• Bulletin of the Korean Chemical Society
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• v.6 no.2
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• pp.79-86
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• 1985

The complete neglect of differential overlap (CNDO/2) approximate wavefunctions have been applied to select the preferred signs for the dipole moment derivatives of SiH$_{4}$ and SiD$_{4}$ in conjunction with the experimental alternatives. The apparent sign discrepancy from earlier report has been identified. The effective atomic charge for hydrogen was found to be X$_{H}$/e = 0.229, more than two times larger in comparison with the values of typical hydrocarbons like CH$_{4}$. The anomalously large effective hydrogen charge was interpreted based on a quantum mechanical model as well as the value of atom anisotropy relative to effective atomic charge.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2003.10a
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• pp.183-186
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• 2003

A finite element-based, integrated process model is presented for a three dimensional, coupled analysis of the thermal and mechanical behavior of type 304 stainless slab during hot charge rolling (HCR) and cold charge rolling (CCR) processes. The validity of the proposed model is examined through comparison with measurements. The susceptibility on micro-crack initiation or propagation due to the thermal stress in these two different process conditions was examined. The model's capability of revealing the effect of diverse process parameters is demonstrated through a series of process simulation.

• Nuclear Engineering and Technology
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• v.41 no.5
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• pp.723-728
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• 2009

The response property of the CZT detector ($5{\times}5{\times}5\;mm^3$), widely used in photon spectroscopy, was evaluated by considering the charge collection efficiency, which depends on the interaction position of incident radiation, A quantitative analysis of the energy spectra obtained from the CZT detector was also performed to investigate the tail effect at the low energy side of the full energy peak. The collection efficiency of electrons and holes to the two electrodes (i.e., cathode and anode) was calculated from the Hecht equation, and radiation transport analysis was performed by two Monte Carlo codes, Geant4 and MCNPX. The radiation source was assumed to be 59.5 keV gamma rays emitted from a $^{241}Am$ source into the cathode surface of this detector, and the detector was assumed to be biased to 500 V between the two electrodes. Through the comparison of the results between the Geant4 calculation considering the charge collection efficiency and the ideal case from MCNPX, an pronounced difference of 4 keV was found in the full energy peak position. The tail effect at the low energy side of the full energy peak was confirmed to be caused by the collection efficiency of electrons and holes. In more detail, it was shown that the tail height caused by the charge collection efficiency went up to 1000 times the pulse height in the same energy bin at the calculation without considering the charge collection efficiency. It is, therefore, apparent that research considering the charge collection efficiency is necessary in order to properly analyze the characteristics of CZT detectors.

• Korean Journal of Soil Science and Fertilizer
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• v.37 no.3
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• pp.136-142
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• 2004

Though diverse methods have been developed to characterize surface charge of soils and pure minerals, there is not still a reliable and rapid method for differentiating permanent charge from variable charge. Thus, it is needed to find out a reasonable method for measuring permanent and pH-dependent charge of soils. In this study various methods such as Cs-adsorption method, Hybrid model, $NH_4{^+}$-adsorption method and theoretical calculation of lattice charge were applied to measure permanent charge of montmorillonite and illite. Calculated lattice charge was $71.82cmol\;kg^{-1}$ and $14.20cmol\;kg^{-1}$ for montmorillonite and illite, respectively. The permanent charge measured by Cs-adsorption method were $78.23cmol\;kg^{-1}$ and $11.13cmol\;kg^{-1}$ for montmorillonite and illite, respectively. The differences between the values measured by Cs-adsorption method and the calculated lattice charge were not different significantly as $6.41cmol\;kg^{-1}$ and $3.07cmol\;kg^{-1}$. But, Hybrid model showed an underestimated values when applied to clay minerals with predominant amounts of permanent charge. The experimental results showed Cs-adsorption method was more reasonable for permanent charge measurement than the Hybrid model for illlte or montmorillonitetype clays.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.04c
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• pp.91-97
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• 2008

Polymers submitted to thermo/electrical stress suffer from ageing that can drastically affect their functional behaviour. Understanding the physico/chemical processes at play during ageing and defining transport regimes in which these mechanisms start to be critical is therefore a prime goal to prevent degradation and to develop new formulation or new materials with improved properties. It is thought that a way to define these critical regimes is to investigate under which conditions (in terms of stress parameters) light is generated in the material by electroluminescence (EL). This can happen through impact excitation/ionization involving hot carriers or upon bi-polar charge recombination (a definition that excludes light from partial discharges, which would sign an advanced stage in the degradation process). After a brief review of the EL phenomenology under DC, we introduce a numerical model of charge transport postulating a recombination controlled electroluminescence. The model output is critically evaluated with special emphasize on the comparison between simulated and experimental light emission. Finally, we comment some open questions and perspectives.

