• Title/Summary/Keyword: Chemical Sensors

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Porous silicon : a new material for microsensors and microactuators (다공질 실리콘: 새로운 마이크로센서 및 마이크로액추에이터 재료)

  • Min Nam Ki;Chi Woo Lee;Jeong Woo Sik;Kim Dong Il
    • Journal of the Korean Electrochemical Society
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    • v.2 no.1
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    • pp.17-22
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    • 1999
  • Since the use of porous silicon for microsensors and microactuators is in the euly stage of study, only several application devices, such as light-emitting diodes and chemical sensors have so far been demonstrated. In this paper we present an overview of the present status of porous silicon sensors and actuators research with special emphasis on the applications of chemical sensors and optical devices. The capacitive type porous silicon humidity sensors had a nonlinear capacitance-humidity characteristic and a good sensitivity at higher humidity above $40\%RH$. The porous silicon $n^+-p-n^+$ device showed a sharp increase in current when exposed to an ethanol vapor. The $p^+-PSi-n^+$ diode fabricated on porous silicon diaphragm exhibited an optical switching characteristic, opening up its utility as an optical sensor or switch. The photoluminescence (PL) spectrum, taken from porous silicon under 365 nm excitation, had a broad emission, peaked at -610 nm. The electroluminescence(EL) from ITO/PSi/In LED had a broader spectrum with a blue shifted peak at around 535nm than that of the PL.

Fabrication of Methanol Sensors Using Conductive Polypyrrole Nanofibers with a Core-Shell Structure (코아-셀 구조를 가지는 전도성 폴리피롤 나노섬유를 이용한 메탄올 센서 제작)

  • Jun, Tae-Sun;Lee, Sungho;Kim, Yong Shin
    • Journal of Sensor Science and Technology
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    • v.23 no.6
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    • pp.383-387
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    • 2014
  • Electrically conductive polypyrrole-polyvinylpyrrolidone (PPy-PVP) nanofiber mats with a core-shell structure have been successfully fabricated by a two-step process: the formation of FeCl3-containing PVP nanofiber mat by electrospinning, and the vapor-phase polymerization (VPP) of pyrrole monomer on the mat in a sealed chamber at room temperature. Surface morphology and chemical composition of the PPy-PVP mat were characterized by SEM, EDX and FTIR analyses. The as-prepared nonwoven mat was composed of PPy-PVP nanofibers with an average diameter of 300 nm. The sheet conductivity of the nanofiber mat was measured to be approximately 0.01 S/cm by a four-point probe. We have also investigated gas-sensing properties of PPy-PVP nanofiber mat upon exposure to methanol vapor. The PPy-PVP nanofiber sensors were observed to have excellent methanol-sensing performance. The nanofiber-based core-shell nanostructure could give an opportunity to fabricate a highly sensitive and fast response sensor due to its high surfaceto-volume ratio.

Fabrication of Pd/poly 3C-SiC Schottky diode hydrogen sensors (Pd/다결정 3C-SiC 쇼트키 다이오드형 수소센서의 제작)

  • Chung, Dong-Yong;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.236-236
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    • 2009
  • This paper describes the fabrication and characteristics of Schottky micro hydrogen sensors for high temperatures by using polycrystalline(poly) 3C - SiC thin film grown on Si substrates with thermal oxide layer using APCVD. Pd/poiy 3C-SiC Schottky diodes were made and evaluated by I-V and C-V measurements. Electric current density and barrier height voltage were $2\times10^{-3}\;A/cm^2$ and 0.58 eV, respectively. These devices could operate stably at about $400^{\circ}C$. According to $H_2$ concentrations, their barrier height($\Phi_{Bn}$) were changed 0.587 eV, 0.579 eV, 0.572 eV and 0.569 eV, respectively. the current was increased. Characteristics of implemented sensors have been investigated in terms of sensitivity, linearity of response, response rate and response time. Therefore, from these results, Pd/poly 3C-SiC Schottky devices have very high potential for high temperature chemical sensor applications.

