• Title/Summary/Keyword: Ceramic membrane

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Effect of Periodic Water-back-flushing Time ad Period in Water Treatment by Tubular Alumina Ceramic Microfiltration

  • Park, Jin-Yong;Lee, A-Reum
    • Korean Membrane Journal
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    • v.10 no.1
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    • pp.33-38
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    • 2008
  • In this study periodic water-back-flushing using permeate water was performed to minimize membrane fouling and to enhance permeate flux in tubular ceramic micro filtration system for Gongji stream water treatment in Chuncheon city. The filtration time (FT) 2 min with periodic 6 sec water-back-flushing showed the highest value of dimensionless permeate flux ($J/J_0$), and the lowest value of resistance of membrane fouling ($R_f$), and we acquired the highest total permeate volume ($V_T$) of 7.44L. Also in the results of BT effect at fixed FT 10 min, BT (back-flushing time) 20 sec showed the lowest value of $R_f$ and the highest value of $J/J_0$, and we could be obtained the highest $V_T$ of 8.04 L. Consequently FT 10 min and BT 20 sec could be the optimal condition in Gongji stream water treatment. Then the average rejection rates of pollutants by our tubular ceramic MF system were 93.8% for Turbidity, 20.7% for $COD_{Mn}$, 39.2% for $NH_3$-N and 31.5% for T-P.

Change of Phase Transformation Temperature at Fabricated Membrane using Sol-gel Method

  • Cheong, Hun;Choi, Duck-Kyun;Cheong, Deock-Soo
    • Journal of the Korean Ceramic Society
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    • v.38 no.10
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    • pp.876-880
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    • 2001
  • The supported and unsupported boehmite ($\gamma$-AlOOH) membranes were prepared using a boehmite sol. The supported membrane was consisted of a porcelain support, two intermediate $\alpha-{Al_2}{O_3}$ layers, and a top boehmite membrane. XRD patterns showed that the supported top membrane had a higher $\theta-$ to $\alpha-{Al_2}{O_3}$ transformation temperature compared to the unsupported membrane. This result was also confirmed from microstructural study of the membrane. The shift in the phase transformation temperature should be explained by difference of a stress generated in the supported top membrane due to interaction between the support layers and the top membrane.

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High Density Silver Nanowire Arrays using Self-ordered Anodic Aluminum Oxide(AAO) Membrane

  • Kim, Yong-Hyun;Han, Young-Hwan;Lee, Hyung-Jik;Lee, Hyung-Bock
    • Journal of the Korean Ceramic Society
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    • v.45 no.4
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    • pp.191-195
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    • 2008
  • Highly ordered silver nanowire with a diameter of 10 nm was arrayed by electroless deposition in a porous anodic aluminum oxide(AAO) membrane. The AAO membrane was fabricated electrochemically in an oxalic acid solution via a two-step anodization process, while growth of the silver nanowire was initiated by using electroless deposition at the long-range-ordered nanochannels of the AAO membrane followed by thermal reduction of a silver nitrate aqueous solution by increasing the temperature up to $350^{\circ}C$ for an hour. An additional electro-chemical procedure was applied after the two-step anodization to control the pore size and channel density of AAO, which enabled us to fabricate highly-ordered silver nanowire on a large scale. Electroless deposition of silver nitrate aqueous solution into the AAO membrane and thermal reduction of silver nanowires was performed by increasing the temperature up to $350^{\circ}C$ for 1 h. The morphologies of silver nanowires arrayed in the AAO membrane were investigated using SEM. The chemical composition and crystalline structure were confirmed by XRD and EDX. The electroless-deposited silver nanowires in AAO revealed a well-crystallized self-ordered array with a width of 10 nm.

Development of Steam Cleaning Technique to Improve Removal Efficiency of Membrane Fouling Matter in Water Treatment Process Using Ceramic Membrane (정수처리용 세라믹 분리막의 막오염 물질의 제거 효율 향상을 위한 스팀세정 기법 개발)

