• 제목/요약/키워드: Charge-Transfer

검색결과 1,027건 처리시간 0.026초

차세대 이차전지용 아연 이온 이차전지 소재 연구 개발 동향 (Recent Research Trend of Zinc-ion Secondary Battery Materials for Next Generation Batterie)

  • 조정근;김재국
    • 세라미스트
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    • 제21권4호
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    • pp.312-330
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    • 2018
  • Energy storage/conversion has become crucial not only to meet the present energy demand but also more importantly to sustain the modern society. Particularly, electrical energy storage is critical not only to support electronic, vehicular and load-levelling applications but also to efficiently commercialize renewable energy resources such as solar and wind. While Li-ion batteries are being intensely researched for electric vehicle applications, there is a pressing need to seek for new battery chemistries aimed at stationary storage systems. In this aspect, Zn-ion batteries offer a viable option to be utilized for high energy and power density applications since every intercalated Zn-ion yields a concurrent charge transfer of two electrons and thereby high theoretical capacities can be realized. Furthermore, the simplicity of fabrication under open-air conditions combined with the abundant and less toxic zinc element makes aqueous Zn-ion batteries one of the most economical, safe and green energy storage technologies with prospective use for stationary grid storage applications. Also, Zn-ion batteries are very safe for next-generation technologies based on flexible, roll-up, wearable implantable devices the portable electronics market. Following this advantages, a wide range of approaches and materials, namely, cathodes, anodes and electrolytes have been investigated for Zn-ion batteries applications to date. Herein, we review the progresses and major advancements related to aqueous. Zn-ion batteries, facilitating energy storage/conversion via $Zn^{2+}$ (de)intercalation mechanism.

열교환기 내장형 어큐뮬레이터가 냉동시스템의 성능에 미치는 영향에 관한 연구 (Effects of Accumulator Heat Exchanger on the Performance of a Refrigeration System)

  • 강훈;최광민;박차식;김용찬
    • 설비공학논문집
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    • 제18권5호
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    • pp.418-425
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    • 2006
  • An AHX (Accumulator Heat exchanger) consists of a commercial accumulator and an inner heat exchanger located inside of the accumulator. The AHX is used in multi air-conditioners to assure that liquid-phase refrigerant enters into the expansion device. This purpose is achieved by heat transfer between the refrigerant leaving the evaporator and the refrigerant leaving the condenser. In this study, the effects of AHX on the performance of a refrigeration system using R-22 were measured and the test results were analyzed. The operating characteristics of the refrigeration system with the AHX are considerably different from those without the AHX. Therefore, it is required to determine optimum refrigerant charge and optimum operating conditions when the AHX is used in the refrigeration system having a constant flow-area expansion device such as capillary tube.

IPA를 이용한 직장멘토링에서 멘토의 역할 분석 : 멘토와 멘티의 관점에서 (Analysis of Mentors' Roles using IPA in the Workplace Mentoring : From the Perspective of Mentors and Mentees)

  • 김재경;최방길;최일영;손유경
    • 한국IT서비스학회지
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    • 제20권4호
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    • pp.69-80
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    • 2021
  • Many studies have discussed the effectiveness of mentoring from a mentor or mentee perspective. However, it is is necessary to deeply understand the formal mentoring relationship from the perspective of both the mentor and the mentee because the mentoring relationship is the interaction between the mentor and the mentee. Therefore, in this study, the mentors' role through IPA was compared and analyzed from the perspective of mentors and mentees. A survey was conducted on 376 employees of the financial bank, and the managers in charge of the company's official workplace mentoring and employees who participated in the mentoring program were interviewed. As a result of the analysis, mentors are more satisfied with the rewarding experience, while mentees are satisfied with commitment, and organizational ascendency and impact. In addition, mentees judge that "Coach", "Provides support", "Provides vision & widens horizons", "Broaden experience", "Cooperation", "Motivates", "Networking ability", "Provide cross-functional information", "Role model", "Share credit", "Teacher", and "Transfer skills, leadership, & technology" are important as mentor's roles are important. Therefore, in order to foster mentors for effective workplace mentoring, it is necessary to educate the mentor in advance about the mentors' role that the mentee considers to be important.

