• 제목/요약/키워드: Ceramic foam

검색결과 72건 처리시간 0.028초

코발트망간 산화물/탄소나노섬유 복합전극의 수퍼케폐시터 특성 (CoMn Oxide/Carbon-nanofiber Composite Electrodes for Supercapacitors)

  • 김용일;윤여일;고장면
    • 한국세라믹학회지
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    • 제45권8호
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    • pp.493-496
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    • 2008
  • Composite electrodes consisting of $CoMnO_2$ and carbon nanofibers(vapor grown carbon nanofiber, VGCF) with high electrical conducivity($CoMnO_2$/VGCF) were prepared on a porous nickel foam substrate as a current collector and their supercapacitive properties were investigated using cyclic voltammetry in 1 M KOH aqueous solution. The $CoMnO_2$/VGCF electrode exhibited high specific capacitance value of 630 F/g at 5 mV/s and excellent capacitance retention of 95% after $10^4$ cycles, indicating that the used VGCF played the important roles in reducing the interfacial resistance in the composite electrode to improve supercapacitive performance.

감광유리를 이용한 MEMS 촉매 연소기의 제작 및 성능 평가 (Fabrication and Performance Test of MEMS Catalytic Combustors Using Photosensitive Glass Wafer)

  • 진정근;권세진
    • 대한기계학회논문집A
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    • 제33권3호
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    • pp.237-242
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    • 2009
  • MEMS catalytic combustors were fabricated to use in micro-power sources as a heat source. The combustor was fabricated by photolithography and anisotropic wet etching of photosensitive glass wafers. Two different catalyst loading methods were used to complete the fabrication of the combustors. For thin film type, the $Al_2O_3$ was washcoated on the surface of the combustion chamber as a catalyst support, and for packed-bed type, ceramic foam was inserted after Pt was coated. The volume of the combustors was 1.8 $cm^3$ and 16W of heat was generated using the fabricated combustors with hydrogen. The energy density of combustor was about 8.9 W/$cm^3$.

폼 형태의 다공성 탄화규소 지지체 표면 위에 ZSM-5 합성 (Synthesis of ZSM-5 on the Surface of Foam Type Porous SiC Support)

  • 정은진;이윤주;원지연;김영희;김수룡;신동근;이현재;권우택
    • Korean Chemical Engineering Research
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    • 제53권4호
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    • pp.425-430
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    • 2015
  • 고분자 복제방법을 이용하여 제조한 폼 형태의 다공성 탄화규소 표면에 수열 합성 방법을 적용하여 ZSM-5를 합성하였다. 다공성 탄화규소 표면으로부터 ZSM-5가 합성될 수 있도록 유도하기 위하여 합성단계에 앞서 탄화규소 표면에 산화 층을 형성하였다. 수열합성 반응은 산화처리 된 다공성 탄화규소와 TEOS, $Al(NO_3){\cdot}9H_2O$ 및 TPAOH를 원료로 사용하여 $150^{\circ}C$에서 7시간 진행하였다. XRD 및 SEM 분석을 통하여 $1{\sim}3{\mu}m$ 크기의 ZSM-5가 다공성 탄화규소 표면에 코팅되어 성장하였음을 확인하였다. BET 분석결과 ZSM-5 합성 후에 $10{\AA}$이하의 미세기공이 급격히 증가하였으며, 비표면적이 $0.83m^2/g$에서 $30.75m^2/g$으로 급격히 증가되었음을 알 수 있었다.

V2O5 - TiO2 촉매 담지된 세라믹 폼 필터를 이용한 NOx 제거 특성 (Characteristics of NOx Reduction Using V2O5 - TiO2Catalyst Coated on Ceramic Foam Filters)

  • 한요섭;김현중;박재구
    • 한국대기환경학회지
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    • 제20권6호
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    • pp.773-781
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    • 2004
  • Ceramic foams prepared from silica -clay were coated with TiO$_2$ and V$_2$O$_{5}$ catalysts for selective catalytic reduction of NOx with NH$_3$. The effects of V$_2$O$_{5}$ loading, reaction temperature, space velocity, and oxygen content on NOx reduction with NH$_3$ were mainly investigated. Also, the NOx reduction characteristics of V$_2$O$_{5}$ and V$_2$O$_{5}$ -TiO$_2$ filters were compared when sulfur dioxide exists. From the results, the optimal NOx reduction with the maximum reduction efficiency of 91 % could be performed under the condition with V$_2$O$_{5}$ loading 6.0 wt. %, reaction temperature 35$0^{\circ}C$, space velocity 6,000h$^{-1}$ , and oxygen content 5%. And, the V$_2$O$_{5}$ -TiO$_2$ filters have shown higher NOx reduction efficiency and acid resistance against sulfur dioxide than the V$_2$O$_{5}$ filters.

석탄 폐석을 이용한 발포유리의 제조 및 물리적 특성 연구 (A study on the fabrication of foamed glass by using refused coal ore and its physical properties)