  • Kang, Joon-Seok;Park, Seo Gyeong;Lee, Jeong Eun;Kang, So Yeon;Lee, Jeong Jun;Quyen, Vo Thi Kim;Kim, Han-Seung
    • Journal of Korean Society of Water Science and Technology
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    • v.26 no.6
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    • pp.99-107
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    • 2018
  • This research has developed a high temperature steam cleaning technology using a ceramic membrane with durability against temperature and pressure conditions. In steam cleaning, steam of $120^{\circ}C$ is injected into the ceramic membrane to induce pyrolysis by the endothermic reaction to remove fouling from the membrane. The water quality of raw water was adjusted to turbidity 10, 25 NTU and DOC 2.5 mg/L, and the membrane was uniformly fouled by constant pressure operation at 100, 200, and 300 kPa. Physical backwashing was performed with water and air at a pressure of 500 kPa and steam at $120^{\circ}C$ was injected for 0 to 5 minutes. As the turbidity concentration and the operating pressure increased, the flux decreased by 0.7 to 14.4%. It is confirmed that 10.7 to 53.8% recovery is possible than physical cleaning at the injection of steam for 3 minutes, so it is considered that the steam cleaning of the ceramic membrane is effective. Compared with CEB after NaOCl (300 mg/L) filtration at 25 NTU and 300 kPa of turbidity, the steam cleaning result for 3 minutes was similar to 46.7% of CEB for 3 hours. It has been confirmed that steam cleaning is suitable for a ceramic membrane having excellent heat resistance against high temperature. It was considered to have better cleaning efficiency as compared with general physical backwashing.

Ceramic Based Photocatalytic Membrane for Wastewater Treatment: A Review (폐수처리를 위한 세라믹 기반 광촉매 분리막: 총설)

  • Kwak, Yeonsoo;Patel, Rajkumar
    • Membrane Journal
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    • v.32 no.3
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    • pp.181-190
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    • 2022
  • Membrane separation provides various advantages including cost effectiveness and high efficiency over traditional wastewater treatment methods such as flocculation and adsorption. However, the effectiveness of membrane separation greatly declines due to membrane fouling, where pollutants are accumulated on the membrane surface. Among different groups of membranes, ceramic membranes can provide good antifouling properties due to its hydrophilicity and chemical stability. In addition, composite membranes such as graphene oxide modified membranes can help prevent membrane fouling. Recently, hybrid photocatalytic membranes have been proposed as a solution to prevent membrane fouling and provide synergetic effects. Membrane separation can solve the disadvantages of photocatalytic oxidation such as low reutilization rate, while photocatalytic oxidation can help reduce membrane fouling.

Effect of Pre-ozonation on the Trans-membrane Pressure of Ceramic Membrane (전오존이 세라믹 막의 차압에 미치는 영향)

  • Bae, Byung-Uk
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.9
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    • pp.656-661
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    • 2011
  • The performance of a domestic ceramic membrane with pore size of $0.1{\mu}m$ was evaluated to produce drinking water. A pilot-scale ceramic membrane filtration plant with a capacity of $1m^3/d$ was operated at the filtration flux of $3.0m^3/m^2{\cdot}d$ to investigate the effect of both backwash interval and pre-ozonation on TMP (trans-membrane pressure) increasing rate. The TMP increased with increasing the backwash interval. However, the application of pre-ozonation reduced the TMP increasing rate remarkably. When 1 mg/L of ozone was dosed with contact time of 5 min, TMP increasing rate at the backwash interval of 1 hr was reduced by 30%. This result indicated that pre-ozonation was very effective in reducing membrane fouling. There was almost no change in TMP increasing rate when the ozone contact time was maintained in the range of 5 to 15 min. Increasing ozone concentration up to 3 mg/L showed beneficial effect on TMP increasing rate.

Effect of Water-back-flushing in Advanced Water Treatment System by Tubular Alumina Ceramic Ultrafiltration Membrane (관형 알루미나 세라믹 한외여과막에 의한 고도정수처리 시스템에서 물 역세척의 영향)

  • Park, Jin-Yong;Lee, Song-Hui
    • Membrane Journal
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    • v.19 no.3
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    • pp.194-202
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    • 2009
  • In this study periodic water-back-flushing using permeate water was performed to minimize membrane fouling and to enhance permeate flux in advanced water treatment by tubular ceramic ultrafiltration membrane for Gongji stream in Chuncheon city. The back-flushing period (FT, filtration time) 2 min with periodic water-back-flushing of 15 sec showed the highest value of dimensionless permeate flux (permeate flux vs. initial permeate flux), and the lowest value of resistance of membrane fouling. Also in the results of BT effect at fixed FT 10 min, BT (back-flushing time) 20 sec showed the lowest value of resistance of membrane fouling and the highest value of dimensionless permeate flux, and we could be obtained the highest total permeate volume of 107.3 L. Consequently FT 10 min and BT 20 sec could be the optimal condition in Gongji stream water treatment, which was the exactly same results of our previous tubular alumina microfiltration. Then the average rejection rates of pollutants by our tubular ceramic UF system were 97.0% for turbidity, 32.1 % for chemical oxygen demand by manganese method, 28.8% for ammoniac nitrogen and 54.4% for T-P.