• Title/Summary/Keyword: Changes of state of water

Search Result 366, Processing Time 0.03 seconds

Effect of Chitosan Treatment Methods on the Dyeing of Cotton, Nylon, and PET using Cochineal (II) - Focusing on Color Change by Laundering, Washfastness and Abrasion Fastness - (코치닐 염색(染色)에서 키토산처리(處理) 방법(方法)의 변화(變化)가 면(綿), 나일론, PET의 염색(染色)에 미치는 영향(影響) (II) - 세탁(洗濯)에 의한 색상변화(色相變化), 세탁견뢰도(洗濯堅牢度)와 마찰견뢰도(摩擦堅牢度) 특성(特性)에 관(關)하여 -)

  • Lee, Dong-Min;Jeon, Dong-Won;Kim, Jong-Jun
    • Journal of Fashion Business
    • /
    • v.9 no.2
    • /
    • pp.71-83
    • /
    • 2005
  • In this study, we reviewed the color changes accompanying the laundering, wash fastness, and abrasion fastness of chitosan-treated cochineal-dyed fabrics. The treatment methods were classified into two based on the chitosan treatment: (Method 1): fabric specimens were pre-treated with chitosan prior to the dyeing procedure in salt form. (Method 2): the state of chitosan acid salt formation, coated on the yarn surface, was destroyed and neutralized prior to the dyeing process. The changes in the chitosan treatment methods bear more important meaning in view of the durability. In Method 1, it is highly likely for the chitosan to be detached from the surface by water during laundering since the chitosan is coated as acid salt state. In Method 2, the resistance d the chitosan to water was supposed to revive since the chitosan would return to its original state. Differences in the resistance of the chitosan treatrrent, however, according to the Method 1 and Method 2, fell short of our expectations. In Method 2, the wash fastness did not improve as we expected since the bond between the fibers comprising fabric specimens and the chitosan is not high even if the chitosan itself has high resistance to water.

A simplified directly determination of soil-water retention curve from pore size distribution

  • Niu, Geng;Shao, Longtan;Sun, De'an;Guo, Xiaoxia
    • Geomechanics and Engineering
    • /
    • v.20 no.5
    • /
    • pp.411-420
    • /
    • 2020
  • Numbers fitting-curve equations have been proposed to predict soil-water retention curve (SWRC) whose parameters have no definitude physical meaning. And these methods with precondition of measuring SWRC data is time-consuming. A simplified directly method to estimate SWRC without parameters obtained by fitting-curve is proposed. Firstly, the total SWRC can be discretized into linear segments respectively. Every segment can be represented by linear formulation and every turning point can be determined by the pore-size distribution (PSD) of Mercury Intrusion Porosimetry (MIP) tests. The pore diameters governing the air-entry condition (AEC) and residual condition (RC) can be determined by the PSDs of MIP test. The PSD changes significantly during drying in SWR test, so the determination of AEC and RC should use the PSD under corresponding suction conditions. Every parameter in proposed equations can be determined directly by PSD without curve-fitting procedure and has definitude physical meaning. The proposed equations give a good estimation of both unimodal and bimodal SWRCs.

TEMPERATURE CHANGES OF IMPLANT SURFACE IN SECOND STAGE SURGERY WITH DETAL LASER : IN VITRO STUDY (레이저를 이용한 임프란트 이차수술시 온도변화에 관한 실험적 연구)

  • Ahn, Hyun-Jeong;Kim, Hyoun-Chull;Choi, Byeong-Gap;Song, Eon-Hee;Kim, Rae-Gyoung
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.37 no.2
    • /
    • pp.256-268
    • /
    • 1999
  • Submerged implants require secondary surgical uncovering of implants after healing period of 3-6 months. In surgical methods, there are surgical scalpel, tissue punch, electro-surgical, and laser-used uncovering, and so forth The objectives of this study are investigation and assessment of 1) thermal change in clinical application for uncovering of HA-coated implant and pure titanium implant irradiated by pulsed Nd-YAG, $CO_2$, and Er-YAG laser. 2) surface change of cover screws aaer irradiation using laser energy. The temperature of apex & side wall of implants were recorded at 10sec, 20sec, 30sec after 30sec irradiation to implant healing screw; 1) pulsed Nd-YAG laser; 2W, 20pps, contact mode 2) $CO_2$ laser; water-infused & non-water infused state, 2.5-3.5W, contibuous mode, noncontact mode 3) $CO_2$ laser ; non-water infused state, 3W, superpulse, noncontact. mode 4) Er-YAG laser; (1) non-water infused state, 10pps, 60mj, contact mode (2) water-infused state, 10pps, 60mj, 80mj, 101mj, contact mode. According to the results of this study, pulsed Nd-YAG laser is not indicated because of increased thermal change and pitting of metal surface of implant cover screw. By contrast, $CO_2$ laser & Er-YAG laser are presumed to indicate because of narrow range of thermal change & near abscence of thermal damage of metal surface. Dental laser is thought to be much helpful to surgical procedure when it is used as optimal power and time condition considering characteristics and indications of each laser. Further research is needed to verify that these techniques are safe and beneficial to implant success.