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Highly Sensitive Multichannel Interdigitated Capacitor Based Bitterness Sensor

  • Khan, Md. Rajibur Rahaman;Kang, Shin-Won
    • Journal of Sensor Science and Technology
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    • v.27 no.2
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    • pp.69-75
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    • 2018
  • In this study, we propose a multichannel interdigitated capacitor (IDC) sensor for detecting the bitterness of coffee. The operating principle of the device is based on the variation in capacitance of a sensing membrane in contact with a bitter solution. Four solvatochromic dyes, namely, Nile red, Reichardt's dye, auramine-O, and rhodamine-B, were mixed with polyvinylchloride (PVC) and N,N-dimethylacetamide (DMAC), to create four different types of bitter-sensitive solutions. These solutions were then individually inserted into four interdigitated electrodes (IDEs) using a spin coater, to prepare four distinct IDC sensors. The sensors are capable of detecting bitterness-inducing chemical compounds in any solution, at concentrations of approximately $1{\mu}M$ to 1 M. The sensitivity of the IDC bitterness sensor containing the Reichardt's dye sensing-membrane was approximately 1.58 nF/decade. The multichannel sensor has a response time of approximately 6 s, and an approximate recovery time of 5 s. The proposed sensor offers a stable sensing response and linear sensing performance over a wide measurement range, with a correlation coefficient ($R^2$) of approximately 0.972.

Excellent Carbon Monoxide Sensing Performance of Au-Decorated SnO2 Nanofibers

  • Kim, Jae-Hun;Zheng, Yifang;Mirzaei, Ali;Kim, Sang Sub
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.741-750
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    • 2016
  • Nanofibers(NFs), because of their high surface area and nanosized grains, have appropriate morphologies for use in chemiresistive-type sensors for gas detection applications. In this study, a highly sensitive and selective CO gas sensing material based on Au-decorated $SnO_2$ NFs was fabricated by electrospinning. $SnO_2$ NFs were synthesized by electrospinning and subsequently decorated with various amounts of Au nanoparticles(NPs) by sputtering; this was followed by thermal annealing. Different characterizations showed the successful formation of Au-decorated $SnO_2$ NFs. Gas sensing tests were performed on the fabricated sensors, which showed bell-shaped sensing behavior with respect to the amount of Au decoration. The best CO sensing performance, with a response of ~20 for 10 ppm CO, was obtained at an optimized amount of Au (2.6 at.%). The interplay between Au and $SnO_2$ in terms of the electronic and chemical sensitization by Au NPs is responsible for the great improvement in the CO sensing capability of pure $SnO_2$ NFs, suggesting that Au-decorated $SnO_2$ NFs can be a promising material for fabricating highly sensitive and selective chemiresistive-type CO gas sensors.

A Unified Potentiostat for Electrochemical Glucose Sensors

  • Sohn, Ki-Sung;Oh, Seok-Jae;Kim, Eui-Jin;Gim, Jeong-Min;Kim, Nam-Soo;Kim, Yeong-Seuk;Kim, Jong-Won
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.5
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    • pp.273-277
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    • 2013
  • A unified potentiostat circuit for both $O_2$- and $H_2O_2$- based electrochemical glucose sensors was proposed and its function was verified by circuit simulations and measurement results of a fabricated chip. This circuit consisted of an operational amplifier, a comparator and current mirrors. The proposed circuit was fabricated with a $0.13{\mu}m$ thick oxide CMOS process and an active area of $360{\mu}m{\times}100{\mu}m$. The measurements revealed an input operation range from 0.5 V to 1.6 V in the $H_2O_2$- based bio-sensor and from 1.7 V to 2.6 V in the $O_2$- based bio-sensor with a supply voltage of 3.3 V. The evaluation results showed that the proposed potentiostat circuit is suitable for measuring the electrochemical cell currents of both $O_2$- and $H_2O_2$- based glucose sensors.

