• 한국주조공학회지
• /
• 제41권2호
• /
• pp.132-138
• /
• 2021

본 연구에서는 16t/h 저주파 유도 용해로에서 주철의 용해 시, 생압고철(Press Scrap)과 파쇄고철(Shredded Scrap)을 사용함에 따른 에너지 원단위(Power Basic Unit)를 비교하였다. 생압고철 대신 파쇄고철을 장입하면, 에너지 원단위가 약 5% 향상되는 것으로 확인되었다. 고철의 형상, 크기에 따른 에너지 측면 특징과 용해로 크기의 영향을 고찰하였다. 마지막으로 본 기술의 활용성을 제고하기 위한 전략을 제안하였다.

• Journal of Electrochemical Science and Technology
• /
• 제14권3호
• /
• pp.222-230
• /
• 2023

Capacitive deionization of saline water is one of the most promising water purification technologies due to its high energy efficiency and cost-effectiveness. This study synthesizes porous carbon composites composed of reduced graphene oxide (rGO) and activated carbon (AC) with various rGO/AC ratios using a facile chemical method. Surface characterization of the rGO/AC composites shows a successful chemical reduction of GO to rGO and incorporation of AC into rGO. The optimized rGO/AC composite electrode exhibits a specific capacitance of ~243 F g^-1 in a 1 M NaCl solution. The galvanostatic charging-discharging test shows excellent reversible cycles, with a slight shortening in the cycle time from the ~260^th to the 530^th cycle. Various monovalent sodium salts (NaF, NaCl, NaBr, and NaI) and chloride salts (LiCl, NaCl, KCl, and CsCl) are deionized with the rGO/AC electrode pairs at a cell voltage of 1.3 V. Among them, NaI shows the highest specific adsorption capacity of ~22.2 mg g^-1. Detailed surface characterization and electrochemical analyses are conducted.

• 한국수소및신에너지학회논문집
• /
• 제35권1호
• /
• pp.75-82
• /
• 2024

In this study, design parameter exploration based on finite element analysis was performed to find the optimal shape of bellows, the key component of compressor-embedded refueling tank for a newly developed hydrogen refueling station capable of high-pressure charging above 900 bar. In the design parametric study, the design variables took into account the bellows shapes such as contour radius and span spacing, and the response factors were set to the maximum stress and the gap in the contact direction. In the shape design of the compressor bellows for hydrogen refueling station considered in this study, it was found that adjusting the contour span is an appropriate design method to improve the compression performance and structural safety. From the selection of optimal design, the maximum stress was reduced to 49% compared to the initial design without exceeding the material yield stress.

• 한국융합학회논문지
• /
• 제13권4호
• /
• pp.331-337
• /
• 2022

전기자동차용 배터리 하우징 소재로 사용되고 있는 금속 소재에서 경량소재로 대체하기 위한 열가소성복합재료를 제조하였다. 매트릭스 소재는 고분자 소재인 나일론 6를 사용 하였으며 방열 성능을 부여하기 위해 열전도도가 높은 Boron Nitrate(BN)를 사용하였다. 동일한 필러의 함량 및 입자 크기에 따른 열전도성 고분자 복합재료의 방열 특성을 분석하였다. 필러의 함량이 증가할수록 열전도도 값이 증가하였으며, 입자크기가 60~70㎛인 BN의 함량이 50%인 복합재료의 경우 1.4W/mK 이상 열전도도를 나타내었다. 입자 크기가 클수록 입자 간 계면 접촉면이 넓어져 Thermal path가 이루어짐을 확인하였다. 제조된 열전도성 고분자복합재료를 이용하여 배터리 하우징을 제작하였으며 셀의 충방전 동안 온도 변화를 관찰하여 배터리 하우징의 대체 소재로서의 가능성을 확인하였다.

• 전기화학회지
• /
• 제3권2호
• /
• pp.90-95
• /
• 2000

겔형 VRLA전지의 파손방식을 조사하기 위하여 $100\%$ 방전심도에서 5시간율 전류로 충방전 수명시험을 하였다. 정전압 충전방식을 사용하여 충전전압을 2.40V와 2.50V로 하였을 때 1,000회 이상의 수명을 나타내었으며, 전지의 무게변화를 측정한 결과 각각 426.4g과 391.2g의 전해액이 감소하였다 2.50V로 충전한 전지가 우수한 수명특성을 나타내었으며, 전해액 손실량이 충전계수와 비례하는 것을 알 수 있었다 1,000회의 충방전 수명시험을 한 전지의 양극기판에는 약 $50{\mu}m$의 부식층이 관찰되었고, 활성물질의 미세구조는 크게 변하였다. 양극판의 파손방식은 활물질 탈락이며, 전해액 손실이 방전용량 감소의 원인인 것을 알 수 있었다.

