• Title/Summary/Keyword: Ceramic tube

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Fabrication and Cell Properties of Flattened Tube Segmented-in-Series Solid Oxide Fuel Cell-Stack Using Decalcomania Paper (전사지를 이용한 다전지식 평관형 고체산화물 연료전지 제작 및 셀 특성)

  • An, Yong-Tae;Ji, Mi-Jung;Park, Sun-Min;Shin, Sang-Ho;Hwang, Hae-Jin;Choi, Byung-Hyun
    • Korean Journal of Materials Research
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    • v.23 no.3
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    • pp.206-210
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    • 2013
  • In the segmented-in-series solid-oxide fuel cells (SIS-SOFCs), fabrication techniques which use decalcomania paper have many advantages, i.e., an increased active area of the electrode; better interfacial adhesion property between the anode, electrolyte and cathode; and improved layer thickness uniformity. In this work, a cell-stack was fabricated on porous ceramic flattened tube supports using decalcomania paper, which consists of an anode, electrolyte, and a cathode. The anode layer was $40{\mu}m$ thick, and was porous. The electrolyte layers exhibited a uniform thickness of about $20{\mu}m$ with a dense structure. Interfacial adhesion was improved due to the dense structure. The cathode layers was $30{\mu}m$ thick with porous structure, good adhesion to the electrolyte. The ohmic resistance levels at 800, 750 and $700^{\circ}C$ were measured, showing values of 1.49, 1.58 and $1.65{\Omega}{\cdot}cm^2$, respectively. The polarization resistances at 800, 750 and $700^{\circ}C$ were measured to be 1.63, 2.61 and $4.17cm^2$, respectively. These lower resistance values originated from the excellent interfacial adhesion between the anode, electrolyte and cathode. In a two-cell-stack SOFC, open-circuit voltages(OCVs) of 1.915, 1.942 and 1.957 V and maximum power densities(MPD) of 289.9, 276.1 and $220.4mW/cm^2$ were measured at 800, 750 and $700^{\circ}C$, respectively. The proposed fabrication technique using decalcomania paper was shown to be feasible for the easy fabrication of segmented-in-series flattened tube SOFCs.

Electrical and Mechanical Characteristics of Ni-YSZ Tubular Support Fabricated by Extrusion (압출공정에 의해 제조된 Ni-YSZ 원통형 음극 지지체의 특성)

  • Yu, Ji-Haeng;Kim, Young-Woon;Park, Gun-Woo;Seo, Doo-Won;Lee, Shi-Woo;Woo, Sang-Kuk
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.768-774
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    • 2006
  • The microstructure of Ni-YSZ cermets was controlled with fine and coarse starting powders (NiO and YSZ) to obtain a optimum strong and conductive tubular anode support for SOFCs. Three types of cermets with different microstructures, i.e., coarse Ni-fine YSZ, fine Ni-coarse YSZ, and fine Ni-fine YSZ, were fabricated to investigate their electrical and mechanical properties. The cermets from fine NiO powder showed high electrical conductivity due to the enhanced percolation of Ni particles. The cermet by foe Ni and coarse YSZ showed excellent electrical conductivity (>1000 S/cm) despite its high porosity $(\sim40%)$ but it showed poor mechanical strength due to the lack of percolation by YSZ particles and due to large pores. Thus fine NiO and YSZ powders were used to make strong and conductive Ni-YSZ support tube by extrusion. The microstructure of the anode tube was modified by the amount of polymeric additives and carbon black, a pore former. Ni-YSZ tube (porosity $\sim34%$) with the finer microstructure showed better performance both in electrical conductivity (>1000 S/cm) and fracture strength $(\sim140\;MPa)$. Either flat or circular NiO-YSZ tubes with the length from 20 to 40cm were successfully fabricated with the optimized composition of materials and polymeric additives.

Energy-saving potential of cross-flow membrane emulsification by ceramic tube membrane with inserted cross-section reducers

