• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.3
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• pp.276-286
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• 2021

General high fluidity concrete is the area of high strength concrete with a high amount of cement to secure the required fluidity and workability. Since most of the concrete structures currently used have normal strength, there is a limit to the practical expansion and practicality of use. Thus it is necessary to develop normal strength-high fluidity concrete with low binders that can be used not only in general buildings but also in special buildings, and can greatly reduce construction time and save labor costs. This requires to develop and apply the polycarboxylate-based superplasticizer. In this study, PCE was prepared for each combination of starting materials(WR, HB, RT) and the rheological properties of cement paste were analyzed using ringflow cone and a rotary viscometer. As a result, when PCE with a combination of WR 80%, HB 6.5%, and RT 13.5% was applied, the yield stress can be minimized while securing the plastic viscosity at level of the normal strength. In addition, high fluidity due to the high dispersion effect was confirmed.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.3
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• pp.268-275
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• 2021

The three factors that determine the strength of concrete are the strength of cement paste, aggregate and ITZ(Interfacial Transition Zone) between aggregate and cement paste. Out of these, the strength of ITZ is the most vulnerable. ITZ is formed in 10~50㎛, the ratio of calcium hydroxide is high, and CSH appears low ratio. A high calcium hydroxide ratio causes a decrease in the bond strength of ITZ. ITZ is due to further weak area. The problem of ITZ appears as a more disadvantageous factor when it used lightweight aggregate. The previous study of ITZ properties have measured interfacial toughness, identified influencing factors ITZ, and it progressed SEM and XRD analysis on cement matrix without using coarse aggregates. also it was identified microstructure using EMPA-BSE equipment. However, in previous studies, it is difficult to understand the microstructure and mechanical properties. Therefore, in this study, a method of measuring electrical resistance using EIS(Electrochemical Impedance Spectroscopy) measuring equipment was adopted to identify the ITZ between natural aggregate and lightweight aggregate, and it was tested the change of ITZ by surface coating of lightweight aggregate with ground granulated blast furnace slag. As a result, the compressive strength of natural aggregate and lightweight aggregate appear high strength of natural aggregate with high density, surface coating lightweight aggregate appear strength higher than natural aggregate. The electrical resistivity of ITZ according to the aggregate appeared difference.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.1
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• pp.29-36
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• 2019

This study investigated the self-healing properties of blast furnace slag cement paste sample with $Na_2SO_4$ as a blast furnace slag activator after conducting the permeability test. Self-healing properties were examined by crack filling ratio and quantification of self-healing products. The degree of self-healing was evaluated by the crack filling ratio, and the crack filling ratio was analyzed by panoramic analysis using BSE-DIP for objectivity. The average crack filling ratio showed a tendency of decreasing from the upper part of the specimen to the lower part as the average of the top part was 18%, the middle part was 7% and the bottom part was 5% on average. The maximum crack filling ratio was 44% and the minimum crack filling ratio was 3%. The residual self-healing product after the permeability test contained a large amount of Ca element and Al element derived from the blast furnace slag, and the Si element was mainly present near the crack surface. The most abundant minerals in self-healing products were about 68% C-A-H. $CaCO_3$ was about 13% and C-A-S-H was about 8%. Three minerals accounted for 90% of self-healing products. C-A-H was mainly present at a part slightly distant from the crack surface and showed an angular or acicular shape. The C-A-S-H was generated on the surface naturally connected to the existing specimen, and the $CaCO_3$ was generally observed on the surface of the specimen or the inside of the crack.

• Journal of the Korea Institute of Building Construction
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• v.22 no.3
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• pp.251-258
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• 2022

In the cement industry, in order to reduce CO₂ emissions, technology for raw materials substitution and conversion, technology for improving process efficiency of utilizing low-carbon new heat sources, and technology for collecting and recycling process-generated CO₂ are being developed. In this study, we conducted a basic experiment to contribute to the development of CSC that can store CO₂ as carbonate minerals among process-generated CO₂ capture and recycling technologies. Three types of CSC clinker with different SiO₂/(CaO+SiO₂) molar ratios were prepared with the clinker raw material formulation, and the characteristics of the clinker were analyzed. As a result of analysis and observation of CSC clinker, wollastonite and rankinite were formed. In addition, as a result of the carbonation test of the CSC paste, it was confirmed that calcite was produced as a carbonation product. The lower the SiO₂/(CaO+SiO₂) molar ratio in the CSC clinker chemical composition, the lower the wollastonite production amount, and the higher the rankinite production amount. And the amount of calcite production increased with the progress of carbonation of the CSC paste specimen. It is judged that rankinite is more reactive in mineralizing CO₂ than wollastonite.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.227-234
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• 2022

In this study, the rheological properties of cement paste composites applied with carbon-based nano-materials were experimental analyzed. Flow table and rheological properties, compressive strength were measured in the cement paste using graphene oxide asqueous solution and carbon nanotube aqueous solution. When carbon nano-materials was mixed in an aqueous solution, flow decreased and plastic viscosity and shear stress were increased. In particular, graphene oxide rapidly increased the plastic viscosity and shear stress. In the case of carbon nanotube aqueous solution, when less than 0.2 % was mixed, the increase rate was low compared to graphene oxide. This is because the specific surface area of graphene, which is in the form of a plate, is large. The compressive strength showed a small amount in strength increase when graphene mix, and CNT had a strength about 112 % of OPC. Carbon-based nanomaterials, is considered that CNT are suitable more to be used construction materials. However, extra studies on the surfactant to be used for mixing proportion and dispersion will be needed.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.349-354
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• 2023

This study wa s conducted a s pa rt of ma ximizing the use of ca rbon dioxide by a pplying CCU(Ca rbon Ca pture, Utiliza tion) a mong technologies for reducing CO₂ in the cement industry. In a carbon dioxide curing environment, changes in carbonation depth and changes in basic physical properties by age due to the mixing of carbonation reaction accelerators were usually targeted at Portland cement paste. In addition, in order to check the fixed amount of CO₂ in the concrete field, a thermal analysis method was applied to evaluate CaCO₃ decarbonization at high temperatures. As a result of the evaluation, it was confirmed that the carbonation depth in the cured body significantly increased due to the incorporation of CRA in the carbonation depth diffusion performance. In addition, it was confirmed that the weight reduction rate increased by 23.8 % and 40.77 %, respectively, compared to Plain, in the order of curing conditions for constant temperature and humidity and curing conditions for carbonation chambers, so it was confirmed that the amount of excellent CaCO₃ produced by the addition of CRA increased as the concentration of CO₂ increased.

