• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.33 no.11
• /
• pp.876-885
• /
• 2009

Char oxidation experiments were performed with a sub-bituminous roto-middle coal in the Drop Tube Furnace (DTF) at atmospheric pressure condition. While temperatures varied between 900, 1100, 1400 $^{\circ}C$, particle size, mass, particle temperature, and CO/$CO_2$ concentration were obtained to be used for kinetic analysis of the char oxidation. This study addresses several different methods to analyze the char consumption rate, which are classified as energy balance method, ash-traced mass method, flue-gas based method, and particle size based method. The char consumption rate obtained with such methods was compared with the results of Monson et al.$^{(24)}$ While there are some differences between them because of differences in experimental apparatus and parameters to be measured, the kinetic results seems to be reasonable enough to be incorporated in a numerical modeling of coal combustion.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.37 no.4
• /
• pp.405-413
• /
• 2013

The char oxidation characteristics of high ash coal were experimentally investigated at several temperatures (from 900 to $1300^{\circ}C$) for 4 types of coals (Gunvor, Glencore, Noble, and ECM) under atmospheric pressure in a drop tube furnace (DTF). The char reaction rate was calculated from the exhaust gas concentrations (CO and $CO_2$) using FT-IR, and the particle temperature was measured using the two-color method. In addition, the activation energy and pre-exponential factor for high ash coal char were calculated based on the Arrhenius equation. The results show that as the ash content increases, the particle temperature and area reactivity decreases. This is because in high ash coal, the large heat capacity of the ash, ash vaporization, and relatively low fixed carbon content of ash suppress combustibility during char oxidation. As a result, the higher ash content of coal leads to high activation energy.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.36 no.7
• /
• pp.675-681
• /
• 2012

The char oxidation characteristics of ashless coal with a relatively low ash content and high heating value were experimentally investigated at several temperatures (from $900^{\circ}C$ to $1300^{\circ}C$), in various oxygen concentrations (from 10% to 30%) under atmospheric pressure in a drop tube furnace. The char reaction rate was calculated from the exhaust gas concentrations (CO, $CO_2$) measured by FT-IR, and the particle temperature was measured by the two-color method. In addition, the activation energy and pre-exponential factor of ashless coal char were also calculated based on the Arrhenius equation. The results show that higher temperature and oxygen concentration result in a higher reaction rate of ashless coal, and the activation energy of ashless coal char is similar to that of bituminous coal.

• Transactions of the Korean hydrogen and new energy society
• /
• v.22 no.4
• /
• pp.534-545
• /
• 2011

This paper describes the evaluation of kinetic parameters for pyrolysis and carbon char oxidation of residual oil. The non-isothermal pyrolysis of residual oil was carried out with TGA (Thermo-Gravimetric Analyzer) at heating rate of 2, 5, 10 and $20^{\circ}C/min$ up to $800^{\circ}C$ under N2 atmosphere. The first order and nth order pyrolysis models were used to fit the experimental data, and the nth order model was turned out to follow the experimental data more precisely than the first order model. For carbon char oxidation experiment, TGA and four heating rates used in pyrolysis experiment were also adapted. The kinetic parameters for the residual carbon char particle were obtained with three char oxidation model, that is, volume reaction, grain and random pore model. Among them, the random pore model described the char oxidation behaviour quite well, compared to other two models. The non-linear regression method was used to obtain kinetic parameters for both pyrolysis and carbon char oxidation of residual oil.

• Journal of Energy Engineering
• /
• v.18 no.4
• /
• pp.239-246
• /
• 2009

A fundamental investigation has been conducted on the combustion of single particle of a sub-bituminous coal char burning at different temperatures and residence times. The lab-scale test setup consisted of a drop tube furnace where gas temperatures varied from $900^{\circ}C$ to $1400^{\circ}C$. A calibrated two color pyrometer, mounted on the top of the furnace, provided temperature profiles of luminous particle during a char oxidation. An amount of char mass reacted during the reaction is measured with thermogravimetry analyzer by using an ash tracer method. As a result, mass and area reactivity as well as reaction rate coefficients are determined for the char burning at atmospheric pressure condition.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.34 no.12
• /
• pp.1101-1109
• /
• 2010

We investigated the combustion rate and kinetic rate of char when burning in oxygen-enriched atmospheres with either an $N_2$ or $CO_2$ bath gas in a drop tube furnace. The experiments were performed with sub-bituminous coal (Adaro) and bituminous coal (Coal valley) under atmospheric pressure conditions. Two different coals were investigated over 12 to 30 vol% oxygen and furnace temperatures of 900, 1100, and $1300^{\circ}C$. For both coals, the particle temperature and overall reaction rate are lower in the $CO_2$ bath gas. However, analysis of single-particle data shows that the surface-specific burning rate of char oxidation is similar in both gases. In addition, the kinetic rate and activation energy for each coal were similar for both gases. Generally, the particle temperature and overall reaction rate of sub-bituminous coal are higher than those of bituminous coal.

