• Title/Summary/Keyword: Chemical Ratio

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Spectroscopic and Morphological Investigation of Copper Oxide Thin Films Prepared by Magnetron Sputtering at Various Oxygen Ratios

  • Park, Ju-Yun;Lim, Kyoung-A;Ramsier, Rex D.;Kang, Yong-Cheol
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3395-3399
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    • 2011
  • Copper oxide thin films were synthesized by reactive radio frequency magnetron sputtering at different oxygen gas ratios. The chemical and physical properties of the thin films were investigated by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray diffraction (XRD). XPS results revealed that the dominant oxidation states of Cu were $Cu^0$ and $Cu^+$ at 0% oxygen ratio. When the oxygen ratios increased above 5%, Cu was oxidized as CuO as detected by X-ray induced Auger electron spectroscopy and the $Cu(OH)_2$ phase was confirmed independent of the oxygen ratio. The valence band maxima were $1.19{\pm}0.09$ eV and an increase in the density of states was confirmed after formation of CuO. The thickness and roughness of copper oxide thin films decreased with increasing oxygen ratio. The crystallinity of the copper oxide films changed from cubic Cu through cubic $Cu_2O$ to monoclinic CuO with mean crystallite sizes of 8.8 nm (Cu) and 16.9 nm (CuO) at the 10% oxygen ratio level.

Surface Morphology Control of Monodisperse Crosslinked-Polymer Particle (단분산 가교고분자 미립자의 표면 모폴로지 제어 연구)

  • Kim, Dong-Ok;Jin, Jeong-Hee;Oh, Seok-Heon
    • Polymer(Korea)
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    • v.30 no.1
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    • pp.50-55
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    • 2006
  • When the monodisperse polystyrene(PS)/HDDA polymer particles were synthesized via one-step polymerization using polystyrene seed particles by dispersion polymerization, the effects of 1) the molecular weight of seed polymer particles, 2) the ratio of the absorbed HDDA to the seed polymer particles (swelling ratio) and 3) seeded polymerization rate on the surface morphology of PS/HDDA polymer particles were investigated. It was observed that the creation of the crater shaped defect on the surface of PS/HDDA polymer particles was irrespective of the molecular weight of seed polymer ant swelling ratio. But its surface morphology could be controlled by the change of the seeded polymerization rate.

Identification of the Sources of Nitrate using Stable Isotope Mass Ratio in Rural Watersheds (안정 동위원소비를 이용한 농촌하천유역 질산성 질소의 오염원 추정)

  • 홍영진;권순국;홍성구
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.43 no.4
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    • pp.120-128
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    • 2001
  • Pollution sources and their environmental contributions were investigated to select the best management practices for the effective control of water quality. The nitrogen isotope mass ratio was determined to estimate the nitrate sources and their contribution. Sampling sites were chosen by calculating effluent loads at each watershed. Two liters each of the surface water samples were collected from four sites at Bokha river and two sites and Gwanri river. They were sequentially prepared through distillation method and analyzed using an isotope ratio mass spectrometer(IsoPrime EA). As revealed by the experimental values obtained the mass ratio values ($\delta$$^{5}$ N) of watersheds with a large amount of nonpoint sources were less than +5 an indication that the samples were influenced by chemical fertilizers. However watersheds with large amount of point sources were influenced not only by chemical fertilizers but also by animal and municipal wastes. The mass ratio values of samples generally decreased during rainy days. But during dry days the mass ratio values well-reflected the nitrate sources and the condition of watersheds. Through this study the nitrogen isotope mass ratio has been found to be useful for estimating nitrate sources and their contribution to the rural watersheds.

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Assesment of Weather ability of Polyester/Polypropylene Geotextile Composites (폴리에스테르/폴리프로필렌 복합형 지오텍스타일의 내후성 평가)

  • 전한용
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.11c
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    • pp.39-55
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    • 1999
  • Geotextile composites to improve the weather ability were composed of recycled polyester geotextile with carbon black as ultraviolet stabilizer and polypropylene geotextile by needle-punching method, and evaluated physical properties, ultraviolet resistance and chemical stability. Retention ratio of tensile properties of non woven polypropylene geotextiles were decreased about 50% by the exposed condition with ultraviolet but those of geotextile composites were slightly decreased than polypropylene geotextiles. Geotextile composites which have larger weights of polyester geotextile were more stable against ultraviolet. For chemical stability, the changes of tensile properties of geotextile composites were in the range of -20~+10% at the various chemical conditions.

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Antibiotic Activity of PVA Blending Films Using Chitosan (키토산을 이용한 PVA 블랜드 필름의 항균특성)

  • Kim, Kyung-Min;Kong, Seung-Dae;Yoon, Cheol-Hun;Kim, Yong-Yeul;Lee, Han-Seob
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.3
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    • pp.198-202
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    • 2000
  • PVA blend films were prepared by solution blending method for the purpose of useful antibiotic polymers. Characteristics properties of blending films such as elongation and tensile strength were determined. Tensile strength and elongation were rapidly reduced as increasing the blending ratio of natural polymer. Blend films were found that phase separation was occured as more than 25wt% increasing the blend ratio of chitosan. Also, The antibiotics of blend films were examined against gram(+) and gram(-) by disk susceptibility test. As a result, kind of blending films to show the highest antibiotics was chitosan 20wt% and the selectivity of mold strain was observed.

