• Title/Summary/Keyword: Ceramic media

Search Result 139, Processing Time 0.02 seconds

Synthesis and Sintering Behavior of Zr2WP2O12 Ceramics (Zr2WP2O12 세라믹스의 합성과 소결거동 연구)

  • Kim, Yong-Hyeon;Kim, Nam-Ok;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
    • /
    • v.49 no.6
    • /
    • pp.586-591
    • /
    • 2012
  • $Zr_2WP_2O_{12}$ powder, which has a negative thermal expansion coefficient, was synthesized by a solid-state reaction with $ZrO_2$, $WO_3$ and $NH_4H_2PO_4$ as the starting materials. The synthesis behavior was dependent on the solvent media used in the wet mixing process. The $Zr_2WP_2O_{12}$ powder prepared with a solvent consisting of D. I. water was fully crystallized at $1200^{\circ}C$, showing a sub-micron particle size. According to the results obtained from a thermal analysis, a $ZrP_2O_7$ was synthesized at a low temperature of $310^{\circ}C$, after which it was reacted with $WO_3$ at $1200^{\circ}C$. A new sintering additive, $Al(OH)_3$, was applied for the densification of the $Zr_2WP_2O_{12}$ powders. The cold isostatically pressed samples were densified with 1 wt% $Al(OH)_3$ additive or more at $1200^{\circ}C$ for 4 h. The main densification mechanism was liquid-phase sintering due to the liquid which resulted from the reaction with amorphous or unstable $Al_2O_3$ and $WO_3$. The densified $Zr_2WP_2O_{12}$ ceramics showed a relative density of 90% and a negative thermal expansion coefficient of $-3.4{\times}10^{-6}/^{\circ}C$. When using ${\alpha}-Al_2O_3$ as the sintering agent, densification was not observed at $1200^{\circ}C$.

A Study on Removal of Organics, Nitrogen and Phoschorus of Domestic Wastewater in Pilot-Scale Upflow Packed Bed Column Reactor (Pilot 규모의 상향류식 충전탑 반응기를 이용한 생활오수의 유기물 및 질소, 인 처리에 관한 연구)

  • Seon, Yong-Ho
    • KSBB Journal
    • /
    • v.22 no.4
    • /
    • pp.191-196
    • /
    • 2007
  • This study used biofilm process, which needs simple operation, maintenance and smaller facility area than conventional activated sludge process with the small plant operation, in the treatment of increasing sewage with the rapid industrial growth. The reactor used in this study consists of one anaerobic and one aerobic chamber filled with waste ceramic and waste vinyl as media and the treated sewage was from restaurant source. The experiment was scaled up from lab. to pilot scale and lasted for about 100 days. We focused on the removal efficiency of organics, nitrogen and phosphorus with constant HRT and continuous aeration. The removal efficiency of $BOD_5$ and SS were 94.33% and 87.77% respectively, which was a satisfaction level. However the removal efficiency of $COD_{Cr}$ was 81.46% somewhat below the desired level of 90%, and that of T-N and T-P showed 71.92% and 21.10% respectively, that was below the expected value. The removal efficiency of $COD_{Cr}$ and T-N in the pilot scale was about 10% low compared with the lab.-scale.

A Study on works converging Found objects: Focusing on how to mix the media (파운드 오브제(Found object)를 융복합한 작품연구: 매체의 활용방식을 중심으로)

  • Park, Kyungjoo
    • Journal of Digital Convergence
    • /
    • v.19 no.4
    • /
    • pp.227-233
    • /
    • 2021
  • Ready-made products produced in the industrialized consumer society after the 20th century have been adopted by artists as a new material called "Found object," and are reinterpreted in a broad sense in their works. The method of giving new meaning using this creates a new paradigm that is expanded conceptually as well as expression style. After Pablo Picasso's in 1912, when the Found object was used for the first time in contemporary art, we examine the development of objects through Dadaism, Surrealism, and Pop Art, and the expression of Found objects in the late 20th century. In this study, the artists and their work are analyzed by dividing it into three types: 'Unprocessed objects', 'Transformed objects', and 'Tenant objects', depending on how the Found object is mixed in works. Through this study, I pay attention to the fact that a work incorporating a Found object not only develops the object materially, but also allows the practice of free concept art to escape from the traditional norms of art.

Performance of High Temperature Filter System for Radioactive Waste Vitrification Plant (방사성폐기물 유리화 플랜트 고온여과시스템의 성능 특성)

  • Seung-Chul, Park;Tae-Won, Hwang;Sang-Woon, Shin;Jong-Hyun, Ha;Hey-Suk, Kim;So-Jin, Park
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
    • /
    • v.2 no.3
    • /
    • pp.201-209
    • /
    • 2004
  • Important operation parameters and performance of a high temperature ceramic candle filter system were evaluated through a series of demonstration tests at a pilot-scale vitrification plant. At the initial period of each test, due to the growth of dust cake on the surface of ceramic candles, the pressure drop across the filter media increased sharply. After that it became stable to a certain range and varied continuously proportion to the face velocity of off-gas. On the contrary, at the initial period of each test, the permeability of filter element decreased rapidly and then it became stable. Back flushing of the filter system was effective under the back flushing air pressure range of 3∼5 bar. Based on the dust concentrations measured by iso-kinetic dust sampling at the inlet and outlet point of HTF, the dust collection efficiency of HTF evaluated. The result met the designed performance value of 99.9%. During the demonstration tests including a hundred hour long test, no specific failure or problem affecting the performance of HTF system were observed.