Mobile Cloud System based on EMRA for Inbody Data

  • Lee, Jong-Sub;Moon, Seok-Jae
    • International Journal of Advanced Culture Technology
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    • 제9권3호
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    • pp.327-333
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    • 2021
  • Inbody is a tool for measuring health information with high reliability and accuracy to analyze body composition. Unlike the existing method of storing/processing and outputting data on the server side, the health information generated by InBody requires accurate support for health sharing and data analysis services using mobile devices. However, in the process of transmitting body composition measurement information to a mobile service, a problem may occur in data transmission/reception processing. The reason for this is that, since the network network in the cloud environment is used, if the connection is cut off or the connection is changed, it is necessary to provide a global service, not a temporary area, focusing on the mobility of InBody information. In addition, since InBody information is transmitted to mobile devices, a standard schema should be defined in the mobile cloud environment to enable information transfer between standardized InBody data and mobile devices. We propose a mobile cloud system using EMRA(Extended Metadata Registry Access) in which a mobile device processes and transmits body data generated in the inbody and manages the data of each local organization with a standard schema. The proposed system processes the data generated in InBody and converts it into a standard schema using EMRA so that standardized data can be transmitted. In addition, even when the mobile device moves through the area, the coordinator subsystem is in charge of providing access services. In addition, EMRA is applied to the collision problem due to schema heterogeneity occurring in the process of accessing data generated in InBody.

Morphology-Controlled WO3 and WS2 Nanocrystals for Improved Cycling Performance of Lithium Ion Batteries

  • Lim, Young Rok;Ko, Yunseok;Park, Jeunghee;Cho, Won Il;Lim, Soo A;Cha, EunHee
    • Journal of Electrochemical Science and Technology
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    • 제10권1호
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    • pp.89-97
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    • 2019
  • As a promising candidate for anode materials in lithium ion battery (LIB), tungsten trioxide ($WO_3$) and tungsten disulfide ($WS_2$) nanocrystals were synthesized, and their electrochemical properties were comprehensibly studied using a half cell. One-dimensional $WO_3$ nanowires with uniform diameter of 10 nm were synthesized by hydrothermal method, and two-dimensional (2D) $WS_2$ nanosheets by unique gas phase sulfurization of $WO_3$ using $H_2S$. $WS_2$ nanosheets exhibits uniformly 10 nm thickness. The $WO_3$ nanowires and $WS_2$ nanosheets showed maximum capacities of 552 and $633mA\;h\;g^{-1}$, respectively, after 100 cycles. Especially, the capacity of $WS_2$ is significantly larger than the theoretical capacity ($433mA\;h\;g^{-1}$). We also examined the cycling performance using a larger size $WO_3$ and $WS_2$ nanocrystals, showing that the smaller size plays an important role in enhancing the capacity of LIBs. The larger capacity of $WS_2$ nanosheets than the theoretical value is ascribed to the lower charge transfer resistance of 2D nanostructures.

Electrochemical Studies on Corrosion Inhibition Behaviour of Synthesised 2-acetylpyridine 4-ethyl-3-thiosemicarbazone and Its Tin(IV) Complex for Mild Steel in 1 M HCl Solution

  • Hazani, Nur Nadira;Mohd, Yusairie;Ghazali, Sheikh Ahmad Izaddin Sheikh Mohd;Farina, Yang;Dzulkifli, Nur Nadia
    • Journal of Electrochemical Science and Technology
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    • 제10권1호
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    • pp.29-36
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    • 2019
  • Corrosion inhibition by synthesised ligand, 2-acetylpyridine 4-ethyl-3-thiosemicarbazone (HAcETSc) and its tin(IV) complex, dichlorobutyltin(IV) 2-acetylpyridine 4-ethyl-3-thiosemicarbazone ($Sn(HAcETSc)BuCl_2$) on mild steel in 1 M hydrochloric acid (HCl) was studied using weight loss measurement, potentiodynamic polarisation, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). The inhibition efficiency increases by increasing the inhibitor concentrations. The polarisation study showed that both synthesised compounds were mixed type inhibitors. The electrochemical impedance study showed that the presence of inhibitors caused the charge transfer resistance to increase as the concentration of inhibitors increased. The adsorption of these compounds on mild steel surface was found to obey Langmuir's adsorption isotherm with the free energy of adsorption ${\Delta}G{^o}_{ads}$ of -3.7 kJ/mol and -7.7 kJ/mol for ligand and complex respectively, indicating physisorption interaction between the inhibitors and 1 M HCl solution.