Trend of Toxic Nanomaterial Detecting Sensors (독성 나노물질 검출 센서 동향)

  • Jang, Kuewhan;Na, Sungsoo
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.24 no.12
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    • pp.977-984
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    • 2014
  • Nanomaterial have grown from scientific interest to commercial products and the nanomaterial market has grown 19.1 % each year. As the nanomaterial market size increases, it is expected that nanomaterial production will increase and its contamination of outdoor environmental system will also increase in the form of industrial waste. Since most of nanomaterials are known as biologically non-degradable materials, nanomaterials will accumulate in the environment, and this will increase the potential threats to human health along the food chain. Recent studies have investigated the toxicity effect of nanomaterials due to their size, chemical composition and shape. For the development of nanomaterial while taking human health into consideration, a nanomaterial detecting sensor is required. In this paper, we have observed the trend of nanomaterial detecting sensor of mechanical, electrochemical, optical and kelvin probe force microscopy sensors and we believe that this trend will shed the light on the development of real-life nanomaterial detecting sensors.

Surface acoustic wave gas sensors by utilizing the phase change (위상변화를 이용한 표면탄성파 가스센서)

  • Kim, Jin-Sang;Jung, Yong-Chul;Kang, Chong-Yun;Kim, Dal-Young;Nam, Chang-Woo;Yoon, Seok-Jin
    • Journal of Sensor Science and Technology
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    • v.14 no.3
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    • pp.186-190
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    • 2005
  • This paper describes the development of a surface acoustic wave gas sensor that is designed to detect volatile gas by monitering phase change of output signal as a function of time. The sensor consists of SAW oscillators with a center frequency of 100 MHz fabricated on $128^{\circ}$ Y-Z $LiNbO_{3}$ substrates. Experimental results, which show the phase change of output signal under the absorption of volatile gas onto sensors, are presented. The proposed sensor has the properties of high sensitivity compare to the conventional SAW gas sensor and chemical selectivity. Thus, it is thought these results are applicable for use in sensor array of an high performance electronic nose system.

Implementation of a Portable Electronic Nose System for Field Screening (필드 스크린을 위한 휴대용 전자코 시스템의 구현)

  • Byun, Hyung-Gi;Lee, Jun-Sub;Kim, Jeong-Do
    • Journal of Sensor Science and Technology
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    • v.13 no.1
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    • pp.41-46
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    • 2004
  • There is currently much interest in the development of instruments that emulate the senses of humans. Increasingly, there is demand for mimicking the human sense of smell, which is a sophisticated chemosensory system. An electronic nose system is applicable to a large area of industries including environmental monitoring. We have designed a protable electronic nose system using an array of commercial chemical gas sensors for recognizing and analyzing the various odours. In this paper, we have implemented a portable electronic nose system using an array of gas sensors for recognizing and analyzing VOCs (Volatile Organic Compounds) in the field. The accuracy of a portable electronic nose system may be lower than an instrument such as GC/MS (Gas Chromatography/Mass Spectrometer). However, a portable electronic nose system could be used on the field and showed fast response to pollutants in the field. Several different algorithms for odours recognition were used such as BP (Back-Propagation) or LM-BP (Levenberq-Marquardt Back-Propagation). We applied RBF (Radial Basis Function) Network for recognition and quantifying of odours, which has simpler and faster compared to the previously used algorithms such as BP and LM-BP.

Effects of Pd Nanoparticles on Single-Walled Carbon Nanotubes as High-Sensitivity Hydrogen Gas Sensors (덴드리머와 팔라듐 나노입자를 이용한 단일벽 탄소나노튜브 고성능수소센서)

  • Lee, Jun Min;Ju, Seonghwa;Joe, Jin Hyoun;Kim, Sung-Jin;Lee, Wooyoung
    • Korean Journal of Metals and Materials
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    • v.48 no.4
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    • pp.342-346
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    • 2010
  • Pd nanoparticles (NPs) were successfully functionalizedon the surfaces of single-walled carbon nanotubes (SWNTs) by dendrimer-mediated synthesis. The hydrogen sensing properties of the Pd NPs functionalized SWNTs were investigated. Pd NPs-dendrimer-SWNTs sensors show much better speedsand superior recovery rates but lower sensitivity compared to Pd NPs-functionalized SWNTs directly fabricated due to the existence of dendrimers. Pyrolysis of the dendrimers by heat treatment resulted in a fast response time and high sensitivity owing to the reduced length of the dendrimers. These results demonstrate that the heat treatment of dendrimers in Pd NPs-dendrimer-SWNTs sensors can enable significant electrical conductance modulation upon exposure to extremely low concentrations (10 ppm) of hydrogen gas ($H_2$) in air.