• Title/Summary/Keyword: Chemical Mixing

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The Effect of CVD Reaction Variable on SnO2 Powder Characteristics

  • Kim, Kyoo-Ho
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.235-239
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    • 1998
  • Ultrafine $SnO_2$ powder was prepared by the diffusion mixing gas-phase reaction of $SnCl_4$(g) and water vapor. The effects of reaction variables, such as the chloride partial pressure, the reaction temperature, and the residence time is the reactor, on the powder size were examined systematically. Calculated concentration and distribution of chemical species, using the Burke-Schumann diffusion mixing model, were compared with the experimetal results. The effects of the reaction variables on the powder size were also discussed qualitatively.

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Numerical Simulation of Thermal Fluctuation of Hot and Cold Fluids Mixing in a Tee Junction

  • Gao, Kai;Lu, Tao
    • International Journal of Advanced Culture Technology
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    • v.3 no.2
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    • pp.171-178
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    • 2015
  • In this work, mixing processes of hot and cold fluids of three different jet types are predicted by large-eddy simulation (LES) on FLUENT platform. Temperature at different positions of internal wall and mixing conditions of T-junctions at different times are obtained, then the simulated normalized mean and root-mean square (RMS) temperature, temperature contour and velocity vector of every case are compared. The results indicate that, the mixing regions in the tee junction is related to the jet type, and temperature fluctuations on the pipe wall in the type of the deflecting jet is the least.

Effect of Helical Ribbon Impeller's Center Shaft & Lateral Supporting Struts on Mixing Performance (Helical Ribbon Impeller의 중심축과 스트럿이 혼합성능에 미치는 영향)

  • Koh, Seung-Tae
    • Korean Chemical Engineering Research
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    • v.60 no.3
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    • pp.468-471
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    • 2022
  • The influence of the central axis and the strut supporting the helical ribbon was investigated in a helical ribbon impeller mixing tank through experiments and visualization. As a result, the strut, which is in the transverse direction, turned out to have a significant adverse effect on the mixing performance such as the occurrence of incomplete mixing region from the change of the liquid level. In contrast, the central axis, which in the longitudinal direction, did not show much adverse effects.

A Numerical Study on Mixing Characteristics of the Chemical Injection Tank

  • Chang, Keun-Sun;Park, Byeong-Ho
    • Nuclear Engineering and Technology
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    • v.29 no.1
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    • pp.58-67
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    • 1997
  • A numerical study has been peformed to investigate the flow and mixing characteristics of a chemical injection tank in the chemical and volume control system (CVCS) of Yonggwang 5&6 (YGN 5&6). This study was undertaken to provide a basis for modification of the previous design (YGN 3&4) which gave a lot of difficulties in installation and operation of the chemical injection system during the start-up test because it needs a special reciprocating pump with a high actual head. For the tank of length-to-diameter ratios (L/D) of 1,2 and 3, each with and without a baffle inside, calculation results were obtained by solving the unsteady laminar two-dimensional elliptic forms of governing equations for the mass, momentum and species concentration. Finite-difference method was used to obtain discretized equations, and the SIMPLER solution algorithm, which was developed based on the staggered grid control volume, was employed for the calculation procedure. Results showed that the baffle is very effective in enhancing the mixing in the tank and that a baffle should be installed near the tank entrance in order to 110 chemicals into the reactor coolant system (RCS) within the operating time required.

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Direct Stacking of Non-metallic Planar Porphyrin to DNA

  • Lee, Min-Ju;Jin, Biao;Lee, Hyun-Mee;Jung, Maeng-Joon;Kim, Seog K.;Kim, Jong-Moon
    • Bulletin of the Korean Chemical Society
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    • v.29 no.8
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    • pp.1533-1538
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    • 2008
  • Porphyrins generally bind DNA in two different ways with respect to the mixing ratio; monomeric binding at a low mixing ratio and outside stacking at a high mixing ratio. In the present study, CTDNA binding property of a planar structured porphyrin, 5,10,15,20-tetrakis(N-methyl-4-pyridin-4-yl-phenyl)porphyrin (referred to as B-TMPyP) was investigated using absorption, CD, LD, and $LD^r$ spectroscopies. B-TMPyP produced a bisignate CD band, even at the lowest mixing ratio, indicating that B-TMPyP may not have a monomeric binding mode. From the observations of the spectral changes to the absorption, CD, and LD spectra in mixing ratio dependent titrations, B-TMPyP seems to have a quite different stacking type compared to that for the binding of $H_2$TMPyP. Moreover, B-TMPyP produced a CD band of opposite shape in the Soret band region. A qualitative explanation for the observed optical differences is also given.

Determination of Mixing Ratio of Mixed Refrigerants and Performance Analysis of Natural Gas Liquefaction Processes (혼합냉매 혼합비에 따른 천연가스 액화공정 성능 비교)

  • Kim, Min Jin;Yi, Gyeong Beom;Liu, Jay
    • Korean Chemical Engineering Research
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    • v.51 no.6
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    • pp.677-684
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    • 2013
  • A mixed refrigerant cycle (MRC) has been widely used in liquefaction of natural gas because it is simple and easily operable with reasonable equipment costs. One of the important techniques in MRC is selection of a refrigerant mixture and decision of its optimum mixing ratio. In this work, it is examined whether mixture components (refrigerants) and their mixing ratio influence performance of general MRC processes. In doing this, mixture design and response surface method, which are well-known statistical techniques, are used to find optimal mixture refrigerants and their optimal mixing ratio that minimize total energy consumption of the entire liquefaction process. A MRC process using several refrigerants and various mixing ratios is simulated by Aspen HYSYS and mixture design and response surface method are implemented using Minitab. According to the results, methane ($C_1$), ethane ($C_2$), propane ($C_3$) and nitrogen ($N_2$) are selected as best mixture refrigerants and the determined mixture ratio (mole ration) can reduce total energy consumption by up to 50%.

