• Title/Summary/Keyword: Chemical Mixing

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3D Printing-Based Ultrafast Mixing and Injecting Systems for Time-Resolved Serial Femtosecond Crystallography (시간 분해 직렬 펨토초 결정학을 위한 3차원 프린팅 기반의 초고속 믹싱 및 인젝팅 시스템)

  • Ji, Inseo;Kang, Jeon-Woong;Kim, Taeyung;Kang, Min Seo;Kwon, Sun Beom;Hong, Jiwoo
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.300-307
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    • 2022
  • Time-resolved serial femtosecond crystallography (TR-SFX) is a powerful technique for determining temporal variations in the structural properties of biomacromolecules on ultra-short time scales without causing structure damage by employing femtosecond X-ray laser pulses generated by an X-ray free electron laser (XFEL). The mixing rate of reactants and biomolecule samples, as well as the hit rate between crystal samples and x-ray pulses, are critical factors determining TR-SFX performance, such as accurate image acquisition and efficient sample consumption. We here develop two distinct sample delivery systems that enable ultra-fast mixing and on-demand droplet injecting via pneumatic application with a square pulse signal. The first strategy relies on inertial mixing, which is caused by the high-speed collision and subsequent coalescence of droplets ejected through a double nozzle, while the second relies on on-demand pneumatic jetting embedded with a 3D-printed micromixer. First, the colliding behaviors of the droplets ejected through the double nozzle, as well as the inertial mixing within the coalesced droplets, are investigated experimentally and numerically. The mixing performance of the pneumatic jetting system with an integrated micromixer is then evaluated by using similar approaches. The sample delivery system devised in this work is very valuable for three-dimensional biomolecular structure analysis, which is critical for elucidating the mechanisms by which certain proteins cause disease, as well as searching for antibody drugs and new drug candidates.

Numerical Investigations of Turbulent Piloted Non-Premixed Flames (난류 Pilot 비예혼합 화염장의 상세구조 해석)

  • Lee, Jeonwon;Jeon, Sangtae;Kim, Yongmo
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.185-186
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    • 2014
  • The multi-environment probability density function model has been applied to simulate the turbulent stratified premixed flames. The direct quadrature method of moments (DQMOM) has been adopted to solve the transport PDF equation due to its computational efficiency and robustness. The IEM mixing model is employed to represent the mixing process and the chemical mechanism is based on Gri 3.0 mechanism. Numerical results obtained in this study are precisely compared with experimental data in terms of unconditional and conditional means for scalar fields and velocity fields.

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Development of Mixing Model for High Durability Creek Concrete Having 300kgf/$\textrm{cm}^2$ Compressive Strength (압축강도 300kgf/$\textrm{cm}^2$ 내외의 하수암거용 고내구성 콘크리트 배합모텔 개발)

  • 이창수;윤인석;이규동;고석봉
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.271-274
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    • 2001
  • Recently, we are facing with the trend of demanding high durability concrete for creek structures. When creek structures are deteriorated, it is very difficult to repair them. The objective of this paper is to develop a mixing model for high durability creek concrete having 300kg/$\textrm{cm}^2$ compressive strength. According to the result of durability experiment, high durability concrete for creek structures has high resistance of air permeability, absorption, chloride diffusion, and chemical attack.

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Mechanical Properties of Carbon Nanofiber Reinforced Hybrid Composites (탄소나노섬유가 강화된 하이브리드 복합재료의 기계적 물성)

  • Kong Jin-Woo;Chung Sang-Su;Kim Tae-Wook
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.31-34
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    • 2004
  • Carbon nanofiber exhibits superior and often unique characteristics of mechanical, electrical chemical and thermal properties. In this study, For improvement of the mechanical properties of composites, carbon nanofiber reinforced hybrid composites was investigated. For the effect of dispersion, The dispersion methods of solution blending and mechanical mixing were used. The mixing of solution blending method was used using ultrasonic. Dispersion of carbon nanofiber was observed by scanning electron microscope (SEM). Mechanical properties were measured by universal testing Machine (UTM).

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Fabrication of caterpillar mixer and its surface characterization (캐터필러형 믹서의 제작 및 표면 특성 연구)

  • Han Chang-Soo;Park June-Ki;Yoon Yeo-Hwan
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.541-542
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    • 2006
  • A micro-size caterpillar mixer has been recently used fur desktop chemical factory and so attractive due to small investment fund for arranging the factory and high efficiency by mixing in sub micro-level region. We report the fabrication of caterpillar mixer and its surface treatment for enhancement of mixing performance. We used the

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A Study on the Effect of Mastication in Solution SBR (용액중합 SBR의 내림효과에 관한 연구)

  • Oh, Jeong-Hoon;Yoon, Dong-Il
    • Elastomers and Composites
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    • v.27 no.4
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    • pp.262-266
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    • 1992
  • A number of tin-containing elastomers are produced commercially by Korea Kumho Petrochemical Co., Ltd. (KKPC) under the Kosyn Sol tradename. The effect of mastication of commercial and laboratory polymerized S-SBR has, been investigated using chemical mixer(ML-500), NMR, GPC and Mooney viscometer. Mastication of polymers containings coupling bonds is affected by the amount of stearic acid, the temperature of mixing and the time length of mixing.