  • PDF

Crystal Phase Changes of Zeolite in Immobilization of Waste LiCI Salt

  • KIM Jeong-Guk;LEE Jae-Hee;Lee Sung-Ho;KIM In-Tae;KIM Joon-Hyung;KIM Eung-Ho
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2005.11b
    • /
    • pp.176-181
    • /
    • 2005
  • The electrolytic reduction process and the electrorefining process, which are being developed at the Korea Atomic Energy Research Institute (KAERI), are to generate molten waste salts such as LiCI salt and LiCI-KCI eutectic salt, respectively. Our goal in waste salt management is to minimize a total waste generation and fabricate a very low­leaching waste form such as a ceramic waste form. Zeolite has been known to one of the most desirable media to immobilize waste salt, which is water soluble and easily radiolyzed. Zeolite can be also used to the removal of fission products from the spent waste salt. Molten LiCI salt is mixed with zeolite A at $650^{\circ}C$ to form a salt-loaded zeolite, and then thermally treated in above $900^{\circ}C$ to become an immobilized product with crystal phase of $Li_{8}Cl_{2}$-Sodalite. In this work, a crystal phase changes of immobilization medium, zeolite, during immobilization of molten LiCI salt using zeolite A is introduced.

  • PDF

Nitritation Characteristics Depending on Influent Nitrogen Concentration in a Biological Aerated Filter (Biological Aerated Filter에서 유입 질소농도에 따른 아질산화 특성)

  • Yoo, Ik-Keun
    • Journal of Korean Society on Water Environment
    • /
    • v.30 no.1
    • /
    • pp.1-7
    • /
    • 2014
  • The purpose of this study was to investigate the nitrification characteristics of biological aerated filter (BAF) packed with ceramic media, especially focusing on nitrite build-up during nitrification. When increasing the nitrogen load above $1.63kgNH_4{^+}-N/m^3{\cdot}d$, ammonium removal efficiency decreased to less than 60% and the nitrite ratio ($NO_2{^-}-N/NO_x-N$) of higher than 75% was achieved due to the inhibitory free ammonia (FA, $NH_3-N$) concentration and oxygen limitation. FA inhibition, however, is not recommended strategy to promote nitrite build-up since FA concentration in the reactor is coupled with decreased ammonium removal efficiency. Nitrite ratio in the effluent was also affected by aeration rate and influent ammonium concentration. Ammonium oxidation was enhanced at a higher aeration rate regardless of influent ammonium concentration but, the nitrite ratio was dependent on both aeration rate and influent ammonium concentration. While a higher nitrite ratio was obtained when BAFs were fed with $50mgNH_4{^+}-N/L$ of influent, the nitrite ratio significantly decreased for a greater influent concentration of $200-300mgNH_4{^+}-N/L$. Taken together, aeration rate, influent ammonium concentration and FA concentrations kept in the BAF were found to be critical variables for nitrite accumulation in the BAF system.

Multivariate Optimization of a Sulfated- β-Cyclodextrin-Modified Capillary Zone Electrophoretic Method for the Separation of Chiral Arylalcohols

  • Zhang, Yu-Ping;Noh, Hyun-Joo;Choi, Seong-Ho;Ryoo, Jae-Jeong;Lee, kwang-Pill;Ohta, Kazutoku;Fujimoto, Chuzo;Jin, Ji-Ye;Takeuchi, Toyohide
    • Bulletin of the Korean Chemical Society
    • /
    • v.25 no.3
    • /
    • pp.377-381
    • /
    • 2004
  • Chiral separation of aryalcohols such as 1-phenyl-propanol, 1-phenyl-2-proanol, and 2-phenyl-1-propanol by capillary electrophoresis has been optimized using the overlapping resolution mapping (ORM) scheme. Three critical parameters of the electrophoretic media, i.e. phosphate concentration, sulfated ${\beta}$-cyclodextrin (CD) concentration and pH, were chosen for optimization. The working ranges were initially presumed by 7 preexperiments. Further optimization was carried out by another seven experiments within the narrow working ranges. From the final overlapping resolution mapping all peak pairs, the area of maximum separations were located. Using the conditions of a point in this area, we found that the target compounds were a baseline separated within 30 min. The maximum separation conditions of arylalcohols were a chiral selector concentration of 5.4%, a phosphate concentration of 28 mM, and a pH of 5.0.

