• 제목/요약/키워드: Chemical Industries

검색결과 869건 처리시간 0.03초

SYNTHESIS AND CHARACTERIZATION OF THE POLYCATIONS FOR THE PREPAEATION OF POLYION COMPLEX MEMBRANS

  • Jegal, J.G.;park, Y.I.;Kim, J.H.;Lee, K.H.
    • 한국막학회:학술대회논문집
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    • 한국막학회 1993년도 추계 총회 및 학술발표회
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    • pp.58-58
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    • 1993
  • Pervaporation has become important as a method to separate liquid mixtures, sepecially azeotropic and close boiling-point mixtures. Especially, water-alcohol separations have been carried out a lot because of the practical interests in the industries. However, outstanding membranes with high selectivity and high permeability have not been available in common use yet. In order to separate selectively out the water mixed with alcohols with an aim of the purification of the alcohols, a membrane has tO have excellent affinity to water. Among the hydrophilic polymers, polyacrylic acid and poly(vinyl alcohol) are used widely. In recent years, ionomers and polyion complexes, better hydrophitic materials, start to be used. The polyion complex membranes, consisting of polyacrylic acid (PAA) and polycation, showed excellent permeation rates and selectivities. It was known that among the polycations, ioneries, which have quaternary ammonium groups in the backbone chain, were more effective in giving membranes of higher permselectivities. On this base, syntheses and characterizations of the polycations, with different chemical structures from the published ones, for the polyion complex membrane formation were studied in this paper.

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안전보건경영시스템 구축을 위한 위험성평가모델에 대한 연구 - 화학물질 사용조직을 중심으로 - (A Study on Risk Assessment Model for Occupational Health and Safety Management System - Focused on Organization Using Chemical Material -)

  • 조경석;이창호
    • 대한안전경영과학회지
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    • 제16권4호
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    • pp.1-9
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    • 2014
  • The occupational health and safety accidents were continuously increased during handling, usage and manufacturing the chemical materials according to increase of small and medium sized enterprises in domestic industries. These accidents mainly resulted from insufficient occupational health and safety management and deteriorative facilities and focused on corresponding operation to minimize the damage of accidents after occurrence. But, it was required that we grasped the occurrence causes of occupational health and safety risk in handling, usage and manufacturing the chemical materials and develop the adequate corresponding operation and system according to the possible occurrence of occupational health and safety risk. This study deals with the development of risk assessment model to derive the risk and important risk of occupational health and safety and then help to construct the self-controlled occupational health and safety system for small and medium sized enterprises handling the chemical materials.

스테인리스 강의 부식 측정방법의 이용과 전망 (Prospects on the Use of Corrosion Rate Measurement Method for Stainless Steel)

  • 최용선;이재원;박은옥;이기영
    • 한국표면공학회지
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    • 제54권6호
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    • pp.294-301
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    • 2021
  • As the number of cases of performance degradation owing to corrosion of plant during processing in industries increases, the cost of maintaining industrial factory is increasing year by the year. Most of the materials of the facilities are consist of stainless steel (SS) such as austenite SS, ferrite SS, martensite SS, and duplex SS. Among them austenite SS is cheap and has excellent corrosion resistance and heat resistance. Corrosion is the consumption and change of metals by altering chemical and electrical reactions. The types of SS corrosion include pitting corrosion, crevice corrosion, galvanic corrosion, stress corrosion cracking, and thermal corrosion. The corrosion of SS is not only investigated various environmental factors but also the measurement of the corrosion rate. Therefore, it aims to understand comprehensive corrosion rates in various environments using qualitative, quantitative and electrochemical methods.