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Factors Affecting Biofouling in Membrane Coupled Sequencing Batch Reactor

  • Lee, Chung-Hak
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.7-10
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    • 2003
  • Factors affecting filtration performance were investigated in a Sequencing Batch Reactor (SBR) coupled with a submerged microfiltration module. Special bioreactors for aerobic and anoxic phases, respectively, were specifically designed in order to differentiate tile effect of Dissolved oxygen (DO) from that of mixing intensity on membrane filterability. DO concentration as well as mixing intensity proved to have a major influence on the membrane performance regardless of the SBR phase. A higher DO concentration resulted in a slower rise in TMP, corresponding to less membrane fouling.

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Study on the Gas-Liquid Mixing Characteristics in Reactor System Using Ejector

  • Jin, Zhen-Hua;Utomo, Tony;Chung, Han-Shik;Jeong, Hyo-Min;Shin, You-Sik;Lee, Sang-Chul
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2708-2713
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    • 2007
  • The aim of this paper is further studies to achieve deeper understanding in this field. First investigate the influence of operating conditions and design parameters on the hydrodynamics and the mass transfer properties of a loop reactor. This paper provides a literature review on the ejectors applications in the mixing system. A number of studies are grouped and discussed in several topics such as the background, theory of ejector, mixing characteristics, optimization of the system. Since the high efficiencies reactor using ejector widely used in gas-liquid system, especially in a number of chemical and biochemical processes. This is due to their high efficiency in gas dispersion resulting in high mass transfer rate and low power requirements. Thus ejector has been applied to the mixing system. An investigation on hydrodynamics and mass transfer characteristics of gas-liquid ejector has been carried out using three-dimensional CFD modeling.

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Effects of Volatile Solid Concentration and Mixing Ratio on Hydrogen Production by Co-Digesting Molasses Wastewater and Sewage Sludge

  • Lee, Jung-Yeol;Wee, Daehyun;Cho, Kyung-Suk
    • Journal of Microbiology and Biotechnology
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    • v.24 no.11
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    • pp.1542-1550
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    • 2014
  • Co-digesting molasses wastewater and sewage sludge was evaluated for hydrogen production by response surface methodology (RSM). Batch experiments in accordance with various dilution ratios (40- to 5-fold) and waste mixing composition ratios (100:0, 80:20, 60:40, 40:60, 20:80, and 0:100, on a volume basis) were conducted. Volatile solid (VS) concentration strongly affected the hydrogen production rate and yield compared with the waste mixing ratio. The specific hydrogen production rate was predicted to be optimal when the VS concentration ranged from 10 to 12 g/l at all the mixing ratios of molasses wastewater and sewage sludge. A hydrogen yield of over 50 ml $H_2/gVS_{removed}$ was obtained from mixed waste of 10% sewage sludge and 10 g/l VS (about 10-fold dilution ratio). The optimal chemical oxygen demand/total nitrogen ratio for co-digesting molasses wastewater and sewage sludge was between 250 and 300 with a hydrogen yield above 20 ml $H_2/gVS_{removed}$.

Evaluation of Local Velocity Gradient and Total Mass transfer Time at Various Rotating Velocity by Using Computational Fluid Dynamics (CFD를 이용한 패들교반속도에 따른 속도경사 및 총물질전달시간 산정)

  • Jun, Hang-Bae;Tian, Dong-Jie;Hong, Ki-Won;Han, Hong-Sig;Park, Byeong-Chang
    • Journal of Korean Society on Water Environment
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    • v.30 no.2
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    • pp.166-174
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    • 2014
  • Velocity gradient, G, a measure of the average velocity gradient in the fluid has been applied for complete mixing of chemicals in mechanical mixing devices. G values were calculated by the power input transferred to fluid in turbulent and transient range. Chemical reactions occur so fast that total mass transfer time required for even distribution of the chemicals determine the overall reaction time. The total mass transfer time is composed of the time for complete mixing through the reactor and for diffusion of the chemicals into the eddy. Complete mixing time was calculated by CFD (computer fluid dynamics) and evaluated by tracer tests in 2 liter jars at different rotating speeds. Turbulent range, Reynolds number above 10,000 in regular 2 liter jars occurred at revolution speed above 100 rpm (revolution per minute), while laminar range occurred at revolution speed below 10 rpm. A typical range of rotating speed used in jar tests for water and wastewater treatment was between 10 and 300 rpm, which covered both transient and turbulent range. G values supplied from a commercial jar test apparatus showed big difference from those calculated with power number specially in turbulent range. Diffusion time through eddy decreased 1.5 power-law of rotating speed. Complete mixing time determined by pumping number decreased increases in rotating speed. Total mass transfer time, finally, decreases as rotating speed increases, and it becomes 1 sec at rotating speed of 1,000 rpm. Complete mixing times evaluated from tracer tests showed higher than those calculated by power number at higher rotating speed. Complete mixing times, however, calculated by CFD showed similar to those of experimentally evaluated ones.