dodecylbenzene sulfonic acid (DBSA) as a dopant. Dedoped film was synthesized by reverse voltage and redoped film was synthesized by using 1-octanesulfonic acid sodium salt as another dopant in electrochemical cell. The sensitivity and reversibility were influenced by doping, dedoping, redoping and thickness for the polypyrrole and polyaniline. We investigated the relation between the structure of conducting polymer and sensitivity of these sensors through the analysis of scanning electron microscope (SEM), scanning probe microscope (SPM) and $\alpha$-step.

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Coating gold nanoparticles to a glass substrate by spin-coat method as a surface-enhanced raman spectroscopy (SERS) plasmonic sensor to detect molecular vibrations of bisphenol-a (BPA)

  • Eskandari, Vahid;Hadi, Amin;Sahbafar, Hossein
    • Advances in nano research
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    • v.13 no.5
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    • pp.417-426
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    • 2022
  • Bisphenol A (BPA) is one of the chemicals used in monomer epoxy resins and polycarbonate plastics. The surface-enhanced Raman spectroscopy (SERS) method is precise for identifying biological materials and chemicals at considerably low concentrations. In the present article, the substrates coated with gold nanoparticles have been studied to identify BPA and control the diseases caused by this chemical. Gold nanoparticles were made by a simple chemical method and by applying gold salt and trisodium citrate dihydrate reductant and were coated on glass substrates by a spin-coat approach. Finally, using these SERS substrates as plasmonic sensors and Raman spectroscopy, the Raman signal enhancement of molecular vibrations of BPA was investigated. Then, the molecular vibrations of BPA in some consumer goods were identified by applying SERS substrates as plasmonic sensors and Raman spectroscopy. The fabricated gold nanoparticles are spherical and quasi-spherical nanoparticles that confirm the formation of gold nanoparticles by observing the plasmon resonance peak at 517 nm. Active SERS substrates have been coated with nanoparticles, which improve the Raman signal. The enhancement of the Raman signal is due to the resonance of the surface plasmons of the nanoparticles. Active SERS substrates, gold nanoparticles deposited on a glass substrate, were fabricated for the detection of BPA; a detection limit of 10-9 M and a relative standard deviation (RSD) equal to 4.17% were obtained for ten repeated measurements in the concentration of 10-9 M. Hence, the Raman results indicate that the active SERS substrates, gold nanoparticles for the detection of BPA along with the developed methods, show promising results for SERS-based studies and can lead to the development of microsensors. In Raman spectroscopy, SERS active substrate coated with gold nanoparticles are of interest, which is larger than gold particles due to the resonance of the surface plasmons of gold nanoparticles and the scattering of light from gold particles since the Raman signal amplifies the molecular vibrations of BPA. By decreasing the concentration of BPA deposited on the active SERS substrates, the Raman signal is also weakened due to the reduction of molecular vibrations. By increasing the surface roughness of the active SERS substrates, the Raman signal can be enhanced due to increased light scattering from rough centers, which are the same as the larger particles created throughout the deposition by the spin-coat method, and as a result, they enhance the signal by increasing the scattering of light. Then, the molecular vibrations of BPA were identified in some consumer goods by SERS substrates as plasmonic sensors and Raman spectroscopy.

Analysis of the characteristics of polymer multi-layers by using quartz crystals (수정진동자를 이용한 고분자 누적막의 특성분석)

  • Kim, Ki-Young;Kim, Jong-Min;Kwon, Young-Soo;Lee, Burm-Jong;Chang, Yong-Keun;Kim, Jong-Deuk;Chang, Sang-Mok
    • Journal of Sensor Science and Technology
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    • v.3 no.2
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    • pp.3-10
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    • 1994
  • The use of preformed polymers and their cross-linking has been attempted in order to improve the intrinsic fragility of monolayers and Langmuir-Blodgett(LB) films. The evaluation of the characteristics of the LB multi-layer by using an AT-cut quartz crystal has been also attempted. This study reveals that the polyether pendants of 2C18VE3 lie at the air-water interface at low surface pressures and are forced down into the subphase when the monolayers are compressed. This characteristic behavoir of the pendant polyethers is very clear on aqueous poly allyl amine(PAA) and is also observeable on saturated aqueous NaCl and $CaCl_{2}$. And the characteristics of LB multi-layers could be evaluated by using AT-cut quartz crystal in situ.

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Electroanalytical Applications Based on Carbon Nanotube/Prussian Blue Screen-printable Composite

  • Shim, Jun-Ho;Lee, Jae-Seon;Cha, Geun-Sig;Nam, Hak-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.6
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    • pp.1583-1588
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    • 2010
  • A single step fabrication process of carbon nanotube/Prussian Blue (CNT/PB) paste electrodes based on screen printing technology has been studied as an amperometric sensor for the determination of hydrogen peroxide and free chlorine. Compared to the classical carbon paste (CP) electrode, the CNT paste electrode greatly enhanced the response in the presence of hydrogen peroxide due to the electrocatalytic activity of the CNT. Based on the CNT/binder paste, PB was also incorporated into a network of CNT paste and characterized. The best electroanalytical properties of PB-mixed sensors to hydrogen peroxide were obtained with PB ratio of 10 wt % composition, which showed fast response time ($t_{90}{\leq}5$ s; 0.2 - 0.3 mM), low detection limit of 1.0 ${\mu}M$, good linear response in the range from $5.0{\times}10^{-5}$ - $1.0{\times}10^{-3}$ mol $L^{-1}$ ($r^2$ = 0.9998), and high sensitivity of -8.21 ${\mu}AmM^{-1}$. In order to confirm the enhanced electrochemical properties of CNT/PB electrode, the sensor was further applied for the determination of chlorine in water, which exhibited a linear response behavior in the range of 50 - 2000 ppb for chlorine with a slope of 1.10 ${\mu}Appm^{-1}$ ($r^2$ = 9971).