• Title/Summary/Keyword: Ceramic-on-ceramic

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Effect of Li3BO3 Additive on Densification and Ion Conductivity of Garnet-Type Li7La3Zr2O12 Solid Electrolytes of All-Solid-State Lithium-Ion Batteries

  • Shin, Ran-Hee;Son, Sam-Ick;Lee, Sung-Min;Han, Yoon Soo;Kim, Yong Do;Ryu, Sung-Soo
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.712-718
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    • 2016
  • In this study, we investigate the effect of the$Li_3BO_3$ additive on the densification and ionic conductivity of garnet-type $Li_7La_3Zr_2O_{12}$ solid electrolytes for all-solid-state lithium batteries. We analyze their densification behavior with the addition of $Li_3BO_3$ in the range of 2-10 wt.% by dilatometer measurements and isothermal sintering. Dilatometry analysis reveals that the sintering of $Li_7La_3Zr_2O_{12}-Li_3BO_3$ composites is characterized by two stages, resulting in two peaks, which show a significant dependence on the $Li_3BO_3$ additive content, in the shrinkage rate curves. Sintered density and total ion conductivity of the system increases with increasing $Li_3BO_3$ content. After sintering at $1100^{\circ}C$ for 8 h, the $Li_7La_3Zr_2O_{12}-8$ wt.% $Li_3BO_3$ composite shows a total ionic conductivity of $1.61{\times}10^{-5}Scm^{-1}$, while that of the pure $Li_7La_3Zr_2O_{12}$ is only $5.98{\times}10^{-6}Scm^{-1}$.

Effect of Process Parameters on the Morphology and Size of Spray-Dried Granule Powder for Fabrication of SiAlON Raw Material (SiAlON 원료분말제조를 위한 분무건조 과립분말의 형상과 크기에 미치는 공정변수효과)

  • Choi, Jae-Hyeong;Lee, Soyul;Han, Yoonsoo;Lee, Sung-Min;Nahm, Sahn;Kim, Seongwon
    • Korean Journal of Materials Research
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    • v.27 no.12
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    • pp.716-721
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    • 2017
  • SiAlON-based ceramics are some of the most typical ceramic materials used as cutting tools for HRSA(Heat Resistant Super-Alloys). SiAlON can be fabricated using ceramic processing, such as mixing, granulation, compaction, and sintering. Spray drying is a widely-used method for producing a granular powder of controlled morphology and size with flowability. In this study, we report a systematic investigation aimed at optimizing spherical granule morphology by controlling spray-drying parameters such as gas flow and feed rate. Before spray drying, the viscosities of the raw material slurries were also optimized with the amount of dispersant added.

The Effect of Binder Burnout Time and Heating Rate on the Electrical Properties of Multilayer Ceramic Capacitors (소결과정에 있어서 Bindex Burnout 온도 및 소결온도까지의 가열속도가 MLC의 전기적 특성에 미치는 영향)

  • 김호기;오창섭;김용혁
    • Journal of the Korean Ceramic Society
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    • v.24 no.3
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    • pp.207-214
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    • 1987
  • This paper is to determine the effect of binder burnout time and heating rate on the electrical propertries of type II multilayer ceramic capacitors(MLC). The quality of multilayer ceramic capacitor depends suitable on the binder burnout time, which is determined for at least 24 hours in the PVB-binder system. It is suggested that theelectrical properties of multilayer ceramic capacitor is due to the control of heating rate, with the dipole moment density from grain size distributiion. Comparing the fast firing with slow, we observed a small but consistent improvement in the electrical properties.

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Enhancement of Oxygen and Moisture Permeability with Illite-Containing Polyethylene Film

  • Seong, Dong Min;Lee, Hyesun;Chang, Jeong Ho
    • Journal of the Korean Ceramic Society
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    • v.56 no.6
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    • pp.601-605
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    • 2019
  • This work reports the preparation of ceramic hybrid films with illite-polyethylene composites analyzed as a function of concentration of added illite in polyethylene. The enhancement of oxygen and water-vapor transmission rate of illite-polyethylene film was evaluated to determine its influence on the freshness in fruit packaging. Particle size of illite materials was controlled in the range of 1~10 ㎛ and then mixed with LDPE to form the masterbatch. Ceramic hybrid films were prepared through a blown film making process. To determine the dispersity and abundancy of illite materials in the polyethylene matrix, various characterizations of illite-PE hybrid masterbatch and films were performed using SEM, TGA, and FT-IR. The oxygen and water-vapor transmission rate of illite-polyethylene film was found to be two times higher than that of LDPE film.

A Stochastic Model for Virtual Data Generation of Crack Patterns in the Ceramics Manufacturing Process

  • Park, Youngho;Hyun, Sangil;Hong, Youn-Woo
    • Journal of the Korean Ceramic Society
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    • v.56 no.6
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    • pp.596-600
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    • 2019
  • Artificial intelligence with a sufficient amount of realistic big data in certain applications has been demonstrated to play an important role in designing new materials or in manufacturing high-quality products. To reduce cracks in ceramic products using machine learning, it is desirable to utilize big data in recently developed data-driven optimization schemes. However, there is insufficient big data for ceramic processes. Therefore, we developed a numerical algorithm to make "virtual" manufacturing data sets using indirect methods such as computer simulations and image processing. In this study, a numerical algorithm based on the random walk was demonstrated to generate images of cracks by adjusting the conditions of the random walk process such as the number of steps, changes in direction, and the number of cracks.