• Journal of the Korean Society of Safety
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• v.29 no.5
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• pp.116-122
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• 2014

Assessment of setting process of concrete is important as it provides useful information to schedule concreting work in construction site. Electrical impedance measurement method, which utilizes the change of electrical resistance of concrete, has been applied to assess setting process of cement-based materials. However, the applicability of the method has been demonstrated only for cement paste and mortar. The main purpose of this research is to develop the electrical impedance based setting process assessment for concrete. To this end, electrical impedance response model for concrete should be developed in advance since it is essential to estimate the electrical resistance of concrete from measured impedance response. The electrical resistance of concrete is a key parameter for the setting process assessment. In this study electrical impedance responses of the concrete in setting process are measured and analyzed. Thereby, an electrical impedance response model of the liquid state concrete is developed and schematically validated.

• Cement
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• s.66
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• pp.12-15
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• 1977

석회석과 고로수재 slag을 1.6 : 1로 혼합 분쇄한 원료를 1,450$^{\circ}C$에서 소결하여 고$C_3A$ clinker를 얻었다. 이 clinker 중에는 $C_3S$ 40$\%$, $C_2S$ 31$\%$, $C_3A$ 22$\%$, $C_4AF$ 2$\%$를 함유하고 있으며 보통 크링카 보다 $C_3A$ 함량이 2$\~$3배 정도 높고, clinker 색은 연두색을 띄는 것이 특색이다. 이와 같이 $C_3A$ 함량이 높은 시멘트의 특성 및 제조 가능성을 검토한 결과는 다음과 같다. 1) 석회석과 slag를 1.6 : 1(61.5$\%$ : 38.5$\%$)로 사용할 경우 보통 시멘트 제조시 석회석 사용량 보다 약 28$\%$ 정도 절감되나 고품위의 석회석이 요구된다. 2) 동일 free CaO 0.4$\%$를 기준으로 소성할 경우 고$C_3A$ clinker가 보통 clinker 보다 소성 시간이 20분 단축된다. 3) carbonate 분해열을 비교하면 고$C_3A$ 시멘트 원료가 보통 시멘트 원료보다 116Kcal/$\cal{kg}$-cl 절감된다. 4) $C_3A$ 함량이 높아 가소성이 저하되고 표준연도의 시멘트 paste를 얻기 위하여서는 보통 시멘트 보다 많은 물량이 요구되며 응결시간도 빠르다. 5) Blaine 3,000$cm^3$/g으로 분쇄한 고$C_3A$ 시멘트의 3 일강도는 보통 시멘트 보다 40$\~$50$\cal{kg}$/$cm^3$ 더 높으나 28 일 강도는 다소 저하되는 경향이며 Blaine 5,000$cm^2$/g으로 분쇄한 고$C_3A$ 시멘트는 조강 시멘트와 같은 강도 수준이다.

• Journal of the Korea Concrete Institute
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• v.17 no.3 s.87
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• pp.473-480
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• 2005

In this study, a mix design for self compacting concrete was based on Okamura's method and concrete incorporated just a ground granulated blast furnace slag. Replacement ratio of slag is in the range of $20-80\%$ of cement matrix by volume. For the optimal self compactability in mixture incorporating ground granulated blast furnace slag, the paste and mortar tests were first completed. Then the slump flow, elapsed time of 500mm slump flow, V funnel time and filling height by U type box were conducted in concrete. The volume of coarse aggregate in self compacting concrete was in the range of $50-60\%$ to the solid volume percentage of coarse aggregate. Finally, the compressive and splitting tensile strengths were determined in the hardened self compacting concrete incorporating ground granulated blast furnace slag. From the test results, it is desirable for self compacting concrete that the replacement of ground granulated blast furnace slag is in the range of $40-60\%$ of cement matrix by volume and the volume of coarse aggregate to the solid volume percentage of coarse aggregate with a limit of $55\%$.

• Proceedings of the KSR Conference
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• 2001.10a
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• pp.558-561
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• 2001

SIP(Soil cement Injected Precast pile) that inserts a precast pile after injecting a cement paste into a boring has been applied rapidly through the change of construction circumstances. But there isnt any logical equation of a bearing capacity fitted to SIP yet. So Meyerhof equation has mainly been used to predict a bearing capacity in a design stage instead. But it has shortcomings such as lack of confidence because it has derived not from a theory but from an experience obtained from the result of SPT (Standard Penetration Test) and because a penetration depth tends to be deeper by an excessive design that depends on an end bearing capacity of a pile more than a skin frictional resistance. In this study, thereupon, a direct shear test in the laboratory was performed to both SM and SC soils in variable conditions to verify skin friction properties for the purpose of presenting some reasons capable of reducing penetration depths. Through the tests, soil to soil of SM in cohesion, rough panel to soil of SM in friction angle and soil to soil of SM in shear strength tended to be high. And a shear strength increased as its total unit weight increased in all cases.