• Journal of Energy Engineering
• /
• v.11 no.2
• /
• pp.166-177
• /
• 2002

The present study is described of the flame structure of one-dimensional, flat, premixed, laminar, coal-air flame with some addition of methane for the flame stability. A low pressure burner operating at a combustion pressure of 0.3 arm was employed in order to extend the reaction zone. Predicted results from the models considered in the present study are compared with experimental results. Comparisons are included gas temperatures, species concentrations, char analysis and measured burning velocity. Among the models, Model II $I^{*}$-d, which specified devolatilization rate constants and a char surface area factor S=4, resulted in good agreement within the present experimental ranges. The results of char analysis suggest that the extent of the reaction occurring on the panicle might be underestimated in the model so that the char surface area should be increased. A value of 4 for this factor was given by sensitivity analysis of change in char surface area. Again, model II $I^{*}$-d gave satisfactory predictions of burning velocities over most of the experimental range studied. It has been clearly shown that the particle diameter appreciably affects the rates of devolatilisation and char oxidation through the effects of thermal lag and volumetric reactive surface area, consequently laminar burning velocity.ity.

• Applied Chemistry for Engineering
• /
• v.20 no.6
• /
• pp.675-680
• /
• 2009

This article describes NO emission characteristics in SM coal combustion. Combustion experiments was performed in the method of increasing temperature after feeding coal and feeding coal after increasing temperature. NOx emission is in inverse proportion to combustion temperature at the fuel rich condition and it was caused by conversion fuel N to $N_{2}$ at the strong reduction condition. In addition, feeding gas flow rate increased as total fuel NOx increase by conversion of fuel N to NO at the oxidation condition. It could be separated in total fuel-N, volatile-N, char-N to NO according to analysis of total fuel NO emission from char combustion at each temperature. In the result, almost total NOx emission was caused by volatile-N in SM-coal.

• KEPCO Journal on Electric Power and Energy
• /
• v.2 no.1
• /
• pp.89-96
• /
• 2016

The mechanism for laminar dust flame propagation can only be elucidated from a comprehensive mathematical model which incorporates conduction and radiation, as well as the chemical kinetics of particle devolatilization and gas phase and char reaction. The mathematical model for a flat, laminar, premixed coal-air flame is applied to the atmospheric coal-air mixtures studied by Smoot and co-workers, and comparisons are made with their measurements and predictions. Here the principal parameter for comparison is the laminar burning velocity. The studies of Smoot and co-workers are first reviewed and compared with those predicted by the present model. The effects of inlet temperature and devolatilization rate constants on the burning velocities are studied with the present model, and compared with their measurements and predictions. Their measured burning velocities are approximately predicted with the present model at relatively high coal concentrations, with a somewhat increased inlet temperature. From the comparisons, their model might over-estimate particle temperature and rates of devolatilization. This would enable coal-air mixtures to be burned without any form of preheat and would tend to increase their computed values of burning velocity.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
• /
• 1997.11a
• /
• pp.146-153
• /
• 1997

An experimental study was performed of natural-convection downward smolder spread across a sawdust bed peripherally enclosed with an insulating container, to examine the effect of the open- ing condition at the top end on downward smolder spread. Experiments were conducted by using relatively coarse sawdust and 25-cm-long cylindrical container The variations of temperature profiles along the bed axis with time were determined far different opening conditions and were com-pared with those in smolder spread from open top to open bottom. It was shown that the smolder zone initiated from open top toward closed bottom penetrates the bed with keeping high peak temperature like the case of open top to open bottom spread, although mean spread rate is smaller. This indicates that the downward smolder zone can be sustained stably if sufficient air or oxygen Is supplied from the back of it by natural convection even if upward draft entering from the bottom of the bed is absent. When the top end was partially closed by mounting a cover after stable smolder spread had begun from open top toward open bottom, the temperature at the peak decreased more than 200 K and the smolder zone became to spread with thickening residue. In this case, the shape of temperature profiles continuously changed or decayed until end-effect at the open bottom end enhanced the reaction. The temperature at the shrunk peak, free from the end-effect, was almost identical with the temperature at the exothermic oxidative-degradation zone in smolder spread from open top to open bottom. from these results, it can be inferred for natural-convection downward smolder spread that the oxidation reaction of the char is very sensitive to the oxygen supply by natural convection in the space above the smolder zone, and that the top end opening condition strongly alters the completeness of reactions, structure, and behavior of the smolder zone.