• Title/Summary/Keyword: Ceramic coating film

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Characterization of Environment-Friendly Ceramic Coating Materials (친환경적인 분말형 세라믹 페인트의 특성평가)

  • 이제철;신영훈;김태현
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.521-526
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    • 2002
  • In this paper, we described about the characteristic evaluation of environment-friendly ceramic paint with calcium-silicate mineral as a main binder. Particularly, we performed discharge of the environmental poisoning materials(e.g. VOCs, heavy metal, etc.), and properties of paint slurry and coating film of the ceramic paint. In the comparison of the ceramic paint with natural paint and mineral paint which were known as our environment-friendly paints, ceramic paint had good characteristics in the environmental safety and properies of wet slurry and dried coating film.

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Fabrication of Transparent Color Coating Glass by Sol-gel Method (솔-젤법을 이용한 투명 칼라 코팅유리 제조)

  • Park, Jong-Guk;Jeon, Dae-Woo;Lee, Mi-Jai;Lim, Tea-Young;Hwang, Jonghee;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.1
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    • pp.40-43
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    • 2016
  • Transparent color coating films were fabricated on a glass substrate by using sol-gel hybrid binder and organic dye. Sol-gel hybrid binder coating film fabricated with PTMS of 0.03 mole showed a very high pencil hardness of 9 H. As the withdrawal speed increased from 1.0 mm/s to 5.0 mm/sec, The yellowness ($b^*$) of coating glass also gradually increased. The transmittance of yellow color coating glass was 82.6% and the haze of coating glass was 0.35%. Red and blue color coating glasses also showed the high transmittance of 62.4% and 80.6% respectively. The surface hardness of color coating films was 6 H.

Manufacturing and Characterization of Organic-Inorganic Hybrid Coating Film Using Sol-Gel Method (Sol-Gel법을 이용한 유무기 하이브리드 코팅막 제조 및 특성평가)

  • Seungwon Cho;Dabin Kim;Ji-Sun Lee;Dongwook Shin;Jinho Kim
    • Korean Journal of Materials Research
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    • v.34 no.9
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    • pp.439-447
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    • 2024
  • Organic-inorganic hybrid coating films have been used to increase the transmittance and enhance the physical properties of plastic substrates. Sol-gel organic-inorganic thin films were fabricated on polymethylmethacrylate (PMMA) substrates using a dip coater. Metal alkoxide precursor tetraethylsilicate (TEOS) and alkoxy silanes including decyltrimethoxysilane (DTMS), 3-glycidoxypropyltrimethoxysilane (GPTMS), phenyltrimethoxysilane (PTMS), 3-(trimethoxysilyl)propyl methacrylate (TMSPM) and vinyltrimethoxysilane (VTMS) were used to synthesize sol-gel hybrid coating solutions. Sol-gel synthesis was confirmed by the results of FT-IR. Cross-linking of the Si-O-Si network during synthesis of the sol-gel reaction was confirmed. The effects of each alkoxy silane on the coating film properties were investigated. All of the organic-inorganic hybrid coatings showed improved transmittance of over 90 %. The surface hardness of all coating films on the PMMA substrate was measured to be 4H or higher and the average thickness of the coating films was measured to be about 500 nm. Notably, the TEOS/DTMS coating film showed excellent hydrophobic properties, of about 97°.

Preparation of Silicon Carbide Ceramic Thick Films by Liquid Process (액상공정을 이용한 탄화규소 세라믹 후막의 제조)

  • Kim, Haeng-Man;Kim, Jun-Su;Lee, Hong-Rim;Ahn, Young-Cheol;Yun, Jon-Do
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.95-99
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    • 2012
  • Silicon carbide ceramics are used for oxidation resistive coating films due to their excellent properties like high strength, good oxidation resistance, and good abrasion resistance, but they have poor formability and are prepared by vapor process which is complicated, costly, and sometimes hazardous. In this study, preparation of silicon carbide coating film by liquid process using polymer precursor was attempted. Coating film was prepared by dip coating on substrate followed by heat treatment in argon at $1200^{\circ}C$. By changing the dipping speed, the thickness was controlled. The effects of plasticizer, binder, or fiber addition on suppression of crack generation in the polymer and ceramic films were examined. It was found that fiber additives was effective for suppressing crack generation.

Microstructure analysis of DLC thin film fabricated by filtered arc ion plating method

  • Park, Y.P.;Kim, T.G.;Cheon, M.W.
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.363-367
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    • 2012
  • DLC (diamond liked carbon) coating of the tungsten carbide (WC) alloy core surface for molding a glass aspheric lens improves the quality of glass lens and the molding core and is characterized by high hardness, high elasticity, abrasion resistance and chemical stability. In this study, the effect of DLC coating of a thin film by means of the filtered AIP (arc ion plating) technique was examined on Ra and shape of the coated surface. Roughness before and after DLC coating was measured and the result showed that the roughness was improved after coating as compared to before coating. It was observed that DLC coating of the WC alloy core surface for molding had an effect on improving the roughness and shape of the core surface. It is considered that this will have an effect on improving abrasion resistance and the service life of the core surface.