  • PDF

A Study on the Microstructure of Organic Ultra Thin Films and Phase Transition of Langmuir Films in BAM (BAM을 이용한 L막의 상전이 현상과 유기초박막의 미세구조에 관한 연구)

  • Kim, Byung-Geun;Chon, Dong-Kue;Kim, Young-Keun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2003.07b
    • /
    • pp.938-941
    • /
    • 2003
  • It is well known that the state of existence of molecules on the surface of water changes during compression of the molecules. Electric methods, such as measurement of the surface potential or displacement current are also useful for investigating dynamic changes of molecular state on the water surface during compression and Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic thin film that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. In this paper Langmuir (L) that is one of basis technology to manufacture of organic matter device using biology material PBDG that is kind of polypeptide that have biology adaptedness. The Experiment method used ${\pi}-A$ isotherm and BAM(Brewster Angle Microscopy), using the BAM, we can to the molecular orientation of monolayer on the water surface and directly see the morphology of the films on water subphase as well as that of the films.

  • PDF

Changes of Protein Composition and Muscle Tissues in Top Shell Meat during Frozen Storage (바다방석고둥육의 동결저장중 단백질조성과 근육조직의 변화)

  • 송대진;김창용;박환준
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.22 no.6
    • /
    • pp.763-770
    • /
    • 1993
  • To investigate the quality changes during frozen storage, top shell, Omphalius pfeifferi capenteri, was stored at -18$^{\circ}C$, -$25^{\circ}C$ and -3$0^{\circ}C$ immediately after shelling and water holding capacity, protein composition and histological features were examined with the lapsed period of the storage. During the storage period, amount of free drip was increased with higher frozen temperature and longer frozen period, but with the longer storage period, the lower water holding capacity was observed. The extractability and composition of muscle protein, sarcoplasmic protein and stroma protein were rather stable regardless of frozen temperature and frozen storage period. However, the extractability of myofibrillar protein was decreased with higher frozen temperature and longer frozen storage period. On the changes of muscle tissue structure, following points were observed. 1) In the muscle tissue structure of fresh sample, fine muscle fiber was closely distributed all over the tissue regardless of cross and longitudinal section. 2) In tissue structure under frozen state, it was observed that ice crystals apparently grew with the higher storage temperature. Empty spaces between muscle bundles which wee formed by aggregations of muscle fiber were observed after 3 months storage at -18$^{\circ}C$ . 3) Tissue structure in thawed state was restored satisfactorily after 1 month storage regardless of storage temperature. After 3 months storage at -3$0^{\circ}C$, muscle tissue was well restored, but at -18$^{\circ}C$, empty spaces were apparent due to incomplete restoration.

  • PDF

Simulation of Pressure Oscillation in Water Caused by the Compressibility of Entrapped Air in Dam Break Flow (댐 붕괴 유동에서 갇힌 공기의 압축성에 의한 물의 압력 진동 모사)

  • Shin, Sangmook
    • Journal of the Society of Naval Architects of Korea
    • /
    • v.55 no.1
    • /
    • pp.56-65
    • /
    • 2018
  • Pressure oscillation caused by the compressibility of entrapped air in dam break flow is analyzed using an open source code, which is a two-phase compressible code for non-isothermal immiscible fluids. Since compressible flows are computed based on a pressure-based method, the code can handle the equation of state of barotropic fluid, which is virtually incompressible. The computed time variation of pressure is compared with other experimental and computational results. The present result shows good agreements with other results until the air is entrapped. As the entrapped air bubbles pulsate, pressure oscillations are predicted and the pressure oscillations damp out quickly. Although the compressibility parameter of water has been varied for a wide range, it has no effects on the computed results, because the present equation of state for water is so close to that of incompressible fluid. Grid independency test for computed time variation of pressure shows that all results predict similar period of pressure oscillation and quick damping out of the oscillation, even though the amplitude of pressure oscillation is sensitive to the velocity field at the moment of the entrapping. It is observed that as pressure inside the entrapped air changes quickly, the pressure field in the neighboring water adjusts instantly, because the sound of speed is much higher in water. It is confirmed that the period of pressure oscillation is dominated by the added mass of neighboring water. It is found that the temperature oscillation of the entrapped air is critical to the quick damping out of the oscillations, due to the fact that the time averaged temperature inside the entrapped air is higher than that of surrounding water, which is almost constant.