Tuning of Electro-optical Properties of Nano-structured SnO2:Ga Powders in a Micro Drop Fluidized Reactor

  • Lim, Dae Ho;Yang, Si Woo;Yoo, Dong June;Lee, Chan Gi;Kang, Yong
    • Korean Chemical Engineering Research
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    • 제57권2호
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    • pp.259-266
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    • 2019
  • Tuning of electro-optical properties of nano-structured $SnO_2:Ga$ powders in a micro drop fluidized reactor (MDFR) was highly effective to enhance the activities of powders to be used as sensor materials. The tuning was conducted continuously in a facile one-step process during the formation of powders. The microscopic hydrodynamic forces affected the band gap structure and charge transfer of $SnO_2:Ga$ powders through the oxygen and interfacial tin vacancies by providing plausible pyro-hydraulic conditions, which resulted in the decrease in the electrical resistance of the materials. The analyses of room-temperature photoluminescence (PL) spectra and FT-IR exhibited that the tuning could improve the surface activities of $SnO_2:Ga$ powders by adjusting the excitation as well as separation of electrons and holes, thus maximizing the oxygen vacancies at the surface of the powders. The scheme of photocatalytic mechanism of $SnO_2:Ga$ powders was also discussed.

Electrodeposition of SnO2-doped ZnO Films onto FTO Glass

  • Yoo, Hyeonseok;Park, Jiyoung;Kim, Yong-Tae;Kim, Sunkyu;Choi, Jinsub
    • Journal of Electrochemical Science and Technology
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    • 제10권1호
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    • pp.61-68
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    • 2019
  • Well aligned $SnO_2$-doped ZnO nanorods were prepared by single step or 2-step electrochemical depositions in a mixture solution of zinc nitrate hexahydrate, ammonium hydroxide solution and 0.1 M tin chloride pentahydrate. The morphologies of electrochemically deposited $SnO_2$-doped ZnO were transformed from plain (or network) structures at low reduction potential to needles on hills at high reduction potential. Well aligned ZnO was prepared at intermediate potential ranges. Reduction reagent and a high concentration of Zn precursor were required to fabricate $SnO_2$ doped ZnO nanorods. When compared to results obtained by single step electrochemical deposition, 2-step electrochemical deposition produced a much higher density of nanorods, which was ascribed to less potential being required for nucleation of nanorods by the second-step electrochemical deposition because the surface was activated in the first-step. Mechanisms of $SnO_2$ doped ZnO nanorods prepared at single step or 2-step was described in terms of applied potential ranges and mass-/charge- limited transfer.

비행자료 처리시스템 분석 (The Analysis of Flight Data Processing System)

  • 김도우;오승희;이덕규;이성현;한종욱
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2009년도 춘계학술대회
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    • pp.785-788
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    • 2009
  • 비행자료 처리시스템은 항공기 관제를 위한 모든 비행관련 자료를 처리하고 관리하며 항적 모델링을 하기 위한 시스템으로 항공관제용 통합 정보처리 시스템의 핵심 기능을 수행하는 역할을 담당한다. 항공기의 안전한 운항을 위해서는 비행자료 처리를 통해 항공교통관제기관간의 정보전달과 교환은 필수적인 요소이다. 따라서 본 논문에서는 비행자료 처리시스템의 개발을 위해 기능을 분석하고, 설계 시 필요한 고려사항을 살펴보고자 한다.

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Ce $L_Ⅲ$-edge X-ray Absorption Spectroscopic Studies on the Tetrameric Ce-polyoxyhydroxy Cation Intercalated Aluminosilicate

  • 윤주병;황성호;김동국;강성구;최진호
    • Bulletin of the Korean Chemical Society
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    • 제21권3호
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    • pp.305-309
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    • 2000
  • The cerium ion intercalated aluminosilicate was prepared by ion exchange reaction between $Na^+$ in montmorillonite and $Ce^{+4}$ in aqueous solution. The X-ray absorption near edge structrure(XANES) analyses indicate that the $Ce^{+4}$ ions are partially reduced to the $Ce^{+3}$ ones during the intercalation into layered aluminosilicate due to a charge transfer between host and intercalant. From the EXAFS analysis, two different (Ce-O) bonding pairs could be characterized with the distances and coordination numbers of 2.31 $({\pm}0.02){\AA}$ ${\times}$ 8.2 $({\pm}1.5)$ and 2.66 $({\pm}0.02){\AA}$ ${\times}$ 2.7 $({\pm}1.0)$, respectively, with the oxygen atoms as the first nearest neighbor, and two (Ce-Ce) pairs at 3.78 ${\AA}$ as the second neighbor. It is therefore concluded that the most probable Ce-species stabilized in the interlayer space of aluminosilicate after the intercalation is the tetrameric Ce-polyoxy/hydorxy cations with the mixed valent state of 0.75 $Ce^{+4}$.0.25 $Ce^{+3}$.