• Title/Summary/Keyword: Chemical Mixing

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Liquefaction Characteristics of Polyethylene-polystyrene Mixture by Pyrolysis at Low Temperature (Polyethylene-polystyrene 혼합물의 저온 열분해에 의한 액화특성)

  • Lee, Bong-Hee;Kim, Su-Ho;Choi, Hong-Jun
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.4
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    • pp.495-502
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    • 2008
  • To investigate the synergy effect on the pyrolysis of mixture of polyethylene(PE) and polystyrene(PS), the pyrolysis of PE, PS and the mixture of PE-PS was carried out in a batch reactor at the atmospheric pressure and $450^{\circ}C$. The pyrolysis time was from 20 to 80 mins. The liquid products formed during pyrolysis were classified into gas, gasoline, kerosene, gas oil and heavy oil according to the distillation temperatures based on the petroleum product quality standard of Korea Institute of Petroleum Quality. The analysis of the product oils by GC/MS showed that the new components produced by mixing were not detected. The synergy effect according to mixing of PE and PS did not also appear. The conversion and yield of mixtures were in proportion to the mixing ratio of sample.

Chemical Solution Mixing and Hydrogen Reduction Method for Fabrication of Nanostructured Fe-Co Alloy Powders (화학용액 혼합과 수소환원법을 이용한 나노구조 Fe-Co 합금분말의 제조)

  • 박광현;박현우;이백희;장시영;이정근;김영도
    • Journal of Powder Materials
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    • v.11 no.2
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    • pp.137-142
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    • 2004
  • In this study, chemical solution mixing and hydrogen reduction method was used to fabricate nanostructured $Fe_xCo_{1-x}$ alloy powders. Fe-Co chloride mixture, FeCl$_2$ and COCI$_2$ with 99.9% purity, were reduced in hydrogen atmosphere. Nanostructured Fe-Co alloy powders with a grain size of 50 nm were successfully fabricated. Magnetic properties of fabricated $Fe_xCo_{1-x}$(x=0, 10, 30, 50, 70, 100) alloy powders with the same grain size were measured because size factor can affect magnetic properties. Coercivity of Fe-Co alloy powders were increased with increasing Co contents. Maximum value of coercivity in various Co contented Fe-Co alloy powders with similar grain size was 125 Oe at Fe$_{100}$. Saturation magnetization value at Fe$_{70}$Co$_{30}$ composition showed maximum value of 219 emu/g and saturation magnetization value decreased with increasing Co contents and minimum value of 155 emu/g was observed at Co$_{100}$.

An estimation and radioactivity measurement for radiocarbon(14C) in the Korean nuclear power plants

  • Seo Ra Yang;Jin Hong Lee;Jae Hwan Yang;Geun-Il Park
    • Nuclear Engineering and Technology
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    • v.56 no.8
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    • pp.2906-2915
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    • 2024
  • Radiocarbon (14C), with a radioactive half-life of approximately 5730 years, poses a long-term environmental contamination risk when released into the atmosphere. The quantification analysis of its release estimates plant-specific generation rates based on factors such as plant power, core neutron flux distribution, and the volume of water exposed to this flux. Utilizing the improved estimation method, the 14C production rate for several Korean Pressurized Water Reactors (PWRs) was calculated. Also, improvements in measurement methods through sampling have also been made. These enhancements include the verification of the absorption method versus the mixing method. The results of this study indicate that plant-specific 14C production rates range from 0.213 to 0.317 TBq/yr, which are comparable to the global range observed in PWRs. Furthermore, the study evaluated a quenching correction curve for a liquid scintillation counter using two quenching correction methods: the external standard method and the internal standard method. The accuracy of these methods with 72 samples was validated with an average relative error within ±2.5%. The relative error of the mixing method, when compared to the direct absorption method, was found to be within ±20%. This finding underscores the validity of the improved measurement technique.

Phase Morphology and Foaming of Polypropylene/Ethylene-octene Copolymer Blends (폴리프로필렌/에틸렌옥텐 공중합체 블렌드의 상분리 구조 및 발포 특성)

  • 서관호;임정철
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.707-718
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    • 2001
  • Polypropylene (PP) exhibits many beneficial properties such as low density high thermal stability, chemical resistance, good processability and recyclability. However, only limited research has been done on expanded polypropylene (EPP). In this study, we were trying to prepare EPP with chemical blowing agent. Ethylene-octene copolymer (mPE) was melt blended with PP to enhance melt fluidity of PP at processing temperature and to make more flexible foamed material. Prior to foaming, phase morphology of PP/mPE blends were investigated to examine the effect of phase morphology on the foaming ratio and cell structure of foams. Phase morphology of PP/mPE blends were affected by the content of mPE and mixing torque ratio. At the same composition, it was affected by mixing rpm. High blowing ratio and stable cell structure were obtained in the blend which has the continuous PP matrix with dispersed droplets of mPE.

