• Title/Summary/Keyword: Charge Separation

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Development of Triboelectrostatic Separation Technique for Material Separation of EVA & PET Mixture Plastic Wastes (EVA와 PET 혼합(混合) 폐플라스틱의 재질분리(材質分離)를 위한 마찰하전형(摩擦荷電形) 정전선별(靜電選別) 기술개발(技術開發))

  • Jeon, Ho-Seok;Park, Chul-Hyun;Baek, Sang-Ho;Kim, Byoung-Gon;Kim, Hyung-Seok
    • Resources Recycling
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    • v.18 no.1
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    • pp.13-21
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    • 2009
  • A research on material separation of EVA and PET mixture plastic waste using a triboelectrostatic separator has been carried out. It was found that PP was the best charging material to give the highest charge on the surface of EVA and PET mixture plastics with an opposite polarity. Therefore, a charger of pipe line type using PP material was manufactured for separation of EVA and PET mixture plastic waste. At optimum test conditions that used PP cyclone charger developed in this study, we could separate out PET with a glade of 98.7% and a recovery of 89.7%.

Study of Aging and Performance About Separation Devices Has Been Stored (장기 보관된 분리장치의 성능 및 노화에 관한 연구)

  • Kim, Dong-seong;Jin, Hong-Sik
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.49 no.7
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    • pp.565-572
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    • 2021
  • In this study, a study on the performance and aging of explosive bolts stored for a long time among pyrotechnic mechanical devices(PMD) used as separation devices in the defense field is conducted. For this, explosive bolts that had been installed in the weapon system for about 10 years are secured. Performance and life extension test procedures are established based on the AIAA Standard and MIL-STD. Before performance evaluation, non-functional tests are performed to check whether external changes or failures occurred. Next, circuit inspection and X-ray tests are conducted to check the failure in internal circuits and structures. After that, performance test is carried out to confirm the operation of the samples that passed the non-functional test. Through this test, separation of bolt and separation time are measured, and some samples are tested after a high temperature storage test to confirm the remaining life and the possibility of extension. Finally, the remaining life and reliability are predicted based on the results of the test and the Arrhenius model to identify remaining shelf life and reliability depend on time.

Solvent Effect on the Reactions of DANSYL and BANSYL Chlorides with Substituted Pyridines

  • 성대동;강동효;장정아;박성배;류준하
    • Bulletin of the Korean Chemical Society
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    • v.19 no.5
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    • pp.561-564
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    • 1998
  • Solvent effects on the reactions of DANSYL and BANSYL chlorides with substituted pyridines have been investigated using two parameters of Taft's solvatochromic correlation and four parameters of Kirkwood-Onsager, Parker, Marcus, Hildebrand equation. The acetonitrile molecules accelerate charge separation of the reactants and stabilize the transition state. The coefficient of the solvent parameters provide a good information to predict and to analyze the reaction mechanism. The nucleophilic substitution reaction of DANSYL and BANSYL chlorides with substituted pyridines are ruled by the contribution of the change in dipole moment term and polarity-polarizability term.

A Study of the Current Status and Issues Pertaining to Vertical Separation between Infrastructure and operation of the Korean Railway (철도 상하 분리의 현상과 과제에 관한 연구)

  • Lee, Yongsang;Chung, Byunghyun
    • Journal of the Korean Society for Railway
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    • v.16 no.6
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    • pp.492-502
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    • 2013
  • This paper analyzes the outcomes of railway reform in the form of vertical separation between the infrastructure and operation since 2004 in Korea. For the analysis, the paper reviewed theoretical issues and case studies of European and Japanese railway reforms efforts. By doing this, we find the implications and a standard model, most useful. Moreover, based on this analysis, the paper reviewed the status of the accomplishment of goals, including solution to current account deficits, improvements in competitiveness and greater efficiency of operations. Finally, the paper highlighted improvement measures to address the problems of railway vertical separation in Korea. This paper suggests specifications pertaining to rail policy and control methods; tower foundation and negotiations and mentions ways to establish legal institutionalization and to secure stable rail system investments in railway in Korea.

Chiral Separation of Quinolone Antibacterial Agent by Capillary Electrophoresis (모세관 전기 영동을 이용한 퀴놀린계 항생제의 광학 이성질체 분석)

  • Gang, Dae Cheon;Jo, Seung Il;Jeong, Du Su;Choe, Gyu Seong;Kim, Yong Seong
    • Journal of the Korean Chemical Society
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    • v.46 no.5
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    • pp.412-429
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    • 2002
  • Chiral separation of gemifloxacin, an quinolone antibacterial agent, using (+)-(18-crown-6)-tetracar-boxylic acid $(18C6H_4)$ as a chiral selector was performed by capillary electrophoresis (CE). Direct analysis of quinolone antibacterial agent in body fluid is beneficial in terms of fast analysis time, multicomponent analysis. However, high con-centration of sodium ion in body fluid can prevent gemifloxacin from interacting with $18C6H_4$ since sodium ion has high affinity with $18C6H_4$ due to the strong charge interaction. Ethylenediaminetetraacetic acid (EDTA), as a chelating ligand, was added in the running buffer in order to reduce the interaction between sodium ion and the chiral selector. Increased separation efficiency and reduced migration time were observed while sodium ion exists in the sample solution at the concentration up to 150 mM.