Anti-fouling Properties of Functional Coating according to the Film Thickness and its Application to the Insulators for Electrical Railway (코팅막의 두께에 따른 기능성 코팅의 내오염 특성 분석 및 전기철도용 애자로의 활용)

  • Shan, Bowen;Kang, Hyunil;Choi, Wonseok;Kim, Jung Hyun
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.66 no.2
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    • pp.94-97
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    • 2017
  • A method of improving the anti-fouling characteristics of porcelain insulators was proposed in this study. Functional coating was performed as a method of reducing the surface contamination of the porcelain insulators. The functional coating was applied on a ceramic substrate, which has the same material as the porcelain insulators. After coating the ceramic substrate 2, 3, 4, and 5 times alternately in the horizontal and vertical directions, the surface characteristics according to the thickness of the coating film were analyzed. The optimal process was selected to coat the surfaces of the post insulators and long rod insulators, which are the representative porcelain insulators. After coating, heat treatment was performed for 1 hour at $200^{\circ}C$ in a furnace to secure the durability of the coating film. Compared to the uncoated insulators, the insulators with the functional coating showed significantly improved anti-fouling characteristics as well as excellent adhesion to the coated insulator surface.

Comparison of plasma resistance between spray coating films and bulk of CaO-Al2O3-SiO2 glasses under CF4/O2/Ar plasma etching (CaO-Al2O3-SiO2 계 벌크 유리와 스프레이 코팅막의 CF4/O2/Ar 플라즈마 식각 시 내식성 비교)

  • Na, Hyein;Park, Jewon;Park, Jae-Hyuk;Kim, Dae-Gun;Choi, Sung-Churl;Kim, Hyeong-Jun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.2
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    • pp.66-72
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    • 2020
  • The difference of plasma resistance between the CAS glass bulk and coating films were compared. Plasma resistance was confirmed by analyzing the etch rate and the microstructure of the surface when the CAS glass bulk and the glass coating film were etched with CF4/O2/Ar plasma gas. CAS glass coating film was etched up to 25 times faster than the glass bulk. A statistically high correlation between the surface roughness and the etching rate of the coating film was derived, and thus, the high surface roughness of the coating film was determined to cause rapid etching. In addition, cristobalite crystals that has a low Ca content and a high Si content, was foamed on the glass coating film. Therefore, the CAS glass coating film is considered to have low plasma resistance compared to the glass bulk.

A Study on the Improvement of Oxidation and Corrosion Resistance of Stainless Steel by Sol-Gel Ceramic Coating; (I) Synthesis of Zirconia Sol and Fabrication of Its Thin Film (졸-겔 세라믹 코팅에 의한 스테인레스강의 내산화 및 내식성 향상에 관한 연구;(I) 지르코니아 졸의 합성 및 박막의 제조)

  • Kim, Byong-Ho;Hong, Kwon;Shin, Dong-Won
    • Journal of the Korean Ceramic Society
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    • v.31 no.9
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    • pp.1060-1068
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    • 1994
  • Stable zirconia sol was prepared from zirconium butoxide Zr(OC4O9)4 as a precursor and ethylacetoacetate(EAcAc) or diethylene glycol(DEG) as a chelating agent under ambient agent under ambient atmosphere by Sol-Gel process. The sythesized sol was coated on 304 stainless steel substrate by dip coating, thereafter zirconia film could be obtained by heat-treatment at $600^{\circ}C$. The characteristics of coating film were determined by FT-IR, XRD, and ellipsometion peak represented Zr-O-Zr bonding of tetragonal phase was shown at 470cm-1. Crystallization of zirconia gel and film from amorphous state to tetragonal phase started at 40$0^{\circ}C$, and then transformed into monoclinic phase around $700^{\circ}C$. Zirconia film coated on 304 stainless steel substrate showed relatively low porosity of 16% when it was coated with 0.4M zirconia sol and thereafter heat-treated at 80$0^{\circ}C$ and the film was densified continuously up to 90$0^{\circ}C$. The zirconia film of 10 nm thick acted as a protective layer against oxidation up to $700^{\circ}C$.

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Fabrication of Single Layer Anti-reflection Thin Film by Sol-gel Method (Sol-gel법에 의한 단층 반사 방지막 제조)

  • Park, Jong-Guk;Jeon, Dae-Woo;Lee, Mi-Jai;Lim, Tea-Young;Hwang, Jonghee;Bae, Dong-Sik;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.12
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    • pp.821-825
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    • 2015
  • Anti-reflective (AR) thin film was fabricated on a glass substrate by sol-gel method. The coating solution was synthesized with TEOS (tetraethlyorthosilicate) and poly ethylene glycol (PEG, 4.0 wt%). As the withdrawal speed of coating was changed from 0.1 mm/sec to 0.3 mm/sec, the thickness and refractive index of prepared thin films were changed. The reflectance and transmittance of coating glass fabricated by the withdrawal speed of 0.1 mm/sec were 0.62% and 95.0% in visible light range. The refractive index and thickness of single layer thin film were n= 1.29 and ca. 99.0 nm.