Effect of Cross-Linking Characteristic on the Physical Properties and Storage Stability of Acrylic Rubber

  • Seong-Guk Bae;Min-Jun Gim;Woong Kim;Min-Keun Oh;Ju-Ho Yun;Jung-Soo Kim
    • Elastomers and Composites
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    • 제58권3호
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    • pp.136-141
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    • 2023
  • Polyacrylic rubber (ACM) is well known for its excellent heat resistance and chemical stability. Additionally, its performance can be readily manipulated by modifying its functional groups, rendering it highly attractive to various industries. However, extreme climate changes have necessitated an expansion of the operating temperature range and lifespan of ACM products. This requires the optimization of both the compounding process and functional-group design. Hence, we investigated the relationship between the cross-linking system and mechanical properties of an ACM with a carboxylic cure site. The crosslink density is determined by chemical kinetics according to the structure of additives, such as diamine crosslinkers and guanidine accelerators. This interaction enables the manipulation of the scotch time and mechanical properties of the compound. This fundamental study on the correlation analysis between cross-linking systems, physical properties, and storage stability can provide a foundation for material research aimed at satisfying the increasingly demanding service conditions of rubber products.

염산수용액의 농도별 간이 영향 평가 방법 연구 (A Study on the Simplified Estimating Method of Off-site Consequence Analysis by Concentration of Hydrochloric Acid)

  • 정유경;김병훈;허화진;유병태;신창현;윤이;윤준헌;마병철
    • 한국안전학회지
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    • 제32권2호
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    • pp.52-58
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    • 2017
  • One of the most important elements of the management of chemical accident is threat zone estimation of fires, explosions and toxic gas dispersion based on chemical releases. The threat zone estimation is going to be standard of emergency response for the first defender and base line data of off-site risk assesment (hereinafter referred to as "ORA") and risk management plan (hereinafter referred to as "RMP"). Generally, ALOHA form EPA(U.S.) and Kora(from KOREA MINISTRY OF ENVIRONMENT) has been used for the off-site consequence analysis in Korea. However it is hard to predict accurate consequences rapidly in case of emergency. Hydrochloric acid is a multipurpose raw material used in many industrial applications such as chemical, metal and food industries. It is usually treated in concentrations from 10 ~ 35 %, and release accident have occurred frequently. In this study, we have developed a simplified estimating method and equation to calculate threat zone easily in case of emergency due to release accident of hydrochloric acid.

중소규모 제조업의 건강·안전·실천에 대한 화학물질 인식도 비교 (Comparison of Recognition of Chemical Substances about Health·Safety·Practice in Small and Medium-Sized Maunfacturing Industries)

  • 어원석;이상민;박근섭
    • 한국안전학회지
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    • 제34권4호
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    • pp.49-58
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    • 2019
  • There was a difference in recognition of chemical substances according to cognitive level of GHS, knowledge level of organic solvents and each department of workers. they were showed higher recognition of chemical substances by research group, partially group and good group. To identify the relationship between types of job classification(group of department, group of GHS cognitive level and group of organic solvents knowledge level) and the levels of recognition of chemical substances, a total of 153 workers in a small and medium business workplace. Descriptive statistics(SAS ver 9.2)was performed. the results of recognition of chemical substances were analyzed the mean and standard deviation by t-test, and anova, (P=0.05). These results In general, small- and medium-sized workplaces have low levels of GHS awareness and organic solvents knowledge. The perception of chemical substances according to the departments. In general, the demand for chemical substances education was highly suggested regardless of the job type. There was a significant difference in the perception of health, safety and practice according to the level of GHS cognitive, and a high perception in the incomplete group. There was not much difference in average awareness of health, safety and practice according to organic solvents knowledge level, but there was a high perception in good group. It is very important to regularly check the worker's perception of the workplace and identify problems with the work environment and improve the work environment. In addition, each department presents appropriate safety and health education such as chemical process safety, toxicity of chemical substances and human exposure. We also propose a chemical substances assessment and management plan that integrates safety and health.