Solubility Comparison by Yield Method of Residual of Photoresist for Printing Plate (인쇄 제판용 Photoresist의 잔막수율법에 의한 용해도 비교)

  • Yoon, Cheol-Hun;Hwang, Sung-Kwy;Oh, Se-Young;Chio, Sung-Yong;Lee, Ki-Chang
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.1
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    • pp.25-33
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    • 1998
  • Photoresist is defined as substance that makes chemical changes in its solubility, colouring and hardening by light energy. In this study, photosensitive photoresists of the positive type for a printing plate were studied. PF, o-, m-, p-CF resins as a matrix resin were synthesized at an identical condition. Photoresists were prepared by mixing NDS derivatives with a matrix resin at various mixing ratios. Characteristics of photoresists were studied by yield method of residual using solubility and Optical microscope was also analyzed. Prepared photoresist using NDS derivatives shows excellent photosensitivity and solubility compared with commercial product. The mixing ratio of 1:4(by mass) of NDS derivative[III] and m-CF resin shows the highest dissoultion rate among others. In addition, photoresist was obtained at this condition resulted in the superior sensitivity and contrast.

A study on development of artificial aggregates for embankment using reclaimed coal ash from thermoelectric power station (화력발전소 매립석탄회를 이용한 성토용 인공골재 개발 연구)

  • Yoon, Myung-Seok;Ahn, Dong-Wook;Jang, Nam-Ju;Han, Sang-Jae;Kim, Soo-Sam
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.1051-1060
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    • 2008
  • The use of the coal ash for surcharge material, in a view of the environmental aspect, can decrease amount of the reclamation through recycling waste materials as well as prevent a destruction of the ecosystem attributed to sand picking. In addition, it can reduce both unit cost of material and construction expenses. In this study, new construction material as alternative surcharge material using coal ash, which is by-product from thermoelectric power plant, were developed. Mixing ratios of fly ash and bottom ash derived from the coal ash in Samchunpo thermoelectric power plants were determined. Furthermore, mixing conditions depending on the ratios of the cement and gypsum used for chemical additive were determined too. Uniaxial compression strength tests were conducted at different mixing conditions and Design graph of optimum mixing ratio at each required strength for economic efficiency is indicated in this paper.

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Effects of Grain Size Distribution in Soil on the Strength Characteristics of Lime-Soil Mixtures (흙의 粒度分捕가 石灰混合土의 强度特性에 미치는 影響)

  • Cho, Seong-Jeong;Kang, Yea-Mook
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.27 no.2
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    • pp.57-71
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    • 1985
  • The characteristics of compaction and unconfined compressive strength were investigated by mixing with lime to all soils adjusted by given percentages of two kinds of clays to sand to obtain the most effective distribution of grain size and the optimum lime content for soil stabilization. In addition, unconfined compressive strength and durability tested by adding of sodium metasilicate, sodium sulfate, sodium carbonate, sodium gydroxide and magnesium oxide to lime-soil mixture mixed with 8 percent lime to adjusted soil having the mixing percentage of 60 percent of cohesive black clay and 40 percent of sand by weight to get the effect and the optimum content of chemicals. The results obtained were as follows; 1.With the addition of more lime, the optimum moisture content was increased, and the maximum dry density was decreased, whereas the more the amount of clay and the less was the maximum drt density. 2. In the soil having more fine grain size the unconfined compressive strength was larger in the earlier stage of curing period, in accordance with the longer period, the mixing percentages of sand to clay showing the maximum unconfined compressive strength, on the basis of 28-day strength, were 60% : 40% (black clay) and 40% : 60% (brown clay) respectively. 3. The reason why the soil adjusted with black clay was remarkably bigger in the unconfined compressive strength than ones adjusted with brown clay for all specimen of lime-soil mixture was the difference in the kind of clay, the amount of chemical compositions the value of pH. Black clay was mainly composed of halloysite that reacted with lime satisfactorily, whereas the main composition of brown clay was kaolinite that was less effect in the enhance of unconfined compressive strength. Also the difference of unconfined compressive strength was because black clay was larger in the amount of composition of calcium oxide and magnesium oxide in the value of pH affecting directly on the unconfined compressive strength of lime-soil mixture than brown clay. 4. In the lime-soil mixture mixed with 8 percent of lime to soil that mixing percentage of sand to black clay was 60% : 40%, on the standard of 7-day strength, the effect of chemical was arranged in the order of magnesium oxide, sodium carbonate, sodium sulfate, sodium hydroxide and sodium metasilicate. 5. The optimum amount of chemical being applicable to the maximum unconfined compressive strength of lime-chemical-soil mixture was 1 percent by weight for air dry soil in the case of adding sodium carbonated and 0.75 percent on sodium hydroxide, the unconfined compressive strength was increased continuously with increase of the amount of chemical up to 2 percent of chemical content is the lime-chemical-soil mixture added sodium metasilicate, sodium sulfate and magnesium oxide. 6. It was considered that the chemical played and accelerant role of early revelation of strength because the rate of increase of unconfined compressive strength of all of lime-chemical-soil mixtures was largest on the 7-day cured specimen. 7. The effect of test on freezing and thawing after adding suitable amount of chemical on the lime-soil mixture mixed with 8 percent of lime to soil that mixing percentage of sand to black clay was 60% : 40% was arranged in the order of magnesium oxide, sodium carbonate, sodium sulfate, sodium metasilicate and sodium hydroxide.

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