• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.427-431
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• 2001

In this research, porous materials were made from mine's waste slime. As a temperature changes, a phase changes, a porosity, and a mechanical strength of porous materials were observed and measured. The process of pore-formation was observed by SEM according to the change of heat-treatment temperature and time. It fumed out that the foaming reaction of mine's waste slime was resulted from liquid phase by decomposition of the sanidine and the muscovite-3T. When heat- treated at over 120$0^{\circ}C$, it appeared high porosity. And, to activate the foaming reaction, an alkaline oxide concerned with liquid formation was added and its effects were examined.

• Resources Recycling
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• v.31 no.5
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• pp.52-58
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• 2022

Silicon carbide powder was prepared from carbon black and silicon recovered from waste solar panels. In the solar power generation market, the number of crystalline silicon modules exceeds 90%. As the expiration date of a photovoltaic module arrives, the development of technology for recovering and utilizing silicon is very important from an environmental and economic point of view. In this study, silicon was recovered as silicon carbide from waste solar panels: 99.99% silicon powder was recovered through purification from a 95.74% purity waste silicon wafer. To examine the synthesis characteristics of SiC powder, purified 99.99% silicon powder and carbon powder were mixed and heat-treated (1,300, 1,400 and 1,500 ℃) in an Ar atmosphere. The characteristics of silicon and silicon carbide powders were analyzed using particle size distribution analyzer, XRD, SEM, ICP, FT-IR, and Raman analysis.

• Journal of the Korean Ceramic Society
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• v.46 no.3
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• pp.275-281
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• 2009

Porous materials were manufactured by hydrothermal treatment of waste bottle glass without foam agent. Factorial design was applied to analyze data by statistical methods and deal with the important factors for a process. The largest effect for porosity was for temperature of hydrothermal treatment. Amount of water and temperature-water interaction appeared to have little effect. The particle size of raw material was also identified as a major factor by one-way ANOVA and the porosity decreased as the size increased. The sintering temperature was not statistically significant for the porosity but was significant for the pore size. The porous material had compressive strength and thermal conductivity comparing with those of ALC (autoclaved lightweight concrete), although it has higher porosity than for ALC.

• Journal of the Korean Ceramic Society
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• v.31 no.11
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• pp.1387-1395
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• 1994

Re-hydration properties of heated and ground CaO-SiO2-H2O system were studied under hydrothermal condition in order to examine the possibility of recycling ALC waste as raw materials of ALC. Powder of calcium silicate hydrates and ALC waste without heat treatment did not show further hydration while those of heat-treated at proper temperature showed re-hydration properties under hydrothermal condition. The lath-like shape of initially synthesized tobermorite was gradually turned into small debris during heating and plate-like tobermorite was crystallized during re-hydration of the heated powders. Heated and ground ALC waste could be added to natural raw mix for ALC at the ammount up to 20% with increased compressive strength and up to 30% with slightly decreased compressive strength. The optimum heating temperature of ALC for recycling was about 50$0^{\circ}C$.

• Journal of Ceramic Processing Research
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• v.19 no.6
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• pp.472-478
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• 2018

In this study, the sintering mechanism of woodceramics (WCs) from cashew nut shell waste (CNSW) was studied by analyzing chemical reactions and structural changes during the sintering process of of CNSW powder, liquefied wood and green bodies of WCs at $900^{\circ}C$ for 60 minutes in the $CO_2$ atmosphere. The chemical and structural properties of the products were investigated by X-ray diffraction (XRD), Raman spectroscopy, Fourier Transform Infrared (FTIR), and scanning electron microscope (SEM). The results showed that the decomposition reactions of liquefied wood and CNSW occurred simultaneously to form the hard carbon and the soft carbon at high temperature. The sintering mechanism of WCs has been presented.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.10 no.3
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• pp.219-228
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• 2012

A long-term R&D program for HLW disposal technology development was launched in 1997 in Korea and Korea Reference disposal System(KRS) for spent fuels had been developed. After then, a recycling process for PWR spent fuels to get the reusable material such as uranium or TRU and to reduce the volume of radioactive waste, called Pyro-process, is being developed. This Pyro-process produces several kinds of wastes including metal waste and ceramic waste. In this study, the characteristics of the waste from Pyro-process and the concepts of a disposal container for the wastes were described. Based on these concepts, thermal analyses were carried out to determine a layout of the disposal area of the ceramic wastes which was classified as a high level waste and to develop the disposal system called A-KRS. The location of the final repository for A-KRS is not determined yet, thus to review the potential repository domains, the possible layout in the geological characteristics of KURT facility site was proposed. These results will be used in developing a repository system design and in performing the safety assessment.