  • Albert, K.;Vatai, Gy.;Giorno, L.;Koris, A.
    • Membrane and Water Treatment
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    • v.7 no.3
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    • pp.175-191
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    • 2016
  • In this work, oil-in-water emulsions (O/W) were prepared successfully by membrane emulsification with $0.5{\mu}m$ pore size membrane. Sunflower oil was emulsified in aqueous Tween80 solution with a simple crossflow apparatus equipped with ceramic tube membrane. In order to increase the shear-stress near the membrane wall, a helical-shaped reducer was installed within the lumen side of the tube membrane. This method allows the reduction of continuous phase flow and the increase of dispersed phase flux, for cost effective production. Results were compared with the conventional cross-flow membrane emulsification method. Monodisperse O/W emulsions were obtained using tubular membrane with droplet size in the range $3.3-4.6{\mu}m$ corresponded to the membrane pore diameter of $0.5{\mu}m$. The final aim of this study is to obtain O/W emulsions by simple membrane emulsification method without reducer and compare the results obtained by membrane equipped with helix shaped reducer. To indicate the results statistical methods, $3^p$ type full factorial experimental designs were evaluated, using software called STATISTICA. For prediction of the flux, droplet size and PDI a mathematical model was set up which can describe well the dependent variables in the studied range, namely the run of the flux and the mean droplet diameter and the effects of operating parameters. The results suggested that polynomial model is adequate for representation of selected responses.

A Fracture Analysis on the Ceramic Dome with Different Geometry under Impact (충격을 받는 세라믹돔의 기하형상에 따른 파괴해석)

  • Kwon, Sun-Guk;Lee, Yung-Shin;Kim, Jae-Hoon;Lee, Jung-Hee;Yoon, Su-Jin
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.706-710
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    • 2008
  • The experiment of dome port cover under shock impact is performed with shock tube. The dome port cover blocked intake air duct up from the solid propellant during air breathing vehicle speed reach Mach 2.0. When the air breathing vehicle reach Mach 2.0, the inlet cover is removed and the dome port cover is broken to pieces by detonator or pressure of inlet air. Thus the dome port cover not only must stand the pressure of combustion chamber but also easy to break from the RAM pressure. In this study, a fracture evaluation on the $Al_2O_3$ ceramic spherical dome and circular plate port under impact has been presented. Ceramic were supported by the rigid body and a couple of O-ring. The Mooney-Rivlin model have been used to describe behaviors of both O-ring. And spherical dome and circular plate fracture results of the LS-DYNA code using Johnson-Holmquist(JH-2) constitutive equation was compared.

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The Property Analysis of Ceramic Metal-Halide Lamp Considering Acoustic Resonance Phenomenon and Design of Inverter by the PSpice Simulation (음향 공명 현상을 고려한 세라믹 메탈핼라이드의 특성 분석과 PSpice 시뮬레이션을 통한 인버터 설계)

  • Jang, Hyeok-Jin;Kim, Nam-Goon;Yang, Jong-Kyung;Lee, Jong-Chan;Park, Dae-Hee
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.10
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    • pp.1989-1994
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    • 2009
  • This study purposes are improvement of system (lamp & ballast) efficacy with and optical characteristics through the developed ceramic arc tube. The designed electronic ballast is substituted for conventional magnetic ballast. These electric signal and optical, thermal characteristics through the improving efficacy of lighting system compared with conventional magnetic ballast. properties of lamp by driving method is researching in ballast. Particularly, electronic ballasts, which improved against weakness of Magnetic Ballast, are researching and applying to control of ceramic metal-halide lamp. but One major limitation is the acoustic resonance problem in CMH lamps at high-frequency operation. In order to avoid acoustic resonance, driving frequency decided 21[kHz]. Before discharge in this paper. The PSpice simulation result obtained sufficient voltage gain and the ignition voltage obtained over 3[kV] at 75[kHz]. After discharge, driving voltage obtained approximately 90[Vrms] at 21[kHz].

Electrical Properties of PVdF/PVP Composite Filled with Carbon Nanotubes Prepared by Floating Catalyst Method

  • Kim, Woon-Soo;Song, Hee-Suk;Lee, Bang-One;Kwon, Kyung-Hee;Lim, Yun-Soo;Kim, Myung-Soo
    • Macromolecular Research
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    • v.10 no.5
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    • pp.253-258
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    • 2002
  • The multi-wall carbon nanotubes (MWNTs) with graphite crystal structure were synthesized by the catalytic decomposition of a ferrocene-xylene mixture in a quartz tube reactor to use as the conductive filler in the binary polymer matrix composed of poly(vinylidene fluoride) (PVdF) and poly(vinyl pyrrolidone) (PVP) for the EMI (electromagnetic interference) shielding applications. The yield of MWNTS was significantly dependent on the reaction temperature and the mole ratio of ferrocene to xylene, approaching to the maximum at 800 $^{\circ}C$ and 0.065 mole ratio. The electrical conductivity of the MWNTs-filled PVdF/PVP composite proportionally depended on the mass ratio of MWNTs to the binary polymer matrix, enhancing significantly from 0.56 to 26.7 S/cm with the raise of the mass ratio of MWNTs from 0.1 to 0.4. Based on the higher electrical conductivity and better EMI shielding effectiveness than the carbon nanofibers (CNFs)-filled coating materials, the MWNTs-filled binary polymer matrix showed a prospective possibility to apply to the EMI shielding materials. Moreover, the good adhesive strength confirmed that the binary polymer matrix could be used for improving the plastic properties of the EMI shielding materials.