• Journal of Mechanical Science and Technology
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• v.16 no.9
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• pp.1102-1111
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• 2002

The study focuses on the heat transfer performance of two-phase closed thermosyphons with plain copper tube and tubes having 50, 60, 70, 80, 90 internal grooves. Three different working fluids(distilled water, methanol, ethanol) are used with various volumetric liquid fill charge ratio from 10 to 40%. Additional experimental parameters such as operating temperature and inclination angle of zero to 90 degrees are used for the comparison of heat transfer performance of the thermosyphon. Condensation and boiling heat transfer coefficients, heat flux are obtained using experimental data for each case of specific parameter. The experimental results are assessed and compared with existing correlations. The results show that working fluids, liquid fill charge ratio, number of grooves and inclination angle are very important factors for the operation of thermosyphons. The relatively high rate of heat transfer is achieved when the thermosyphon with internal grooves is used compared to that with plain tube. The optimum liquid fill charge ratio for the best heat transfer performance lies between 25% and 30%. The range of the optimum inclination angle for this study is 20$^{\circ}$～30$^{\circ}$ from the horizontal position.

• Journal of environmental and Sanitary engineering
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• v.13 no.1
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• pp.82-90
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• 1998

The study was carried out to investigate on the response of environmental sanitation problems in action of the volume based waste charge system in Seoul. The responses from the 396 persons who dwelled in Seoul was stimulatively answered, this system was considered as a successful one 69.6% of total answers, but little portion (21.2%) of those was unknown on the mean of this system. And we knew that this system was need to the communication and education through the press media about this one. After the action of the volume based waste charge system, the volume of refuse discharged in a day was decreased 30-50% than before. In the problems of environmental sanitation after this system, the number of sanitary insect(cockroach etc) and rat was decreased, also the production of order and dust caused by refuse was decreased in comparison with those before. This results were considered that the Separate Collection should be perfectly performed. In response, the regular envelope of refuge was serious problems, the improvement for this one was demanded, The kind of difficult refuse treated was waste foodstuffs> electric products> rubbers> furniture> bottles, cans>papers, pulps etc. and the next proposal for this system should be prepared. Conclusively, the volume based waste charge system should be remarkable system in terms of resources recycling as well as wastes reduction. Above all in order to conform this system the separate collection system should be systematically performed, the next improvable proposal of the detailed methods in this system should be prepared.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.9
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• pp.1217-1228
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• 1998

In order to elucidate the operational characteristics of rotating heat pipes, the internal flow patterns and heat transfer performance are investigated. Flow patterns and its transition are studied with various rotational speeds by visualizing flows established inside a rotating tube. To verify those results of analysis, 2 heat pipes of the same geometries but fill charge rates of 7, 30% were manufactured and submitted to operating tests. Comparison of experimental results on heat transfer rate show a fairly good agreement with the analytical results. The analysis reveals that the optimum charge ratio is ranged in 4~7% depending on the quantity of thermal loads. but the heat pipe with 7% of fill charge ratio reached dry-out limitation at heat flux of $q^{{\prime}{\prime}}=6.2kW/m^2$ lower than that of analytic results. Transition of flow regime was well related to the correlation by Semena & Khmelev on transient centrifugal Froude Number Frc. But hysteresis phenomenon was observed in transition of flow regime, when the rotational speed was stepwisely changed in the way to undergo 1 cycle.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.32 no.2
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• pp.133-140
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• 2019

In this paper, the penetration process of Shaped charge jet(SCJ) was simulated through finite element analysis to obtain physical quantities such as jet incidence velocity, penetration rate, and penetration increment. As a result of applying these physical quantities to the hydrodynamic theory, it was confirmed that the penetration efficiency of the jet with a high incident velocity is higher than that of the following slow jet. This efficiency decreased sharply when the jet was slower than the hydrodynamic limit(HL). On the other hand, the comparison of penetration increment and jet consumption over time showed that the length extension effect should be considered for SCJ's theoretical penetration analysis.

• Journal of the Korea Institute of Military Science and Technology
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• v.18 no.5
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• pp.574-581
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• 2015

In this paper, the effect of high voltage current pulse against shaped charge jet was analyzed through the visualization of jet behavior using flash X-ray and comparison of depth of penetration(DOP) into RHA(Rolled Homogeneous Armor) witness plates. The behavior of jet particles has been acquired using a flash X-ray equipment when current pulse was applied into the metal jet of a shaped charge(SC) warhead. Typical results such as jet breakup and radial jet dispersion, which are due to electromagnetic pressure by current pulse, have been obtained. Dozens of penetration experiments using a shaped charge with 55 mm diameter were performed according to various combinations of major parametric variables such as electrode spacing, standoff distance from SC warhead to electrode, and charge voltage. Subsequently, interrelations between major parametric variables and DOPs into RHA were analyzed.