• Journal of the Korean Ceramic Society
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• v.53 no.6
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• pp.659-664
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• 2016

Ash deposition of heat exchange boiler, caused mainly by accumulation of particulate matter, reduces heat transfer of the boiler system. Heat and mass transfer through porous media such as ash deposits mainly depend on the microstructure of deposited ash. Therefore, in this study, we investigated microstructural and thermal properties of the ash deposited on the boiler tube. Samples for this research were obtained from the fuel economizer tube in an industrial waste incinerator. To characterize microstructures of the ash deposit samples, scanning electron microscope (SEM), energy-dispersive spectroscopy (EDS), inductively coupled plasma optical emission spectroscopy (ICP-OES), X-ray diffraction (XRD) and BET analysis were employed. The results revealed that it had a porous structure with small particles mostly of less than a few micrometers; the contents of Ca and S were 19.3, 22.6% and 18.5, 18.7%, respectively. Also, the results showed that it consisted mainly of anhydrite ($CaSO_4$) crystals. - The thermal conductivities of the ash deposit sample obtained from the economizer tube in industrial waste incinerator were measured to be 0.63 and 0.54 W/mK at $200^{\circ}C$, which were about 100 times less than the thermal conductivity (61.32 W/mK) of the boiler tube itself, indicating that ash deposition on the boiler tube was closely related to a decrease in boiler heat transfer.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.8 no.1
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• pp.49-56
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• 2010

In the pyroprocessing of spent nuclear fuels, LiCl-KCl waste salt containing radioactive rare earth chlorides are generated. The radioactive rare earth oxides are recovered by co-oxidative precipitation of rare earth elements. The powder phase of rare eath oxide waste must be immobilized to produce a monolithic wasteform suitable for storage and ultimate disposal. The immobilization of these waste developed in this study involves a solid state sintering of the waste with host borosilicate glass and zinc titanate based ceramic matrix(ZIT). And the rare-earth monazite which synthesised by reaction of ammonium di-hydrogen phosphate with the rare earth oxides waste, were immobilzed with the borosilicate glass. It is shown that the developed ZIT ceramic wasteform is highly resistant the leaching process, high density and thermal conductivity.

• Journal of Powder Materials
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• v.23 no.3
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• pp.221-227
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• 2016

Waste oyster shells create several serious problems; however, only some parts of them are being utilized currently. The ideal solution would be to convert the waste shells into a product that is both environmentally beneficial and economically viable. An experimental study is carried out to investigate the recycling possibilities for oyster shell waste. Bulk ceramic bodies are produced from the oyster shell powder in three sequential processes. First, the shell powder is calcined to form calcium oxide CaO, which is then slaked by a slaking reaction with water to produce calcium hydroxide $Ca(OH)_2$. Then, calcium hydroxide powder is formed by uniaxial pressing. Finally, the calcium hydroxide compact is reconverted to calcium carbonate via a carbonation reaction with carbon dioxide released from the shell powder bed during firing at $550^{\circ}C$. The bulk body obtained from waste oyster shells could be utilized as a marine structural porous material.

• Journal of the Korean Ceramic Society
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• v.43 no.3 s.286
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• pp.148-151
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• 2006

In order to examine the process parameters for the vitrification of Low and Intermediate Level radioactive Waste (LILW) generated from nuclear power plants, measurements of several melt properties was performed for four selected glasses containing simulated waste. Electrical conductivity and viscosity were determined at temperatures ranging from 1123 to $1673^{\circ}C$. The temperature dependences of both properties in the molten state showed a similar behavior in which their values decrease as the temperature increases. The values of the electrical conductivity and viscosity at a temperature of 1423K adopted in an induction cold crucible melter process were $0.27{\sim}0.42$ S/cm and $9.8{\sim}42$ dPas, respectively.