A Study on the Wire Manufacturing and Properties of High Tc Superconductor (고온 초전도체의 선재제작 및 특성연구)

  • Ha, Dong-Woo;Cho, Hae-Ryong;Sohn, Myung-Bwan;Kim, Sang-Hyun;Yun, Mun-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.05a
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    • pp.7-9
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    • 1988
  • This paper considers problems which must be overcome to produce long lengths of superconductor wire from the 90K Tc superconducting ceramic material, $Y_1Ba_2Cu_3Ox$. Attention is focused on the powder-in-tube process where the superconducting powder is placed in a tube which is then formed into wire. Two major problems are considered, control of the oxygen level and improvement of Jc in the final wire. The results show that Jc of the wire were $400A/cm^2$ at liquid nitrogen temp.

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Intelligent computer modeling of large amplitude behavior of FG inhomogeneous nanotubes

  • Wu, Xiongwei;Fang, Ting
    • Advances in nano research
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    • v.12 no.6
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    • pp.617-627
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    • 2022
  • In the current study, the nonlinear impact of the Von-Kármán theory on the vibrational response of nonhomogeneous structures of functionally graded (FG) nano-scale tubes is investigated according to the nonlocal theory of strain gradient theory as well as high-order Reddy beam theory. The inhomogeneous distributions of temperature-dependent material consist of ceramic and metal phases in the radial direction of the tube structure, in which the thermal stresses are applied due to the temperature change in the thickness of the pipe structure. The general motion equations are derived based on the Hamilton principle, and eventually, the acquired equations are solved and modeled by the Meshless approach as well as a computer simulation via intelligent mathematical methodology. The attained results are helpful to dissect the stability of the MEMS and NEMS.

A Comparative Study on the Characteristics of Thermoacoustic Laser for Applying Solar Energy (태양열 적용을 위한 열음향 레이저의 특성 비교 연구)

  • Park, Sung-Seek;An, Eoung-Jin;Oh, Seung-Jin;Chun, Won-Gee;Kim, Nam-Jin
    • Journal of the Korean Solar Energy Society
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    • v.32 no.2
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    • pp.105-112
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    • 2012
  • The conversion of solar energy into acoustic waves is experimentally studied. Measurements were made on the Sound Pressure Level (SPL), frequency, onset time and the temperature gradient across the stack. A pyrex resonance tube is used with a honey-comb structure ceramic stack along with Ni-Cr and Cu wires. An AL1 acoustical analyzer was used to measure the SPL and frequency of acoustic waves whereas K-type thermocouples were hired to estimate temperature gradients. For a resonance tube of 100 mm, no acoustic waves were generated with a power input of 25W. By increasing its length to 200 mm, however, maximum SPLs of 96.4 dB, 106.3 dB and 112.8 dB were detected for the tubes of 10mm,20mm and 30mm in IDs and their respective stack positions of 70mm, 60mm and 50mm from the closed end.

A Comparative Study on the Characteristics of Thermoacoustic Laser for Using Solar Energy (태양에너지 이용을 위한 열음향 레이저의 특성 비교 연구)

  • Park, Sung-Seek;An, Eoung-Jin;Oh, Seung-Jin;Chun, Won-Gee;Kim, Nam-Jin
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.516-521
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    • 2012
  • The conversion of solar energy into acoustic waves is experimentally studied. Measurements were made on the Sound Pressure Level (SPL), frequency, onset time and the temperature gradient across the stack. A pyrex resonance tube is used with a honey-comb structure ceramic stack along with Ni-Cr and Cu wires. An AL1 acoustical analyzer was used to measure the SPL and frequency of acoustic waves whereas K-type thermocouples were hired to estimate temperature gradients. For a resonance tube of 100mm, no acoustic waves were generated with a power input of 25W. By increasing its length to 200mm, however, maximum SPLs of 96.4 dB, 106.3 dB and 112.8 dB were detected for the tubes of 10mm, 20mm and 30mm in IDs and their respective stack positions of 70mm, 60mm and 50mm from the closed end.

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