국내 화학물질 배출량 특성에 관한 연구: 악취물질 중심으로 (A Study on the Emission Characteristics of Odorous Substances in Korea)

  • 임지영;전다영;김보경;류지성;윤대식;이청수
    • 한국환경보건학회지
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    • 제45권5호
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    • pp.465-473
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    • 2019
  • Objectives: A variety of industries handling hazardous chemicals emit odorous substances. Based on the emission characteristics of major odor substances from the results of hazardous chemical substance emissions, we will define basic data for improving the management methods of odorous substances. Methods: A survey of hazardous pollutant emissions for 2010-2016 was conducted through the Pollutant Release and Transfer Register homepage. Eight kinds of designated odor substances (ammonia, hydrogen sulfide, dimethyl disulfide, acetaldehyde, styrene, toluene, xylene, methyl ethyl ketone) provided the study subjects. The status of chemical accidents for the target substances was analyzed using the Chemistry Safety Clearing-house system. Results: From 2010 to 2016, it was found that more than 30% of businesses that emitted odorous substances accounted for more than 50% of the total emissions of the eight substances. Emissions of xylene, toluene, methyl ethyl ketone, and ammonia were found, in that order, and they made up more than 90% of the total emitted. By region, about 70% of odorous substances were emitted in the top-four regions: Gyeongsangnam-do Province, Ulsan, Gyeonggi-do Province, and Jeollanam-do Province. Conclusion: Recently, the amount of chemical emissions has been continuously increasing, including those that can cause odor. Odorous substances can be a serious risk to the lives of local residents. Systematic research is needed for the health protection of residents.

영세사업장 보건관리 지원사업 실시 전후의 산업보건수준 비교 분석 (A Comparative Analysis of the Level of Occupational Health : Before and After the Subsidiary Program on Health Care Management of Small Scale Industries)

  • 정혜선
    • 한국직업건강간호학회지
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    • 제4권호
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    • pp.58-83
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    • 1995
  • The small scale industries which have less than 30 employees occupy 86.5% of total number of industries in Korea. And though they have higher accident rate and lower environmental condition than big industries, it has been not mandatory to appointing health care manager at factory. So, from 1993, government subsidizes to the health care management of small industries. The purpose of this study is to identify the real feature of health care status in small industries, and to evaluate the level of health care management, before and after the subsidiary program. 65 small plating industries which have been managed by the same health care management support institution in 1993 were selected for study. Of the 65 industries, 3 which have not taken both environmental evaluation and health screening in 1994, and 9 which have closed were excluded from study sample. And the remaining 53 were analyzed by using the results of environmental evaluation and health screening, reported to the Ministry of Labor, before and after the subsidiary program, the analysis was done by the comparison of the two year paired data of the same industry. Over-permissible-limit rate, health screening implementation rate, above grade C rate were calculated and compared. The status of health care management ; 1. Of the sample industries, 96.9% provide protective equipment and 80.0% set up ventilating system. Protective gloves (89.2%) and protective clothing (80.0%) are widely provided, but ear plugs (4.6%) are rarely provided. 21.5% of the protective equipment are well put on, and 40.4% of the ventilating systems function well. 2. In 1993, 35 industries, 53.8% of the sample, checked working environment twice. Over-permissible-limit rates of heavy metal (12.2%), suspended particle (11.1%), noise (5.5%) were high. To put on protective equipment and to set up local ventilating system were pointed out by the examiners. 3. General health screening was done at 63.1% of the sample industries and 35.3% of total workers were examined. Specific health screening was done at 93.8% of the sample industries and 75.4% of workers were examined. 15.5% of workers was provided to be above grade C and to have digestive system disease (43.3%), circulatory disease (18.9%), and hematopoietic disease (14.2%), etc. 4. In 1993, the subsidiary program of health care management was provided in forms of health education, health counseling, and rounding check of working field. And 61.5%, 83.0%, 55.4% of sample industries respectively received it. The average visit per industry was 1.8. Comparisons of the level of occupational health before and after the subsidiary program ; 1. Over-permissible-limit rates of hazardous factors of 1993 and that of 1994 were compared. The rates of suspended particle, noise, organic solvent of 1994 (37.5%, 13.4%, 24.2% respectively) were higher than that of 1993 (25.0%, 6.0%, 6.3% respectively). In the case of acid, there was no difference between the rate of 1993 and that of 1994. Only the rate of heavy metal decreased from 12.9% in 1993 to 3.0% in 1994. 2. General health screening was done at 38.7% of the sample industries in 1993 and at 44.6% in 1994. But the implementation rate of specific health screening decreased from 72.4% in 1993 to 64.6% in 1994. 3. The implementation rate of specific health screening was analyzed by some health factors. The rate of suspended particle increased from 61.8% in 1993 to 91.2% in 1994. But the rates of the others-noise, organic solvent, heavy metal, specific chemical substances-decreased. 4. Above grade C rate in health screening increased from 27.8% in 1993 to 35.5% in 1994. But that of endocrine disorders and pulmonary disease decreased.

