• Bulletin of the Korean Chemical Society
• /
• v.16 no.5
• /
• pp.389-391
• /
• 1995

• Bulletin of the Korean Chemical Society
• /
• v.20 no.12
• /
• pp.1509-1512
• /
• 1999

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2004.07b
• /
• pp.878-881
• /
• 2004

When it converted solar energy or light energy into chemical energy, it studied the electric charge transfer property of the viologen which is used widely as the electron acceptor for the electric charge delivery mediation of the devices. It was formed monolayer in QCM by self-assembled viologen. The absorbed quantities of viologen's electron through peak current and to analyze the electron transfer property of viologen in redox reaction made experiments in cyclic voltammetry among the electrochemical process. It studied the electron transfer relation of viologen from changing the anion in 0.1M NaCl and $NaClO_4$ electrolyte and the interrelation between scan rate and peak current when scan rate increased twice.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2006.05a
• /
• pp.63-64
• /
• 2006

본 연구에서는 광에너지를 화학적인 에너지로 변환할 때, 디바이스의 전하전달 매개를 위한 electron transfer mediator로서 널리 이용되는 Viologen이 자기조립화된 수정진동자률 전기화학법의 하나인 순환전압전류법(Cyclic Voltammetry)을 이용하여 산화 환원 반응 (redox reaction) 특성과 주사속도와 피크전류와의 상관관계를 분석하였다. 먼저 수정진동자를 친수 처리한 후, 메탄올 용액과 아세토니트릴 용액을 섞은 용매에 Viologen 분자를 자기조립 (self-assembly)하여, 전해질 용액의 농도 변화에 따른 산화 환원반응 특성과 피크전류의 값을 측정하였다 주사 속도를 2 배씩 증가하여 피크전류와의 상관관계를 조사한 결과, 선형적인 증가를 보였으며, 이를 통해 가역적인 반응(reversible reaction)이 일어났음을 확인할 수 있었다. 또한, 산화 환원 반응과 동시에 측정된 수정진동자의 공진 주파수(resonant frequency) 변화로부터 전하이동(charge transfer) 특성에 의해 반응에 참가한 이온의 질량을 알 수 있었다.

• Proceedings of the Optical Society of Korea Conference
• /
• 1995.06a
• /
• pp.127-137
• /
• 1995

Anomalously large real space charge transfer through thick barries in GaAs asymmetric double quantum wells is studied by photoluminesence exitation. This inter-well excitonic transfer is very large when the barrier is the Al0.3Ga0.7As alloy, but disappears when the barrier is GaAs/AlAs digital alloy with an equivalent Al concentration of 0.28. These resilts combined with observed x and barrier thickness depence suggest that the spatial fluctuation of the atomic arrangment of Ga and Al in the alloy may be responsible for this transfer. This picture is supported by the quantum mechanical calculation in three dimensions which takes into account the side fluctuation effects.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.14 no.8
• /
• pp.617-625
• /
• 2002

In this study, effects of refrigerant and oil charges on the performance of a refrigeration system simulating an automobile air conditioner have been experimentally investigated using R134a and PAG oil. Measurements were taken in a breadboard type refrigeration test unit with a compressor used for a commercial automobile air-conditioner under a set of condition imposed upon normally to automobile air conditioners. Both the COP and capacity decreased rapidly as the oil charge increased because of the decrease in vapor pressure of the circulating refrigerant/oil mixture. The excess oil left in the evaporator also caused heat transfer degradation resulting in a decrease in capacity and in turn COP. It was found that there is an optimum refrigerant charge at which the COP becomes the maximum. Below this optimum charge, both the capacity and COP increased as the refrigerant charge increased and above the optimum charge, both of them remained almost constant. Hence, the COP seems to be the most important factor in determining the optimum refrigerant charge. When the system was undercharged, the refrigerant at the condenser exit lost subcooling and showed a sign of poor miscibility.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.36 no.11
• /
• pp.1073-1079
• /
• 2012

This study aims to experimentally investigate the heat transfer characteristics of a thermosyphon using nanofluids. A thermosyphon with three individual pipes, which share the internal volume of the evaporator section, was designed, and its performance was tested for various charge amounts, input powers of the evaporator section's heater, and concentrations of working fluids. The optimized charge amount of the thermosyphon using distilled water was 30%, and the thermal resistance of the thermosyphon with $TiO_2$ nanofluid was 18.1% lower than that with Ag nanofluid. In addition, the heat transfer performance of the thermosyphon with $TiO_2-1%$ was optimized at an input power of 300 W at the evaporator section's heater and a charge amount of 30%.

• Journal of the Institute of Electronics Engineers of Korea SD
• /
• v.45 no.5
• /
• pp.50-57
• /
• 2008

In this paper, a high-efficiency charge pump for use in CMOS image sensor(CIS) is proposed. The proposed charge pump pursues high pumping efficiency by minimizing the switching and reversion losses by taking advantage of operation characteristics of CIS. That is, the proposed charge pump minimizes the switching loss by dynamically controlling the size of clock driver, pumping capacitor, and charge transfer switch based on the operation phase of CIS pixel sensor. The charge pump also minimizes the reversion loss by guaranteeing a sufficient non-overlapping period of local clocks using a tri-state local clock driver adapting the schmitt trigger. Comparison results using a 0.13-um CMOS process technology indicate that the proposed charge pump achieves up to 49.1% reduction on power consumption under no loading current condition as compared to conventional charge pump. They also indicate that the charge pump provides 19.0% reduction on power consumption under the maximum loading current condition.

• Journal of the Korean Chemical Society
• /
• v.36 no.2
• /
• pp.191-196
• /
• 1992

Reaction of N,N-dimethylaniline(N,N-DMA) and iodine in $CHCl_3,\;CH_2Cl_2 : CHCl_3$(1:1), $CH_2Cl_2$(1:1), and CH2Cl2 has been studied kinetically by using conductivity method. Pseudo first-order rate constants ($k_{obs}$) and second-order rate constants ($k_{obs}$/[N,N-DMA]) are dependent on the N,N-DMA concentration. Second-order rate constants obtained were decreased with increasing N,N-DMA concentration. We analysed these results on the basis of formation of charge transfer complex as a reaction intermediate. From the construction of reaction scheme and activation parameters for the formation and transformation of charge transfer complex. The equilibrium constants decreased when the dielectric constant of solvent was increased, and the value is 1.9${\sim}$4.2$M^{-1}$. The rate of transformation are markedly affected by the solvent polarity.${\Delta}H^{\neq}$ is 6.3-12.6kJ/mol, and ${\Delta}S^{\neq}$ is large negative value of -234J/mol K.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
• /
• 2005.11a
• /
• pp.363-365
• /
• 2005

It describes a design analysis and test results of an energy transfer system which consists of two 0.5 MJ superconducting coil and three Inverter-Converter Bridges(hereinafter called ICB). A point of design is to satisfy the required stored energy capacity rather than magnetic field density with minimum energy transfer time using the calculation results of state-space averaging methods instead of Fourier series. It is proven that the considered methods are effectively through system experiments.