Analysis of Damaged Instance and Forming Fault for Disc Part in Automotive Steel Wheel (자동차용 스틸휠 디스크부품의 성형불량 및 파손사례분석)

  • Lee, Sung-Hee;Kim, M.Y.;Kim, T.G.;Yun, H.Y.;Kang, S.W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.234-238
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    • 2006
  • In this research, an analysis of damaged instance and forming fault for disc part in automotive steel wheel was performed. Rolled steel material, which had been used in the manufacturing of the damaged disc part, was prepared for tensile test, quantitative analysis of chemical component and acquirement of scanning electron microscope images. Although the results of mechanical properties and chemical component ratio for the material satisfied the suggested specification, some material inherent problem was found in the scanning electron microscope images. Finally, in an analysis of chemical component for the damaged disc part used in road condition, mismatching of chemical component ratio between the suggested specification and test result was found.

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Visualization of the Slurry Flow-Field during Chemical Mechanical Polishing by PIV (PIV를 이용한 Chemical Mechanical Polishing 공정 중의 연마용액 유동흐름 측정)

  • Shin Sanghee;Kim MunKi;Yoon Youngbin;Koh Young-Ho
    • 한국가시화정보학회:학술대회논문집
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    • 2004.11a
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    • pp.48-51
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    • 2004
  • Chemical Mechanical Polishing(CMP) is popularly used in production of semiconductor because of large area polishing ability probability of improvement for more integrated circuit. However, present CMP processing causes some non-uniformity errors which can be critical for highly integrated circuit. Previous studies predict that flow-field of slurry during CMP can create non-uniformity, but no quantitative measurement has conducted. In this study, using PIV, slurry velocity flow-field during CMP is measured by changing the ratio of RPM of pad and carrier with tuned PIV system adequate for small room in CMP machine and Cabot's non-groove pad Epad-A100. The result show that velocity of slurry is majorly determined by pad-rpm and the ratio of between carrier and pad rpm make some changes in streamlines.

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Optimization of Extraction of Astaxanthin from Portunus trituberculatus by Ionic Liquids (이온성 액체를 사용한 꽃게 껍질에서 아스타크산틴 추출 조건의 최적화)

  • Lee, Yu Jin;Lee, Yu Ri;Tang, Baokun;Row, Kyung Ho
    • KSBB Journal
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    • v.28 no.4
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    • pp.238-243
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    • 2013
  • Astaxanthin is one of the carotenoid with strong antioxidant. The conditions of extraction of astaxanthin from Portunus trituberculatus were optimized in this work. Six factors of conditions such as, extraction method, extraction solvent, ratio of solvent to raw material, temperature, and time, were investigated. For the increase of the extraction yield, ionic liquids were used as additives in the extraction solvent. The optimum extraction conditions were found: heat reflux extraction, Dichloromethane/methanol (25:75, v/v) as solvent, 1:30 of the ratio of solvent raw material, $80^{\circ}C$, 90 min, and ionic liquid as additive. As a result, 45.81 ${\mu}g/g$ of astaxanthin was extracted from waste.

Chemical Modification of Wood with Alkylene Oxides, Vinylpirrolidinone and Furans:Effects on Dimensional Stabilization

  • Guevara, R.;Moslemi, A.A.
    • Journal of the Korean Wood Science and Technology
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    • v.10 no.4
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    • pp.38-52
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    • 1982
  • The effect of propylene oxide, butylene oxide, furan resin, and vinylpyrrolidinone in controlling wood dimensional stability have been examined. Wood in the green or ovendry condition was treated with various chemical treatments using a vacuum-pressure procedure, and treated specimens were tested for tangential sweelling, moisture gain, and changes in sorption hysteresis. Results' indicate that propylene oxide, and butylene oxide enhanced with the crosslin king agent trimethylol propane trimethacrylate and applied to ovendry wood were the most efficient chemical treatments in controlling tangential sweeling caused by liquid water or water vapor, and in reducing water vapor adsorption. The sorption behavior of treated wood as depicted by the ratios of sorption was "very favorable" in most instances. In the particular case of furan resin treatments, ratios of sorption were improved from 25 to 100 percent as compared to those of untreated wood.

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Feasibility Analysis of Korea TURA Reflecting Fuzzy Weights (Fuzzy 가중치를 반영한 배출 저감 규제의 타당성 분석)

  • Yoon, Daniel Jongsoo;Byun, Hun-Soo
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.186-190
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    • 2021
  • The toxics regulatory body provides a benefit/cost ratio as a justification criterion while implementing regulations that induce the industry to reduce emissions voluntarily. Furthermore, since, the body wants to reflect not only the efficiency standard but also the policy standard in the evaluation of feasibility, it calculates the ratio by adjusting the importance weights. The problem is that respondents answer ambiguously. It should be removed for the reasonable evaluation. This study introduced a fuzzy-AHP methodology for this, and applied it to the voluntary emission reduction plan program in Korea.