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DMF 취급 사업장에 대한 매트릭스 적용 및 위험성 평가 연구 (Application of Matrices and Risk Assessment of Industries and Processes using DMF)

  • 하권철;박동욱;윤충식;최상준;이광용;백도현;남택형;이재환;이종근;정은교
    • 한국산업보건학회지
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    • 제18권4호
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    • pp.303-309
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    • 2008
  • The reduction of risk within the workplace has long been focus of attention both through industry initiatives and legislation. Exposure matrices according to industries and processes treated DMF (N,N-Dimethylformamide) were constructed based on KOSHA (Korean Occupational Safety and Health Agency)'s 2005 exposure database which were gathered from Korean agencies of workplace hazards evaluation for business place. These exposure matrices were assessed by danger value (DV) that was calculated from combination of hazard rating, duration of use rating, and risk probability rating of exposure to chemical hazardous agents in accordance with Hallmark Risk Assessment Tool. The results of risk assessment is divided four kinds of control bands which were related with control measures. The applicability of risk assessment using exposure matrices was performed by field study and survey for high matrices group. This study found that more attentions should be paid to two industries, manufacture of sewn wearing apparel and manufacture of textiles, among 19 industries, and to 3 processes, coating, processing & mixing, and lab, among 80 processes because those were regarded as having the highest risk.

우리나라 노출기준 초과 발암성물질의 특성 (Characteristics of Occupational Carcinogens Exceeding Occupational Exposure Limit in Korea, 1999 to 2009)

  • 피영규
    • 한국산업보건학회지
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    • 제21권4호
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    • pp.227-235
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    • 2011
  • The objective of this study was to analyze 157 processes of 145 industries that exceeded Korean Occupational Exposure Limits (KOEL) for carcinogen during the 11 year period from 1999 to 2009. The data included number of industry and workers exposed, type of carcinogen and their exceeded ratio, type and size of industry in each year. These data were collected by 46 regional employment & labor offices in Korea using work environment monitoring reports. The result showed that, in each year, about 10 industries exceed their carcinogen exposure limit. The most common carcinogen exceeding KOEL were found to be formaldehyde, benzene, ethylene oxide and chromium VI. The carcinogen with the highest level of over-exposure were in the order of formaldehyde, benzene, ethylene oxide and asbestos. Fabricated metal product manufacturing industry were found to be most vulnerable against carcinogen with 11.1% of them exceeding carcinogen KOEL followed by electronic components manufacturing industry (8.3%), chemical products manufacturing industry (6.3%), and electrical equipments manufacturing industry (4.9%). The industry employing less than 50 workers had the highest percentage of exceeding carcinogen KOEL with 52.8%. The result also showed that strengthening KOEL for benzene and asbestos helped reduce the level of carcinogen over-exposure. Based on these results, strengthening the KOEL or new regulation turned out to help reduce the carcinogen over-exposure level. Benzene, ethylene oxide and chromium VI were the most frequently over-exposed carcinogen with the highest level. Therefore, these chemicals need to be regulated with a highest priority to improve the workplace environment. The results also show that the small-sized industries employing less than 50 workers was the most vulnerable against carcinogen exposures. Therefore, more government support are needed for these small-sized industries to help them to improve their workplace environment.