• 한국전기전자재료학회논문지
• /
• 제30권7호
• /
• pp.407-412
• /
• 2017

This paper introduces a biocompatible packaging system for implantable medical device having a hermetic sealing, such that a perfect physical and chemical isolation between electronic medical system and human body (including tissue, body fluids, etc.) is obtained. The hermetic packaging includes an electronic MEMS pressure sensor, power charging system, and bluetooth communication system to wirelessly measure variation of capacitance. The packaging was acquired by Quartz direct bonding and $CO_2$ laser welding, with a size of width $ 6cm{\times}length\;10cm{\times}lheight\;3cm$. Hermetic sealing of the packaged system was tested by changing the pressure in a hermetic chamber using a precision pressure controller, from atmospheric to 900 mmHg. We found that the packaged system retained the same count or capacitance values with sensor 1 - 25,500, sensor 2 - 26,000, and sensor 3 - 20,800, at atmospheric as well as 900 mmHg pressure for 5 hours. This result shows that the packaging method has perfect hermetic sealing in any environment of the human body pressure.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
• /
• pp.254.2-254.2
• /
• 2014

The Transmission Fourier Transform Infrared spectroscopy (FTIR) of SiOx charge storage layer with the richest silicon content showed an assignment at peaks around 2000~2300 cm-1. It indicated that the existence of many silicon phases and defect sources in the matrix of the SiOx films. The total hysteresis width is the sum of the flat band voltage shift (${\Delta}VFB$) due to electron and hole charging. At the range voltage sweep of ${\pm}15V$, the ${\Delta}VFB$ values increase of 0.57 V, 1.71 V, and 13.56 V with 1/2, 2/1, and 6/1 samples, respectively. When we increase the gas ratio of SiH4/N2O, a lot of defects appeared in charge storage layer, more electrons and holes are charged and the memory window also increases. The best retention are obtained at sample with the ratio SiH4/N2O=6/1 with 82.31% (3.49V) after 103s and 70.75% after 10 years. The high charge storage in 6/1 device could arise from the large amount of silicon phases and defect sources in the storage material with SiOx material. Therefore, in the programming/erasing (P/E) process, the Si-rich SiOx charge-trapping layer with SiH4/N2O gas flow ratio=6/1 easily grasps electrons and holds them, and hence, increases the P/E speed and the memory window. This is very useful for a trapping layer, especially in the low-voltage operation of non-volatile memory devices.

• 한국자동차공학회논문집
• /
• 제23권2호
• /
• pp.199-207
• /
• 2015

Solid materials of ammonia sources with SCR have been considered for the application of lean NOx reduction in automobile industry, to overcome complex problems of liquid urea based SCR. These solid materials produce ammonia gas directly with proper heating and can be packaged by compact size, because of high volumetric ammonia density. Among ammonium salts and metal ammine chlorides, calcium ammine chloride was focused on this paper due to low decomposition temperature. In order to make calcium ammine chloride in lab-scale, simple reactor and glove box was designed and built with ammonium gas tank, regulator, and sensors. Basic test conditions of charging ammonia gas to anhydrous calcium chloride are chosen from equilibrium vapor pressure by Van't Hoff plot based on thermodynamic properties of materials. Synthetic method of calcium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%) from simple weight calculations which were confirmed by IC. Also, lab-made calcium ammine chloride were analyzed by TGA and DSC to clarify decomposition step in the equations of chemical reaction. To understand material characteristics for lab-made calcium ammine chloride, DA, XRD and FT-IR analysis were performed with published data of literature. From analytical results, water content in lab-made calcium ammine chloride can be discovered and new test procedures of water removal were proposed.

• 한국지반신소재학회논문집
• /
• 제13권2호
• /
• pp.21-29
• /
• 2014

시멘트 페이스트를 사용한 충전재는 현장 시공 시 실제 주입량이 지나치게 커서 비효율적이며, 설계기준에 비해 과도한 강도를 발현하여 시멘트 사용에 따른 환경성 문제를 지니고 있다. 이에 대한 대안으로 기존의 시멘트 페이스트를 대체함과 동시에 경제성과 환경성을 고려하여 현장에서 발생되는 현장토를 충전재로 재활용한 고화처리 충전재의 현장 적용성을 평가하였다. 또한, 현장 재하시험 및 하중전이 계측을 수행하여 말뚝의 축방향 지지거동을 분석하였다. 그 결과 고화처리 충전재는 기존 시멘트 페이스트에 비해 유동성과 재료분리저항성 및 부착강도에서는 좋은 성능을 발휘하였고, 동재하시험에 의한 주면마찰력은 다소 떨어졌으나 수평지지력 및 인발력 등은 유사하였고, 설계지지력 이상 도출되어 기준에 부합된 결과를 나타내었다.

• 전기학회논문지
• /
• 제66권2호
• /
• pp.357-362
• /
• 2017

Among the lithium metal oxides for asymmetric hybrid supercapacitor, $Li_4Ti_5O_{12}(LTO)$ is an emerging electrode material as zero-stain material in volume change during the with the charging and discharging processes. The pulverized LTO powder was observed to show the enhanced capacity from 120 mAh/g to 156 mAh/g at C-rate (10, 100 C). Hybrid supercapacitor module(48V, 416F) was fabricated using an asymmetric hybrid capacitor with a capacitance of 7500F. As a result of the measurement of C-rate characteristics, the module shows that the discharge time is drastically reduced at more than 50C, and the ESR and voltage drop characteristics are increased. The energy density and power density were reduced under high C-rate conditions. When designing asymmetric hybrid supercapacitor module, the C-rate and ESR should be considered As a result of measuring the 5 kw UPS, it was discharged at the current of 116A~170A during the discharge in the voltage range of 48V~30V, and the compensation time at discharge was measured to be about 33.2s. Experimental results show that it can be applied to applications related to stabilization of power quality by applying hybrid supercapacitor module.