Granulations of SiOx Nanoparticles to Improve Electrochemical Properties as a Li-Ion Battery's Anode (리튬이온전지 음극용 SiOx 나노입자의 조대화를 통한 전기화학 특성 향상)

  • Lee, Bora;Lee, Jae Young;Jang, Boyun;Kim, Joonsoo;Kim, Sung-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.1
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    • pp.70-77
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    • 2019
  • $SiO_x$ nanoparticles were granulated, and their microstructures and effects on electrochemical behaviors were investigated. In spite of the promising electrochemical performance of $SiO_x$, nanoparticles have limitations such as high surface area, low density, and difficulty in handling during slurry processing. Granulation can be one solution. In this study, pelletizing and annealing were conducted to create particles with sizes of several decades of micron. Decrease in surface area directly influences the initial charge and discharge process when granules are applied as anode materials for Li-ion batteries. Lower surface area is key to decreasing the amount of irreversible phase-formation, such as $Li_2Si_2O_5$, $Li_2SiO_3$ and $Li_4SiO_4$, as well as forming the solid electrolyte interface. Additionally, aggregation of nanoparticles is required to obtain further enhancement of the electrochemical behavior due to restrictions that there be no $Li_4SiO_4$-related reaction during the first discharge process.

Trajectory Simulation of ASR Particles in Induction Electrostatic Separation (유도형 정전선별에서 ASR 입자의 궤적모사)

  • Kim, Beom-uk;Park, Chul-hyun
    • Resources Recycling
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    • v.28 no.6
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    • pp.96-105
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    • 2019
  • Automobile shredder residue (ASR) is the final waste produced when end-of-life vehicles (ELVs) are shredded. ASR can be separated using mineral-processing operations such as comminution, air classification, magnetic separation, and/or electrostatic separation. In this work, trajectory analyses of conductors (copper) and non-conductors (glass) in the ASR have been carried out using induction electrostatic separator for predicting or improving the ASR-separation efficiency. From results of trajectory analysis for conductors, the trajectories of copper wire by observation versus simulation for coarse particles of 0.5 and 0.25 mm showed consistent congruity. The observed 0.06 mm fine-particles trajectory was deflected toward the (-) attractive electrode owing to the charge-density effects due to the particle characteristics and relative humidity. In the case of non-conductors, the actual trajectory of dielectric glass deflected toward the (-) electrode, showing characteristics similar to those of conductive particles. The analyses of stereoscopic microscope and SEM & EDS found heterologous materials (fine ferrous particles and conductive organics) on the glass surface. This demonstrates the glass decreasing separation efficiency for non-ferrous metals during electrostatic separation for the recycling of ASR. Future work will require a pretreatment process for eliminating impurities from the glass and advanced trajectory-simulation processes.

A Study of Separation Mechanism in Ball Type Separated Bolt (볼타입 분리볼트의 분리현상 연구)

  • Lee, Yeung-Jo;Koo, Song-Hoe;Jang, Hong-Bin;Lee, Bang-Eop
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.2
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    • pp.62-67
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    • 2011
  • Launching tube is a kind of case to protect the guided weapons from external environments and conducted as a guide when they are fired. The guided weapons have been firmly kept at the launching tube and transferred, and would be separated at the required time when they are fired To meet the aim, it has been used explosive bolts which are reliable and efficient mechanical fastening devices having the special feature of a built-in release. The disadvantage of explosive bolt lies in that it is based on the high explosive effect of a pyrotechnic charge. When the explosive bolt is ignited, there are some bad effects; a flame, fragments and pyro-shock. Because of these bad effects there are many restriction to use bolt as joining devices to precision guided weapons. To solve these problems, the aim of the present work is to invent the ball-type separation bolt which is a pyrotechnically releasable mechanical linking device for two mechanical elements that does not suffer from such drawbacks. A standard pressure cartridge can moreover be easily integrated inside the device according to the present work and this with no modification to its structure. The present work was represented quantitatively the margin of separation safety and analysed separation mechanism in ball type separating bolt to perform the dynamic separation test.

Preparation and Photoelectrochemical Behavior of Cu2O/TiO2 Inverse Opal Heterojunction Arrays

  • Kim, Hyun-Sik;Lee, Sang-Kwon;Kang, Soon-Hyung
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.149-153
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    • 2012
  • The $Cu_2O/TiO_2$ inverse opal heterojunction arrays were developed by electrochemical deposition of $Cu_2O$ nanoparticles on $TiO_2$ inverse opal arrays. The $Cu_2O$ nanoparticles completely filled the inner pores of $TiO_2$ inverse opal film (prepared by liquid phase deposition with an average thickness of 400 nm) and covered the entire area; exhibiting high crystalline properties of anatase and cubic phase from $TiO_2$ and $Cu_2O$, respectively. From asymmetric current-voltage profile, it was noticeable that a heterojunction was well formed for charge transport from $Cu_2O$ to $TiO_2$ film resulting from the enhanced charge separation yield. In addition, increased photocurrent of 0.19 $mA/cm^2$ (versus 0.08 $mA/cm^2$ under dark condition) was obtained at -0.35 V from the heterojunction structure in the 0.5M $Na_2SO_4$ solution.