Hydraulic Shock Load Response of Activated Sludge Process (활성슬러지공정의 수리학적 충격부하 반응)

  • Whang, Gye Dae;Kim, Min Ho;Ko, Sae;Cho, Chul Hwi
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.11 no.3
    • /
    • pp.67-78
    • /
    • 1997
  • The objective of study was to examine to transient response of hydraulic shock loading in activated sludge process for treatment of municipal sewage. The general experiment approach was to operate the system under steady-state(pre-shock), then to apply step changes during 24hours in fourfold hydraulic shock loading at the same organic loading. Performance was assessed in both the transient state and the new steady-state(post-shock). Three bench scale activated sludge reactors were operated to investigate the effect of fourfold hydraulic shock loading on TSS and COD removal efficiency. In activated sludge reactors operated with 13hours and 7hours of HRT, effluent quality of all reactors was not changed for few effects, and also showed no foaming and no sludge bulking. Those results are the same as sludge withdrawn reactors. The effect of fourfold hydraulic shock loading on the activated sludge reactors operated with 3hours of HRT was most severe. The effluent quality was deteriorated significantly and generate foaming in reactors. Less than 24hours after the fourfold shock loading applied, the activated sludge system seemed to attain a new steady-state condition as show by effluent.

  • PDF

Synthesis and Characterization of Sulfonated Poly(arylene ether) Polyimide Multiblock Copolymers for Proton Exchange Membranes

  • Lee, Hae-Seung;Roy Abhishek;Badami Anand S.;McGrath James E.
    • Macromolecular Research
    • /
    • v.15 no.2
    • /
    • pp.160-166
    • /
    • 2007
  • Novel multiblock copolymers, based on segmented sulfonated hydrophilic-hydrophobic blocks, were synthesized and investigated for their application as proton exchange membranes. A series of segmented sulfonated poly(arylene ether sulfone)-b-polyimide multiblock copolymers, with various block lengths, were synthesized via the coupling reaction between the terminal amine moieties on the hydrophilic blocks and naphthalene anhydride functionalized hydrophobic blocks. Successful imidization reactions required a mixed solvent system, comprised of NMP and m-cresol, in the presence of catalysts. Proton conductivity measurements revealed that the proton conductivity improved with increasing hydrophilic and hydrophobic block lengths. The morphological structure of the multiblock copolymers was investigated using tapping mode atomic force microscopy (TM-AFM). The AFM images of the copolymers demonstrated well-defined nanophase separated morphologies, with the changes in the block length having a pronounced effect on the phase separated morphologies of the system. The self diffusion coefficient of water, as measured by $^1H$ NMR, provided a better understanding of the transport process. Thus, the block copolymers showed higher values than Nafion, and comparable proton conductivities in liquid water, as well as under partially hydrated conditions at $80^{\circ}C$. The new materials are strong candidates for use in PEM systems.

External mechanisms driving ecosystem changes in a coastal wetland, the Mississippi Delta, USA

  • Ryu, Junghyung;Liu, Kam-biu;McCloskey, Terrence A.;Yun, Sang-Leen
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2022.05a
    • /
    • pp.85-85
    • /
    • 2022
  • The world's most extensive and active deltas, Louisiana's wetlands, are deteriorating rapidly due to multiple stressors such as the discharge of the Mississippi River, sea-level rise, and coastal retreat, the substantial but spatially and temporally variable impacts. However, the ecological and anthropogenic histories, the mode of environmental changes on a multi-millennial timescale have not been thoroughly documented. This study, a palynology-based multiproxy analysis, investigates hydrological, geological, geochemical, and anthropogenic impacts on southern Louisiana wetlands and a variety of external forcing agents influencing ecological succession. Sediment cores extracted from a small pond on a mangrove-dominate island near Port Fourchon, Louisiana, USA yielded a 4,000-year record. The site has been transformed from freshwater to saline water environments, to a mangrove dominant island over the late Holocene. The multivariate principal component analysis identified the relative strength of external drivers responsible for each ecological shift. The Mississippi River delta cycle (lobe switching) was the dominant driver of ecosystem changes during the late Holocene, while relative sea-level rise, tropical cyclones, climate, and anthropogenic effects have been the main drivers late in the site's history.

  • PDF