• Title/Summary/Keyword: Ceramic-glass

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The Holding Characteristics of the Glass Filter Separators of Molten Salt Electrolyte for Thermal Batteries (열전지용 용융염 전해질의 유리필터분리판의 담지특성)

  • Cho, Kwang-Youn;Riu, Doh-Hyung;Huh, Seung-Hun;Shin, Dong-Geun;Kim, Hyoun-Ee;Cheong, Hae-Won;Cho, Sung-Baek
    • Journal of the Korean Ceramic Society
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    • v.45 no.8
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    • pp.464-471
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    • 2008
  • The electrolyte separator for thermal battery should be easily handled and loaded a large amount of the molten salt. Ceramic fibers, especially fibrous commercial glass filters were used as an electrolyte separator and the lithium based molten salts were infiltrated into the ceramic filters. The pore structures of the ceramic filter and the melting properties of the lithium salts affected to the electrolyte loading and leakage. During the infiltration, ions of $Li^+$ and $F^-$ in the molten salts were reacted with the glass fiber and caused to be weaken the fiber strength.

Preparation of $10TiO_2$.$90SiO_2$ Glass by Sol-Gel Process (졸-겔법에 의한 $10TiO_2$.$90SiO_2$ 유리의 제조)

  • Rhee, Jhun;Chi, Ung-Up;Kang, Tae-Soo;Jo, Dong-Soo;Ko, Sung-Kwan
    • Journal of the Korean Ceramic Society
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    • v.23 no.4
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    • pp.27-34
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    • 1986
  • In the present study an attempt was made to synthesize $10TiO_2$.$90SiO_2$ glass by Sol-Gel process. Tetra-ethyl-ortho-silane and titanium-iso-propoxide were used as precursors. As the mutual solvent ethanol and iso-propanol were used. TEOS was partially hydrolyzed with one-fold mole of $H_2O$ prior to the reaction with titanium-iso-propoxide to control the difference of hydrolysis rate of the two metal alkoxides. At gelling temperature higher than 6$0^{\circ}C$ it was difficult to obtain monolithic gels. At such a low temperature as 85$0^{\circ}C$ clear amorphous gel derived glass with Si-O-Ti bonding was obtained.

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Dielectric Properties in Cordierite/Glass Composite for LTCC Material (LTCC소재용 Cordierite/Glass Composite계의 유전특성 변화)

  • Hwang, Il-Sun;Shin, Hyo-Soon;Yeo, Dong-Hun;Kim, Jong-Hei
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.304-304
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    • 2007
  • 고주파 모률에서 사용되는 기판소재는 저유전율과 낮은 loss 특성을 요구함으로 지속적인 연구를 필요로 한다. 지금까지의 ceramic/glass composite 에서 주로 사용된 ceramic filler는 Al2O3로 낮은 유전률을 구현에 한계가 있었다. Cordierite는 낮은 유전율 (${\varepsilon}_r$ < 4)을 나타내는 filler로서 그 가능성이 높지만 아직까지 보고된 결과들이 미흡한 실정이다. 따라서 본 연구에서는 cordierite filler와 SiO2-B2O3-Al2O3-RO (R : Zn, Sr, Ba, Ca)계의 glass를 혼합하여 LTCC용 기판소재로서의 가능성을 확인하고자 저온 동시소성이 가능한 소결온도인 $850^{\circ}C{\sim}1.000^{\circ}C$ 사이에서 소재의 소결실험을 진행하였다. 소결온도에 따른 상변화, 유전특성을 확인한 결과 filler로 사용된 cordierite상만이 관찰 되었으며 소결조건에 따라 5.0~5.5의 낮은 유전율과 1.000~1,500의 Q를 나타내는 것을 확인 하였다.

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Preparation and properties of glass fiber-reinforced endodontic (root canal therapy) posts (유리섬유 강화 근관치료 포스트의 제조 및 특성에 대한 연구)

  • Son, Jae-Yong;Kim, Kyoung-Ja;Kim, Kyoung-Hun;Park, Joo-Seok;Shim, Kwang-Bo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.3
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    • pp.105-110
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    • 2015
  • The fiber-reinforced endodontic posts were prepared using a photocurable resin and a glass fiber. The mechanical property of the posts increased with increasing density of glass fiber and the micro-pores in the post were removed by a vacuum impregnation process. To improve the interfacial adhesion between glass fiber and polymer, silane coupling agent was used. The surface treatment of glass fiber increased the surface wettability of resing on glass fiber and increased the adhesion property with resin, consequently improved the mechanical property of posts.