A Study on the Coated Characteristics of Ceramic Tools (세라믹공구 재료의 피복특성에 관한 연구)

  • Lee, Myeong-Je;Im, Hong-Seop;Yu, Bong-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.4 s.175
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    • pp.900-906
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    • 2000
  • Ceramic, PCD and CBN tools are available for the difficult-to-cut-materials such as hardened carbon tool steel, stainless steel, Inconel 718 and etc. Ceramic tools are likely to be chipped and abruptly broken before the appearance of normal wear in turning. Ceramic tools are suitable for continuous in turning, not for intermittent in milling. In this study, TiN/TiCN multi-layer coated ceramic tools were found to restrain the chipping, breaking and early fracture and to increase the critical cutting speed owing to TiN/TiCN multi-layer coating in Arc Ion Plating of PVD method.

Effects of the Thickness and Dopant on the Photoelectro- chemical Conversion in the Polycrystalline $TiO_2$ Electrodes (광전기 화학변환에 미치는 $TiO_2$ 전극의 두께와 첨가제의 영향)

  • 윤기현;강동헌
    • Journal of the Korean Ceramic Society
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    • v.21 no.3
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    • pp.266-270
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    • 1984
  • The photoelectrochemical properties of the reduced $TiO_2$ceramic electrodes are investigated varying the thickness of the electrodes and the amounts of $Sb_2O_3$ as dopant. As the thickness of the undoped. $TiO_2$ceramic electrode increases the photocurrent tends to decrease. However for the R-F sputtered $TiO_2$ thin film electrodes the photocurrent tends to increase to about 1$\mu\textrm{m}$ thick and then decreases with increasing thickness. For the $TiO_2$ ceramic electrodes doped with $Sb_2O_3$ the photocurrent decreases with inreasing the amounts of dopant and in the case of rapid cooling in air without reduction treatment the photocurrent shows lower value. Also visible light excitation is observed at 500~550(nm) wavelength for the $TiO_2$ ceramic electrodes doped with $Sb_2O_3$comparing wtih the $TiO_2$ ceramic electrodes (~420nm)

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Recent advances and future potential of anaerobic ceramic membrane bioreactors for wastewater treatment: A review

  • Cha, Minju;Kim, Soyoun;Park, Chanhyuk
    • Membrane and Water Treatment
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    • v.11 no.1
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    • pp.31-39
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    • 2020
  • Anaerobic membrane bioreactor (AnMBR) treatment has been widely studied in recent years because of the potential for production of bio-energy from wastewater and energy-positive operation of wastewater treatment plants. Several AnMBR systems, including those that incorporate ceramic membranes, take advantage of enhanced water permeability and low membrane fouling potentials. Given that differences in the ceramic membranes may influence the results of AnMBR studies, relevant details are discussed in this review, which focuses on the profiles of common ceramic membranes used in AnMBR, treatment and filtration performances of different anaerobic ceramic membrane bioreactors (AnCMBRs), and the membrane fouling mitigation methods available for effective AnCMBRs operation. The aim of this review is to provide a comprehensive summary of AnCMBR performance, feed wastewater characteristics, operating conditions, and the methods available for effective fouling mitigation.

Changes in the composition according to the manufacturer and the characteristics of the ceramic support (조성변화에 따른 세라믹지지체의 제조 및 그 특성)

  • Kwom, Yongjin;Choi, Byunghyun;Jee, Mijung;Ahn, Yongtae;Seol, Kwanghee;Nham, Shan
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.83.2-83.2
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    • 2011
  • In this study, we fabricated tubular ceramic support for segmented-in-series solid oxide fuel cell (SOFC) by using MAO(MgAl-stabilized ) as main material and activated carbon as pore former. Thermal expansion properties of ceramic support with different amounts of activated carbon were analyzed by using dilatometer to decide a suitable sintering temperature. The tubular ceramic supports with different amounts of activated carbon (15, 20, 30wt.%) were fabricated by the extrusion technique. After sintering at $1400^{\circ}C$ for 2h, cross section and surface morphology of tubular ceramic support were analyzed by using SEM image. Also, the porosity, mechanical property, gas permeability of tubular ceramic supports was measured. Based on these results, we established the suitable fabrication technique of tubular ceramic support for segmented-in-series SOFC.

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GROWTH AND CHARACTERIZATIONS OF $La_3Ga_5SiO_{14}$ SINGLE CRYSTALS AND SINTERED BODY FOR THE APPLICATIONS OF FILER AND RESONATOR

  • Jung, Il-Hyoung;Kyung Joo;Shim, Kwang-Bo;Auh, Keun-Ho
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.09a
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    • pp.73-77
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    • 1998
  • Langasite(La3Ga5SiO14) is a new piezoelectric material which is similar to quartz, LN(LiNbO3) and LT(LiTaO3) in its acoustic behavior. In this study, pure Langasite and Langasite family groups were synthesized by the solid state reactions in air. For the synthesis process, diffusion species were investigated and sintered body of synthesized powders were studied on dielectric property according to surface microstructures.

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