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Performance of the Negative Carbon Electrode Prepared with Graphitic Carbon and Nongraphitic Carbon Material in Lithium Ion Secondary Battery (흑연계 및 비흑연계 탄소로 조합된 리튬이온 이차전지의 탄소부극 특성)

  • Kim, Hyun-Joong;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.1065-1069
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    • 1998
  • This study was investigated to improve peformance of carbon negative electrode for lithium ion secondary battery. The carbon electrode was prepared by mixing with graphitic carbon material, natural graphite, and nongraphitic carbon material, petroleum cokes, which was heat-treated at $700^{\circ}C$ for l hour. Its electrochemical and charge-discharge characteristics were tested according to mixing ratio of different two types of carbon material. The carbon electrode prepared with various mixing ratio showed both charateristcs of two different types of carbon materials and the best characteristics as carbon electrode was demonstrated at mixing ratio of 1:1.

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Optimized Mixing Design of Carbon-Capturing and Sequestering Activated Blast-Furnace Slag Mortar by Response Surface Analysis (반응표면분석법에 의한 탄소포집 활성 고로슬래그 모르타르의 최적배합 도출에 관한 연구)

  • Jang, Bong Jin;Park, Cheol woo;Kim, Seung Won;Ju, Min Kwan;Park, Ki Tae;Lee, Sang Yoon
    • International Journal of Highway Engineering
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    • v.15 no.6
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    • pp.69-78
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    • 2013
  • PURPOSES : In this study blast furnace slag, an industrial byproduct, was used with an activating chemicals, $Ca(OH)_2$ and $Na_2SiO_3$ for carbon capture and sequestration as well as strength development. METHODS : This paper presents the optimized mixing design of Carbon-Capturing and Sequestering Activated Blast-Furnace Slag Mortar. Design of experiments in order to the optimized mixing design was applied and commercial program (MINITAB) was used. Statistical analysis was used to Box-Behnken (B-B) method in response surface analysis. RESULTS : The influencing factors of experimental are water ratio, Chemical admixture ratio and Curing temperature. In the results of response surface analysis, to obtain goal performance, the optimized mixing design for Carbon-Capturing and Sequestering Activated Blast-Furnace Slag Mortar were water ratio 40%, Chemical admixture ratio 58.78% and Curing temperature of $60^{\circ}C$. CONCLUSIONS : Compared with previous studies of this experiment is to some extent the optimal combination is expected to be reliable.

LES of Turbulent Mixing of Non Reacting Flow in a Gas Generator

  • Lee, Chang-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.391-398
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    • 2008
  • LES analysis was conducted with in-house CFD code to investigate the turbulence evolution and interaction due to turbulence ring and splash plate in the gas generator. Though chemical reaction was not accounted for, the results can be useful in determining the turbulence characteristics generated by ring and plate. The calculation results show that the installation of turbulence ring can introduce additional turbulences and improve turbulent mixing in the downstream flow. However, the addition of splash plate in the downstream of TR brings totally different shape of perturbation energy and enstrophy distribution for turbulent mixing. This enhancement can be done by the formation of the intensively strong vorticity production and mixing behind the plate. Pressure drop was found to be a reasonable level of about 1% or less of initial pressure in all calculation cases. Also, calculation results revealed that the variation of TR shape and intrusion length did not change the characteristics of turbulent mixing in the chamber. Even though the effect of installation location of splash plate on the turbulent mixing is not investigated yet, calculation results conclude the addition of splash plate leads to the increase in turbulent mixing with an acceptable pressure drop.

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Experimental Studies on the Properties of Epoxy Resin Mortars (에폭시 수지 모르터의 특성에 관한 실험적 연구)