Tensile strength of bilayered ceramics and corresponding glass veneers

  • Anunmana, Chuchai;Champirat, Tharee;Jirajariyavej, Bundhit
    • The Journal of Advanced Prosthodontics
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    • v.6 no.3
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    • pp.151-156
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    • 2014
  • PURPOSE. To investigate the microtensile bond strength between two all-ceramic systems; lithium disilicate glass ceramic and zirconia core ceramics bonded with their corresponding glass veneers. MATERIALS AND METHODS. Blocks of core ceramics (IPS e.max$^{(R)}$ Press and Lava$^{TM}$ Frame) were fabricated and veneered with their corresponding glass veneers. The bilayered blocks were cut into microbars; 8 mm in length and $1mm^2$ in cross-sectional area (n = 30/group). Additionally, monolithic microbars of these two veneers (IPS e.max$^{(R)}$ Ceram and LavaTM Ceram; n = 30/group) were also prepared. The obtained microbars were tested in tension until fracture, and the fracture surfaces of the microbars were examined with fluorescent black light and scanning electron microscope (SEM) to identify the mode of failure. One-way ANOVA and the Dunnett's T3 test were performed to determine significant differences of the mean microtensile bond strength at a significance level of 0.05. RESULTS. The mean microtensile bond strength of IPS e.max$^{(R)}$ Press/IPS e.max$^{(R)}$ Ceram ($43.40{\pm}5.51$ MPa) was significantly greater than that of Lava$^{TM}$ Frame/Lava$^{TM}$ Ceram ($31.71{\pm}7.03$ MPa)(P<.001). Fluorescent black light and SEM analysis showed that most of the tested microbars failed cohesively in the veneer layer. Furthermore, the bond strength of Lava$^{TM}$ Frame/Lava$^{TM}$ Ceram was comparable to the tensile strength of monolithic glass veneer of Lava$^{TM}$ Ceram, while the bond strength of bilayered IPS e.max$^{(R)}$ Press/IPS e.max$^{(R)}$ Ceram was significantly greater than tensile strength of monolithic IPS e.max$^{(R)}$ Ceram. CONCLUSION. Because fracture site occurred mostly in the glass veneer and most failures were away from the interfacial zone, microtensile bond test may not be a suitable test for bonding integrity. Fracture mechanics approach such as fracture toughness of the interface may be more appropriate to represent the bonding quality between two materials.

Synthesis and Printability of Aqueous Ceramic Ink with Graft Polymer (Graft Polymer를 이용한 수계 세라믹 잉크의 합성 및 프린팅 특성평가)

  • Lee, Ji-Hyeon;Hwang, Hae-Jin;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Korean Journal of Materials Research
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    • v.29 no.10
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    • pp.639-646
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    • 2019
  • Ink-jet printing is a manufacturing process technology that directly prints a digitalized design pattern onto a substrate using a fine ink jetting system. In this study, environmentally friendly yellow aqueous ceramic ink is synthesized by mixture of distilled water, yellow ceramic pigment and additives for ink-jet printing. The graft polymer, which combines electrostatic repulsion and steric hindrance mechanism, is used as a surfactant for dispersion stability of aqueous ceramic ink. Synthesized ceramic ink with graft polymer surfactant shows better dispersion stability than did ceramic ink with PAA surfactant; synthesized ink also shows desirable ink-jet printability with the formation of a single ink droplet during printability test. Finally, ceramic ink printed on glass substrate and ceramic ink with graft polymer surfactant shows a high contact angle without surface treatment on glass substrate. Consequently, it is confirmed that the ceramic ink with graft polymer surfactant can achieve high printing resolution without additional surface treatment process.

A Study on the Prediction and Reduction of Residual Stress in Glass (I): Analysis of Residual Stress in Glass by Instant Freezing Model (유리의 잔류응력 예측 및 감소화 방안 연구(I): 순간동결모델에 의한 유리의 잔류응력 해석)

  • 이재춘;백태현
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.902-910
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    • 1994
  • Residual stress measurements were made for cylindrical glass rods to compare experimental results with the calculated values obtained by Instant Freezing Model. According to the photoelastic measurements, the stress ratio of surface compression and center tension was increased from 1.4 to 2.0 as the heat-treatment temperature was lowered, the fictitious forzen temperature was found to be closer to the heat-treatment temperature and the fictitious coefficient was increased.

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The Study on Foam Formation in Waterslag-Bentonite System (수광재와 백토조합물에서의 기포형성에 관한 연구)

  • 김종희;송한식
    • Journal of the Korean Ceramic Society
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    • v.14 no.4
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    • pp.248-255
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    • 1977
  • The effect of firing temperature, soaking time and batch composition upon the glass phase and pore formation as well as their distribution in slag foamed glass was investigated. Sulfur dioxide gas produced by the oxidation and reduction of metal sulfide in waterslag was attributed to foam forming agent. Slag foamed glass matrix was mainly composed of 35~60% glas phase and melilite crystalline phase. The increment of bentonite addition in batch lowered the foam forming temperature in studied system. The result showed also that the foam size distribution was broadened as th firing temperature wa inbereased.

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