Art Therapy impact on the lives of the elderly study (미술치료가 노인의 생활에 미치는 영향에 대한 연구)

  • Kim, Sung-Min
    • Journal of Digital Convergence
    • /
    • v.11 no.9
    • /
    • pp.319-324
    • /
    • 2013
  • The old man has different characteristics than those which have ages. To experience a variety of different environments and has tendencies because. Therefore, all the old uniform to the progress of art therapy is not possible and when you feel the need for self-treatment is effective participation hayeoyaman looks. Art therapy through the medium of art to express the inner feelings that are kept on the image of the elderly because of the feelings that naturally help revealing, emotion plays a role in mitigating the crisis. Art therapy in the treatment of non-verbal means of means of self-defense, so receives less control is reduced. In addition, the opportunity to use art media sensation itself reduced stimulation of the elderly a sense of the way so you are valued as a very useful educational program.

The Development of Treatment System for Removing the Low Concentrated Nitrogen and Phosphorus Using Phototrophic Bacteria and Media (광합성 박테리아 및 담체를 이용한 하천의 저농도 질소, 인 처리 시스템 개발)

  • Kim, Sun-Jung;Lee, Sang-Seob
    • Korean Journal of Microbiology
    • /
    • v.46 no.1
    • /
    • pp.27-32
    • /
    • 2010
  • We used phototrophic bacteria to remove low concentrated organic materials (CODCr), nitrogen and phosphorus. We applied $COD_{Cr}$ 37.3 mg/L, $NH_3-N$ 4.0 mg/L, and $PO_4^{3-}-P$ 1.0 mg/L (C:N:P=100:10:1) in the batch test, and the removal efficiencies were shown as follow: $COD_{Cr}$ 87.4%, $NH_3-N$ 46.3%, $PO_4^{3-}-P$ 79.7%. The aerobic process with mixed phototrophic bacteria, ceramic media, and media KSP01 showed the removal efficiencies of $COD_{Cr}$, $NH_3-N$, and $PO_4^{3-}-P$, each as 72.7% and 79.2%, respectively in the lab-scale reactor. The maximum $PO_4^{3-}-P$ removal efficiency reached 92.6% by adjusting pH. There were three conditions used to remove $NH_3-N$. The highest removal efficiency was 98.5% with 10.2 L/min of aeration in 1-2 reactors, and the result of applying river-water showed the high removal efficiency of $NH_3-N$ (82.8%). Therefore, this purification system may be useful to control nitrogen and phosphorus at low concentration in field.

A Study of Ni-resistant bacteria isolated from gingival crevicular fluid on the patients wearing Ni-Cr alloy prosthesis (In terms of molecular biological aspects) (니켈-크롬 합금 보철물 주위 치은열구 내에서 발견된 니켈 내성 균주에 관한 분자생물학적 연구)

  • Chae, Young-Ah;Woo, Yi-Hyung;Choi, Boo-Byung;Choi, Dae-Gyun;Lee, Sung-Bok;Kwon, Kung-Rock
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.37 no.6
    • /
    • pp.741-755
    • /
    • 1999
  • As a material of metal-ceramic prosthesis, nickel as a form of Ni-Cr alloy has been used for many dental prostheses in many cases. However, several problems in use of the alloy have been revealed (ex : tissue stimulation, skin allergy, hypersensitivity, cytotoxicity and carcinogenecity). Little is known about nickel with respect to the relationship between Ni-prosthesis and gaining of Ni-resistance in oral microorganisms. The present study was undertaken to check wheather use of Ni-prosthesis leads to occurrence of Ni-resistant microorganisms. So this study may suggest the possible relationships between the oral microorganisms and nickel-resistance in oral environment. Bacteria were isolated from the gingival crevicular fluid on the pateints wearing Ni-Cr prosthesis. The isolated bacteria were tested for their Ni-resistance in nickel containing media at different concentration from 3mM to 110mM. E. coli HB101 was used as control. The Ni-resistant bacteria were isolated and biochemically identified. The Ni-resistant bacteria were tested several bio-chemical, molecular-biological tests. Performed tests were ; measuring the growth curve, antibiotic test, growth ability test in liquid media, isolation of the chromosome and plasmid, digestion of DNA by restriction enzyme, electrophoresis of chromosome and plasmid DNA, identification of Ni-resistant genes by the DNA hybridization. The results were as follows: 1) The bacteria isolated from gingival crevicular fluid on the patients wearing Ni-Cr alloy pros-thesis showed nickel-resistance. 2) The isolated microorganisms grew at nickel containing media of high concentrations (60mM-110mM). 3) Based on the biochemical tests, the isolated microorganisms were identified as Enterococcus faecalis(13 cases), Klebsiella pneumoniae(1 case) and Enterobacter gergeviae(1 case). 4) Enterococcus faecalis expressed not only nickel resistance but also the multi-drug resistance to several antibiotics ; chloramphenicol, kanamicin, streptomycin, lincomycin, clindamycin. However, all strain showed the sensitivity against the tetracycline. 5) DNA hybridization result suggest that there is no homology between the previousely known gene of nickel resistance in Klebsiella pneumoniae and chromosomal DNA of Enterococcus faecalis.

  • PDF