• Title/Summary/Keyword: Chemical Milling

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Determination of Optimal Cutting Conditions Based on the Relationship between Tool Grade and Workpiece Material (피삭재와 공구재종의 상관관계에 근거한 적정 절삭조건의 결정)

  • 한동원;고성림;이건우
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.6
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    • pp.79-89
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    • 1998
  • In determining optimal cutting condition for face milling operation, tool wear is an important factor. For the purpose of establishing the relationship between various machining factors and tool wear, cutting tests have been performed. As a result, hardness and chemical composition of workpiece material, chemical composition and grain size of cutting tool and cutting speed have been selected as machining factors. In addition, relationship between feed rate and workpiece hardness has been observed. Prior to utilizing cutting conditions recommended by ‘Machining Data Handbook(MDH)’ as a knowledge base, an analysis for the validity of the MDH has been provided. Based on this analysis, tool life criteria applied by MDH has been modified. Finally, using MDH recommended data for neural network trainning, the results from the trained neural network for optimal cutting condition for some given workpiece and cutting tool can be used as reference cutting conditions.

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Characteristics of Grain Qualtiy at Different Transplanting Times among Rice Cultivars (벼의 품종별 이앙시기가 미질 특성에 미치는 영향 II. 미립의 외관특성과 화학적 성분의 변화)

  • 고재권
    • Korean Journal of Plant Resources
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    • v.11 no.1
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    • pp.64-69
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    • 1998
  • This experiment was conducted to investigatd the variation of some apearance chemical components at National Honam Agricultural Experiment Station in Korea. the treatements consisted of five transplating times, form May 5 to July 5 at 15-day interval , and six cultivars ; two early-maturing, two mid-maturing and two latematuring cultivars. The results showed that the variatio of grain appearance such as length-wide ratio was not significantly different in early -maturing cultivars, but mid-and late-maturing cultivars made slightly a round shape of grain in case of early transplanting. Percentage of complete grain was found to be high at transplanting of MAy 20 inearly-maturing cultivars and on June 5 in mid-and late-maturing ones. PERcentage of existed embryo after milling showed high at early transplanting of May 5 for early -maturing cultivars, and at the late transplanting of June 5 in early and late maturing one. The chemical components of rice grain showed high in protein , lipid,ash and amylose content inthe earlier transplanting, and also revealed high in carbohydrates, magnesium and potassium in the later transplanting of all cultivars.

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Electrochemical Properties of $LiNi_{1-y}In_yO_2$ Synthesized by Milling and Solid-/state Reaction Method (기계적 혼합과 고상법에 의해 합성한 $LiNi_{1-y}In_yO_2$ 전기화학적 특성)

  • Kim, Hun-Uk;Youn, Sun-Do;Lee, Jae-Cheon;Park, Hye-Ryoung;Park, Chan-Gi;Song, Myoung-Youp
    • Journal of Hydrogen and New Energy
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    • v.17 no.1
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    • pp.117-124
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    • 2006
  • By calcining at $750^{\circ}C$ for 30 h in $O_2$ stream after milling, $LiNi_{1-y}In_yO_2$(y = 0.005, 0.01, 0.025, 0.05, and 0.1) were synthesized and their electrochemical properties were investigated. All the samples had the $R{\bar{3}}m$ structure. In addition, they contained $LiInO_2$ phase and the intensities of the peaks for the $LiInO_2$ phase increased as the value of y increased. The sample with y = 0.01 had the largest first discharge capacity (140.2 mAh/g), but the sample with y = 0.005 had a better cycling performance. The samples with y $\geq$ 0.025 had a bad cycling performance irrespective of the first discharge capacity. The sample with y = 0.005 had the largest value of $I_{003}/I_{104}$ and the smallest value of R-factor. Among all the samples, $LiNi0_{0.995}In_{0.005}O_2$ had the best electrochemical properties. This sample had a smaller first discharge capacity than $LiNiO_2$, but it showed a better cycling performance than $LiNiO_2$.

Electrochemical Properties of LiNi1-yMyO2(M=Zn2+, Al3+, and Ti4+) Synthesized by Milling and Solid-State Reaction Method (기계적 혼합과 고상법에 의해 합성한 LiNi1-yMyO2(M=Zn2+, Al3+, and Ti4+)의 전기화학적 특성)

  • Kim, Hunuk;Youn, SunDo;Lee, Jaecheon;Park, HyeRyoung;Song, Myoungyoup
    • Journal of the Korean Ceramic Society
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    • v.42 no.5 s.276
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    • pp.352-358
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    • 2005
  • By calcining at $750^{\circ}C$ for 30 h in $O_2$ stream after milling, $LiNi_{1-y}M_yO_2(M=Zn^{2+},\;Al^{3+}$, and $Ti^{4+}$, y = 0.005, 0.01, 0.025, 0.05, and 0.1) were synthesized and their electrochemical properties were investigated. All the samples had R3m structure. $LiNi_{1-y}Zn_yO_2$ (y = 0.025, 0.05, and 0.1) contained ZnO anuor $Li_2ZnO_2$ as impurities. Among the samples substituted with the same element, the samples with relatively large value of $I_{003}/I_{104}$ and the smallest R-factor had the largest first discharge capacity and good cycling performance. $LiNi_{0.975}A1_{0.025}O_2$ had the largest first discharge capacity (172.5 mAh/g) and good cycling performance (about $89.4\%$ of the first discharge capacity at the 20th cycle). This sample had the largest value of $I_{003}/I_{104}$ and the smallest R-factor among all the samples. In addition, the particles of this sample were finer and their size was more homogeneous than the other samples. $LiNi_{0.95}A1_{0.05}O_2$ had relatively large first discharge capacity 150.4 mAh/g and good cycling performance.

