• Title/Summary/Keyword: Ceramic oxides

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Determination of Surface Diffusivities of Oxides by the Combined Sintering (소결에 의한 산화물촉매의 표면확산계수의 측정)

  • 문세기;유경옥;김형진
    • Journal of the Korean Ceramic Society
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    • v.14 no.2
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    • pp.73-77
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    • 1977
  • The surface diffusion coefficients for nickel, nickel oxide, cuppric oxide, cobalt oxide, alumina and ferric oxide have been determined at various temperatures using the sintering technique. This investigation is based on the model accounting for the sum of the contribution of volume and surface diffusion to the overall shrinkage rate during the initial stage of sintering. Simultaneous measurements of shrinkages and shrinkage rates of the materials compacts were conducted for various annealing times, the results of which were then correlated to the diffusion coefficient.

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Ceramics superconducting Energy Materials (세라믹 에너지 재료)

  • Lee, Sang-Heon
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1238-1239
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    • 2008
  • The high Tc supeconductor of ceramic oxides type was studied for finding its application field. The results reportaed in this paper on the stability of the ceramic superconductors and the resistance to ripening in the BCO liquid phase at elevated temperature opens a processing window for engineering the microstructure of large superconductor at the nanoscale level. The results suggest further that the introduction of highly efficient artifical pinning center to bulk ceramics superconductor.

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Ceramic Coating by Electron Beam PVD for Nanos-Tructure Control (나노구조 제어를 위한 EB-PVD법에 의반 세라믹스 코팅)

  • Matsbara, Hideaki
    • Ceramist
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    • v.9 no.6
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    • pp.24-29
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    • 2006
  • Electron beam physical vapor deposition (EB-PVD) process has currently been applied to thermal barrier coatings (TBCs) for aircraft engines. Due to unique columnar structure, EB-PVD TBCs have advantages in resistances to thermal shock and thermal cycle for their applications, compared to films prepared by plasma spray By the EB-PVD equipment, we successfully obtained yttria-stabilized zirconia (YSZ) layer which has columnar and feather like structure including a large amount of nano size pores and gaps. The EB-PVD technique has been developed for coating functional perovskite type oxides such as (La, Sr)MnO3. Electrode properties have been improved by interface and structural control.

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Synthesis and Characterization of Dense Ceramic Membranes for Methane Conversion - Part II

  • Santos, A.;Fontes, V.A.;Fontes, F.A.Oliveira;De Sousa, J.F.;De Souza, C.P.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1112-1113
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    • 2006
  • The perovskite- type oxide $(ABO_3)$ containing transition metals on the B-site show mixed (electronic/ionic) conductivity. These mixed-conductivity oxides are promising materials for oxygen permeating membranes. The main objective of this research work is to synthesize and characterization ceramic powders of the Sr-Co-Fe-O system for methane conversion using membrane reactor. SCFO powders were synthesized from the route was based on the complex method of combination of acid EDTA and citrate and shown be available by control efficient of synthesis to performed $SrCo_{0.8}Fe_{0.2}O_{3-\delta$, moreover, it presented easy implementation, reproducibility and operation. Powder ceramic was characterized by XRD, microscopic optic, SEM and TG-DTA.

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SrAl2Si2O8 ceramic matrices for 90Sr immobilization obtained via spark plasma sintering-reactive synthesis

  • Papynov, E.K.;Belov, A.A.;Shichalin, O.O.;Buravlev, I. Yu;Azon, S.A.;Golub, A.V.;Gerasimenko, A.V.;Parotkina, Yu. А.;Zavjalov, A.P.;Tananaev, I.G.;Sergienko, V.I.
    • Nuclear Engineering and Technology
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    • v.53 no.7
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    • pp.2289-2294
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    • 2021
  • In the present study, an original spark plasma sintering-reactive synthesis (SPS-RS) method for minerallike ceramic materials based on SrAl2Si2O8 feldspar-like skeleton structure was used for the first time, promising solid-state matrices for reliable immobilization of high-energy 90Sr. The method is based on the "in-situ" reaction of a mixture of SrO, Al2O3 and SiO2 oxides when heated by a unipolar pulsed current under compacting pressure. The phase and elemental composition structure were studied. The dynamics of the consolidation of the reaction mixture of oxides was studied in the range of 900-1200 ℃. The study found the temperature of the high-speed (minutes) SPS-RS formation of single-phase SrAl2Si2O8 composition ceramic in the absence of intermediate reaction products with a relative density of up to 99.2% and compressive strength up to 145 MPa and a strontium leaching rate of 10-4g/cm2·day.

Analysis of Monoclinic Phase Change and Microstructure According to High-temperature Heat Treatment of Oxide-doped YSZ (산화물이 Doping된 YSZ의 고온 열처리에 따른 Monoclinic 상변화 및 미세구조 분석)

  • Gye-Won, Lee;Yong-Seok, Choi;Chang-Woo, Jeon;In-Hwan, Lee;Yoon-Suk, Oh
    • Journal of Powder Materials
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    • v.29 no.6
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    • pp.468-476
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    • 2022
  • Yttria-stabilized zirconia (YSZ) has a low thermal conductivity, high thermal expansion coefficient, and excellent mechanical properties; thus, it is used as a thermal barrier coating material for gas turbines. However, during long-time exposure of YSZ to temperatures of 1200℃ or higher, a phase transformation accompanied by a volume change occurs, causing the YSZ coating layer to peel off. To solve this problem, YSZ has been doped with trivalent and tetravalent oxides to obtain coating materials with low thermal conductivity and suppressed phase transformation of zirconia. In this study, YSZ is doped with trivalent oxides, Nd2O3, Yb2O3, Al2O3, and tetravalent oxide, TiO2, and the thermal conductivity of the obtained materials is analyzed according to the composition; furthermore, the relative density change, microstructure change, and m-phase formation behavior are analyzed during long-time heat treatment at high temperatures.