  • 임태영;구현우;황종희;김진호;김정국
    • 한국결정성장학회지
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    • 제21권6호
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    • pp.266-273
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    • 2011
  • 삼척 도계지역의 탄광에서 석탄채취 시에 부산물로 발생되는 석탄폐석을 원료로 하여 제조된 분말유리와 다양한 종류의 발포제를 활용하여 발포유리를 제조하였다. 유리는 소다라임계 화학조성을 갖는 유리였고, 유리분말에 발포제로서 탄산칼슘, 인산칼슘, 그리고 석탄폐석 중 카본함량이 높은 셰일(shale) 계의 석탄폐석분말을 사용하였고, 이들 원료에 액상 바인더를 첨가하여 혼합한 후, 판상의 형태로 성형하였다. 성형체를 건조한 후 전기로에서 $800^{\circ}C$ 20분간 열처리함으로써 다공성의 발포유리 패널을 제조할 수 있었다. 발포제의 종류에 따라 다양한 특성을 갖는 발포유리샘플이 제조되었으며, 이들의 비중 및 압축강도와 같은 물리적 특성을 측정하였고, 기공의 크기 및 형태를 현미경으로 관찰하였다. 석탄폐석으로 제조한 폐유리를 활용하여 비중 0.4~0.7, 압축강도 30~72 kg/$cm^2$를 갖는 발포유리 샘플을 얻을 수 있었으며, 특히 액체인산 칼슘 발포제를 사용하여 0.47의 낮은 비중과 72 kg/$cm^2$의 높은 압축강도를 갖는 발포유리를 얻을 수 있었다. 따라서 삼척지역에 폐기된 다량의 석탄폐석이 건축용 및 산업용 발포유리 2차 제품을 제조하는데 충분히 활용이 가능하리라 판단되었다.

세라믹스의 축열연소시스템 응용 (Ceramic Application for Regenerative Burner System)

  • 한동빈;박병학;김영우;배원수
    • 한국세라믹학회지
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    • 제36권5호
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    • pp.497-503
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    • 1999
  • Recently regenerative burner system was developed and begins to be gradually used for better energy savings. Compared to conventional burner system the regenrative one has the several merits such as higher fuel efficiency light weigh of apparatus low harmful toxic gas and homogeneous heating zone etc. The regenerative material a very important component of the new regenerative burner system should possess the properties of low specific density higher surface area and high specific heat capacity. Ceramics is the best regenerative material because of stable mechanical properties even at high temperature and better thermal properties and excellent chemical stability. In this study alumina ball alumina tube 3-D ceramic foam and hoeycomb as regenerative materials were tested and evaluated. The computer silumation was conducted and compared to the result of field test. This paper is aimed to introduce a new application of ceramics at high temperature.

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Diesel Particulate Filter의 특성 및 제조방법(II) (Fabrication and Characteristics of Diesel Particulate Filters(II))

  • 양진
    • 멤브레인
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    • 제8권4호
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    • pp.191-202
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    • 1998
  • 경유자동차에서 발생하는 입자상물질은 대기오염의 주범으로 인식되어 국내외적으로 이의 규제가 점점 강화되고 있다. 본 고에서는 전 호에 이어 이러한 입자상물질을 제거하기 위하여 가장 보편적으로 사용되는 필터인 세라믹 하니컴 필터에서의 기공 및 필터특성의 조절과 설계에 대하여 언급하였다. 또한 그 외 각종 필터, 즉 세라믹 화이버 캔들 필터, 세라믹 폼 필터, 세라믹 크로스 플로우 필터 그리고 금속 필터 등의 성능 및 제조방법을 정리하였다. 이와같이 후처리장치용 필터로는 수없이 많은 필터들이 개발되어 많은 실증시험을 거치고 있으나 이러한 필터의 본격적인 상용화를 위하여는 재료 측면에서의 보다 많은 연구, 개발이 뒤따라야 할 것으로 판단된다.

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수증기 메탄 개질 반응을 이용한 수소 생산용 Ni-Cr-Al 다공체 지지 촉매의 제조, 기계적 안정성 및 수소 환원 효율 (Fabrication of Ni-Cr-Al Metal Foam-Supported Catalysts for the Steam Methane Reforming (SMR), and its Mechanical Stability and Hydrogen Yield Efficiency)

  • 김규식;강태훈;공만식;박만호;윤중열;안지혜;이기안
    • 한국분말재료학회지
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    • 제28권3호
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    • pp.201-207
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    • 2021
  • Ni-Cr-Al metal-foam-supported catalysts for steam methane reforming (SMR) are manufactured by applying a catalytic Ni/Al2O3 sol-gel coating to powder alloyed metallic foam. The structure, microstructure, mechanical stability, and hydrogen yield efficiency of the obtained catalysts are evaluated. The structural and microstructural characteristics show that the catalyst is well coated on the open-pore Ni-Cr-Al foam without cracks or spallation. The measured compressive yield strengths are 2-3 MPa at room temperature and 1.5-2.2 MPa at 750℃ regardless of sample size. The specimens exhibit a weight loss of up to 9-10% at elevated temperature owing to the spallation of the Ni/Al2O3 catalyst. However, the metal-foam-supported catalyst appears to have higher mechanical stability than ceramic pellet catalysts. In SMR simulations tests, a methane conversion ratio of up to 96% is obtained with a high hydrogen yield efficiency of 82%.

수모델 실험을 이용한 전통 탕구계의 유동 양상에 미치는 필터의 영향 연구 (A Study on the Effects of the Filter on Flow Pattern of the Traditional Gating System by the Water Modeling Experiment)

  • 황호영;남철희;최영심;홍준호
    • 한국주조공학회지
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    • 제36권6호
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    • pp.208-214
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    • 2016
  • Casting defects, which are closely related to entrapped air bubbles and metallic oxides, occur very frequently in the casting process. Many researchers have shown that these defects can be reduced by adopting an appropriate gating system design. But, it is difficult for field engineers to identify a specific gating system that is more appropriate for their products. In this study, we tried to draw a comparison of gating system designs with and without ceramic foam filters. A ceramic foam filter was added to the horizontal runner just after the sprue to prevent air bubble generation and to reduce turbulence without change of the gating system design. To verify the effects of initial pouring velocity, the experiment was conducted with four different amounts of water volume in the reservoir. Results of the water modeling experiment applying the filter showed remarkably changed flow characteristics. Although the study confirmed that use of the filter may change the flow characteristics, it needs to be noted that only filter use alone cannot solve all the problems caused by a poorly designed gating system.