  • 연규석;강신업
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.26 no.1
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    • pp.52-72
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    • 1984
  • This study was performed to obtain the basic data which can be applied to the use of epoxy resin mortars. The data was based on the properties of epoxy resin mortars depending upon various mixing ratios to compare those of cement mortar. The resin which was used at this experiment was Epi-Bis type epoxy resin which is extensively being used as concrete structures. In the case of epoxy resin mortar, mixing ratios of resin to fine aggregate were 1: 2, 1: 4, 1: 6, 1: 8, 1:10, 1 :12 and 1:14, but the ratio of cement to fine aggregate in cement mortar was 1 : 2.5. The results obtained are summarized as follows; 1.When the mixing ratio was 1: 6, the highest density was 2.01 g/cm$^3$, being lower than 2.13 g/cm$^3$ of that of cement mortar. 2.According to the water absorption and water permeability test, the watertightness was shown very high at the mixing ratios of 1: 2, 1: 4 and 1: 6. But then the mixing ratio was less than 1 : 6, the watertightness considerably decreased. By this result, it was regarded that optimum mixing ratio of epoxy resin mortar for watertight structures should be richer mixing ratio than 1: 6. 3.The hardening shrinkage was large as the mixing ratio became leaner, but the values were remarkably small as compared with cement mortar. And the influence of dryness and moisture was exerted little at richer mixing ratio than 1: 6, but its effect was obvious at the lean mixing ratio, 1: 8, 1:10,1:12 and 1:14. It was confirmed that the optimum mixing ratio for concrete structures which would be influenced by the repeated dryness and moisture should be rich mixing ratio higher than 1: 6. 4.The compressive, bending and splitting tensile strenghs were observed very high, even the value at the mixing ratio of 1:14 was higher than that of cement mortar. It showed that epoxy resin mortar especially was to have high strength in bending and splitting tensile strength. Also, the initial strength within 24 hours gave rise to high value. Thus it was clear that epoxy resin was rapid hardening material. The multiple regression equations of strength were computed depending on a function of mixing ratios and curing times. 5.The elastic moduli derived from the compressive stress-strain curve were slightly smaller than the value of cement mortar, and the toughness of epoxy resin mortar was larger than that of cement mortar. 6.The impact resistance was strong compared with cement mortar at all mixing ratios. Especially, bending impact strength by the square pillar specimens was higher than the impact resistance of flat specimens or cylinderic specimens. 7.The Brinell hardness was relatively larger than that of cement mortar, but it gradually decreased with the decline of mixing ratio, and Brinell hardness at mixing ratio of 1 :14 was much the same as cement mortar. 8.The abrasion rate of epoxy resin mortar at all mixing ratio, when Losangeles abation testing machine revolved 500 times, was very low. Even mixing ratio of 1 :14 was no more than 31.41%, which was less than critical abrasion rate 40% of coarse aggregate for cement concrete. Consequently, the abrasion rate of epoxy resin mortar was superior to cement mortar, and the relation between abrasion rate and Brinell hardness was highly significant as exponential curve. 9.The highest bond strength of epoxy resin mortar was 12.9 kg/cm$^2$ at the mixing ratio of 1:2. The failure of bonded flat steel specimens occurred on the part of epoxy resin mortar at the mixing ratio of 1: 2 and 1: 4, and that of bonded cement concrete specimens was fond on the part of combained concrete at the mixing ratio of 1 : 2 ,1: 4 and 1: 6. It was confirmed that the optimum mixing ratio for bonding of steel plate, and of cement concrete should be rich mixing ratio above 1 : 4 and 1 : 6 respectively. 10.The variations of color tone by heating began to take place at about 60˚C, and the ultimate change occurred at 120˚C. The compressive, bending and splitting tensile strengths increased with rising temperature up to 80˚ C, but these rapidly decreased when temperature was above 800 C. Accordingly, it was evident that the resistance temperature of epoxy resin mortar was about 80˚C which was generally considered lower than that of the other concrete materials. But it is likely that there is no problem in epoxy resin mortar when used for unnecessary materials of high temperature resistance. The multiple regression equations of strength were computed depending on a function of mixing ratios and heating temperatures. 11.The susceptibility to chemical attack of cement mortar was easily affected by inorganic and organic acid. and that of epoxy resin mortar with mixing ratio of 1: 4 was of great resistance. On the other hand, when mixing ratio was lower than 1 : 8 epoxy resin mortar had very poor resistance, especially being poor resistant to organicacid. Therefore, for the structures requiring chemical resistance optimum mixing of epoxy resin mortar should be rich mixing ratio higher than 1: 4.

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A Large-scale Structural Mixing Model applied to Blowout of Turbulent Nonpremixed Jet Flames in a Cross air-flow

  • Lee, Kee-Man;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 1997.06a
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    • pp.163-173
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    • 1997
  • This article presents an application of a large-scale structural mixing model (Broadwell et al. 1984) to the blowout of turbulent reacting jets discharging perpendicularly into an unconfined cross air-flow. In an analysis of a common stability curve, a plausible explanation can be made that the phenomenon of blowout is related only to the mixing time scale of the two flows. The most notable observation is that the blowout distance is traced at fixed positions at all times according to the velocity ratio R. Measurements of the lower blowout limits in the liftable flame agree qualitatively with the blowout parameter ${\varepsilon}$, proposed by Broadwell et al. Good agreement between the results calculated by a modified blowout parameter ${\varepsilon}^'$ and experimental results confirms the important effect of a large-scale structure in specifying the stabilization feature of blowouts.

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The Study of Optimum Design of Y-Channel Micro-Mixer by Using LIF Conforcal Microscope (LIF Conforcal Microscope을 이용한 Y-channel 마이크로믹서의 최적설계 연구)

  • Kim, Sang-Woo;Hyun, Seok-Ho;Shin, Tae-Seok;Lee, Do-Hyung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.5
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    • pp.311-317
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    • 2009
  • Due to extremely small device size and velocity scale, mixing in microchannel take place very slowly by way of molecular diffusion transport. Mixing enhancement becomes a central issue in microfluidics for biomedical and chemical applications. In this work, The optimization results and validation through experiment and fabrication. In this efficient micromixer design, it is essential to evaluate mixing efficiency with good precision. Mixing efficiency for Y-channel micromixer is measured by fluorescence intensity using LIF(Laser Induced Fluorescence) Confocal Microscope. The Y-channel micromixers are fabricated with polydimethylsiloxane(PDMS). Nile Blue A is injected into the micromixer as a fluorescence dye for measuring of fluorescence intensity by He/Ne laser. Throughout the experiments and computer simulation, accurate mixing efficiency evaluation process for a PDMS Y-channel micromixer is established.