A Relation between the Electrochemical Behaviors and Morphology of Co3O4 and Ni-Co3O4 Composites as Anode Materials for Li Ion Secondary Batteries (리툼 이차 전지용 Co3O4 및 Ni-Co3O4 복합물의 전기화학적 특성 및 표면 형상의 관계)

  • Kang, Yong-Mook;Lee, Yong-Ju;Song, Min-Sang;Park, Min-Sik;Lee, Jai-Young
    • Journal of Hydrogen and New Energy
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    • v.14 no.3
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    • pp.217-228
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    • 2003
  • Li 이차 전지 음극용 활물질인 $Co_3O_4$의 초기 충방전 효율을 향상시키기 위해 chemical reduction method나 mechanical milling법을 이용하여 $Co_3O_4$에 Ni을 첨가하여 $Ni-Co_3O_4$, 복합물을 제조하였다. 그 결과 초기 충방전 효율이 약 69%에 불과한 $Co_3O_4$에 비해 mechanical milling법을 이용하여 제조된 $Ni-Co_3O_4$ 복합물은 약 79%이상의 대폭 향상된 초기 충방전 효율 특성을 나타내었다. 하지만 chemical reduction method를 이용하여 제조된 $Ni-Co_3O_4$ 복합물은 약 71%의 초기 충방전 효율 특성만을 나타내었다. SEM 분석을 통해 각 물질의 표면 형상을 관찰한 결과 mechanical milling법과 chemical reduction method를 통해 제조된 $Ni-Co_3O_4$ 복합물에서는 $Co_3O_4$ 표면에 분포된 Ni의 균일성의 차이가 존재하였다. $Co_3O_4$$Li_2O$의 분해, 형성에 의해 충방전되고 Ni이 $Li_2O$의 분해를 촉진시키는 효과를 가지고 있음을 고려할 때 이러한 균일성의 차이는 결국 Ni 과 $Co_3O_4$ 사이의 접촉면적의 차이로 이어져 $Ni-Co_3O_4$ 복합물의 초기 충방전 효율 특성이 그 제조 방법에 따라 달라지는 것으로 보인다.

Size Control and Dispersion Properties of Illite Clay by Physicochemical Treatment (물리화학적 처리에 의한 일라이트 점토광물의 입도조절 및 분산특성)

  • Lim, Jae Won;Jeong, Euigyung;Seo, Kyeong-won;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.22 no.2
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    • pp.133-137
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    • 2011
  • In this study, illite was size-reduced using a wet-ball-milling treatment to improve its dispersion. Changes in illite particle size, size distribution, and dispersion characteristics after varying the treatment period were investigated. And the dispersion and dispersion stability of illite solution after 2 h wet ball milling treatment with different pH conditions were also evaluated. The illite particle size significantly decreased as the treatment time increased and the size reduction effect of wet ball milling deteriorated above 2 h treatment time. In addition, illite particle size was more evenly distributed as the treatment time increased. X-ray diffraction (XRD) analysis showed that no crystal structural changes of illite were induced, but the characteristic peak of illite the weaker due to the size reduction and exfoliation, as the treatment time increased. Zeta potential analysis showed that the illite dispersion improved, as the treatment time increased. The illite wet-ball-mill treated at pH 2 had the lowest dispersion stability. Illite dispersion and dispersion stability increased as pH increased, due to the increase in surface ionization. Hence, the results showed that as the treatment time increased, the illite particle size decreased, and dispersion and dispersion stability improved due to the increase in surface energy and repulsion force between particles.

Influence of Yeast-treated Rice By-products on Growth, Yield and Grain Quality of Rice

  • Seo, Pil Dae;Nunez, John Paolo;Park, Jae Sang;Ultra, Venecio U. Jr.;Lee, Sang Chul
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.58 no.2
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    • pp.128-135
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    • 2013
  • The use of agricultural by-products as alternative nutrient sources in crop production had gained popularity in order to reducing the rate of chemical fertilizer application in the field. This study was conducted to determine whether the application of rice milling by-products treated with yeast inoculants could substitute, or reduce the rate of chemical fertilizer application. The results of agronomic measurements showed that the effect of incorporated materials was not immediate, as compared to 100% chemical fertilizer application. However, grain yield and quality was either the same or greater than 100% chemical fertilizer application. It was found out that expanded rice hull (treated with yeast or not) could reduce the rate of applying chemical fertilizers by half. Also, yeast treatment was only favorable only to expanded rice hull and not with rice bran, and was already found to be a potential material in reducing chemical fertilizer application in rice production.

Effects of Microbe-inoculated Expanded Rice Hull on Growth, Yield and Grain Quality of Rice

  • Kim, Young Jun;Nunez, John Paolo;Seo, Pil Dae;Ultra, Venecio U. Jr.;Lee, Sang Chul
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.58 no.1
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    • pp.78-83
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    • 2013
  • The excessive and indiscriminate use of chemical fertilizers in the past has brought serious soil and other environmental problems so alternatives over this agrochemical are being searched. Our study focuses on the effects of expanded rice hull inoculated with selected beneficial microorganisms on growth (through agronomic characters), yield and yield components, and grain quality indices of rice. Results showed that favorable effects of different expanded rice hull preparations were not readily apparent at vegetative stage and only treatments with supplemental chemical fertilizer application were comparable with the conventional practice. Expanded rice hull combined with 50% rate of chemical fertilizer exhibited a significantly higher yield (6,471 kg $ha^{-1}$) over conventional practice (5,719 kg $ha^{-1}$). Good milling quality indices were observed in treatments having 50% chemical fertilizers plus alternatives from expanded rice hull. Finally, we demonstrated that chemical fertilizer rate can potentially be reduced into 50% if combined with expanded rice hull, and show even better output than chemical fertilizer alone.