• Title/Summary/Keyword: Cement-paste

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Experimental Study on Thermal Conductivity of Concrete (콘크리트의 열전도율에 관한 실험적 연구)

  • 김국한;전상은;방기성;김진근
    • Journal of the Korea Concrete Institute
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    • v.13 no.4
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    • pp.305-313
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    • 2001
  • Conductivity is an important thermal property which governs heat transfer in a solid medium. Generally, the determination of conductivity in concrete is very difficult, because concrete is a heterogeneous material composed of cement, water, aggregate, et cetera and time dependent material of which properties change with curing age. In this study, influencing factors on thermal conductivity of concrete are quantitatively investigated by QTM-D3, a conductivity tester developed in Japan. Then, a prediction equation of thermal conductivity of concrete is suggested from the regression analysis of test results. To consider the factors influencing thermal conductivity of concrete, mortar, and cement paste, seven testing variables (age, amount of cement, types of admixtures, amount of coarse aggregate, fine aggregate ratio, temperature, and humidity condition) of the specimens are used. According to the experimental results, the amount of coarse aggregate and humidity condition of specimen are the main factors affecting the conductivity of concrete. Meanwhile, the conductivity of mortar and cement paste is strongly affected by the amount of cement and types of admixtures. However, the curing age has minor effect on the conductivity variation. Finally, the prediction formula of concrete conductivity as a function of aggregate amount, fine aggregate ratio, specimen temperature, and humidity condition is developed.

Prediction of Rheological Properties of Cement-Based Pastes Considering the Particle Properties of Binders (결합재의 입자특성을 고려한 시멘트 기반 2성분계 페이스트의 유변특성 예측)

  • Eun-Seok Choi;Jun-Woo Lee;Su-Tae Kang
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.6
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    • pp.111-119
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    • 2023
  • Recently, a variety of new cement-based materials have been developed, and attempts to predict the properties of these new materials are increasing. In this study, we aimed to predict the rheological properties of binary blended pastes. The cementitious materials used in the study included Portland cement (PC), fly ash (FA), blast furnace slag (BS), and silica fume (SF). The three binder components, fly ash, blast furnace slag, and silica fume, were blended with cement as the foundational composition. We predicted the yield stress and plastic viscosity of the pastes using the YODEL (Yield stress mODEL) and Krieger-Dougherty's equation. The predictive model's performance was validated by comparing it with experimental results obtained using a rheometer. When the rheological properties of the binary blended paste were predicted by reconstructing the properties and parameters used to predict the individual materials, it was evident that the predictions made using the proposed method closely matched the experimental results.

A constitutive model for fiber-reinforced extrudable fresh cementitious paste

  • Zhou, Xiangming;Li, Zongjin
    • Computers and Concrete
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    • v.8 no.4
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    • pp.371-388
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    • 2011
  • In this paper, time-continuous constitutive equations for strain rate-dependent materials are presented first, among which those for the overstress and the consistency viscoplastic models are considered. By allowing the stress states to be outside the yield surface, the overstress viscoplastic model directly defines the flow rule for viscoplastic strain rate. In comparison, a rate-dependent yield surface is defined in the consistency viscoplastic model, so that the standard Kuhn-Tucker loading/unloading condition still remains true for rate-dependent plasticity. Based on the formulation of the consistency viscoplasticity, a computational elasto-viscoplastic constitutive model is proposed for the short fiber-reinforced fresh cementitious paste for extrusion purpose. The proposed constitutive model adopts the von-Mises yield criterion, the associated flow rule and nonlinear strain rate-hardening law. It is found that the predicted flow stresses of the extrudable fresh cementitious paste agree well with experimental results. The rate-form constitutive equations are then integrated into an incremental formulation, which is implemented into a numerical framework based on ANSYS/LS-DYNA finite element code. Then, a series of upsetting and ram extrusion processes are simulated. It is found that the predicted forming load-time data are in good agreement with experimental results, suggesting that the proposed constitutive model could describe the elasto-viscoplastic behavior of the short fiber-reinforced extrudable fresh cementitious paste.

The characteristics of Low Blaine Cement (저 분말도 포틀랜드 시멘트의 특성)

  • 김재영;전준영;송종택
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.13-18
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    • 1998
  • This experiments carried out in order to investigate decreasing of the hydration heat and physical characteristics of the low blaine OPC. The experiments results indicated hydration heat was reduced by about 15% in th low blaine OPC(2300$\textrm{cm}^2$/g). The Mini-slump value of the cement paste was significantly increased and viscosity of one was decreased as blaine value in OPC decrease.

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Tests on Superplasticizers for High Strength Concrete (고강도 콘크리트용 고성능감수제 성능평가)

  • 노재호;김기철;조일호;한정호;박연동
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.151-156
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    • 1994
  • This study is to investigate the quality of superplasticizers in domestic market. Therefore, the physico-chemical characteristics, the fluidity characteristics of fresh cement paste and mortar were tested. Also fresh and hardened properties of mortars and concretes using these superplasticizers were tested. From these results, differences of quality among superplasticizers are checked clearly in low water/cement ratio. And it is concluded that several superplasticizers have better dispersion ability than others in every tests. It has known that all samples are naphtalene sulfornate formaldehede types by the UV(ultra-violet) test.

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Test Method of Determination of Chloride content by JCI Standards in Cement Paste (JCI 규준에 따른 시멘트페이스트내 염화물량 측정)

  • 문소현;윤성진;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.1233-1237
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    • 2000
  • In this study, we measured and assay the analysis of chloride ion in cement hydration by the standard method of JCI and understand the mutual relation between added contents and result. The purpose of this research is to provide fundamental information for the deterioration of the reinforcing concrete on account of steel of reinforced steel to repress.

The mechanical characteristics and CO2 emmissions of eggshell powder in cement paste (계란껍질 분말을 혼입한 시멘트 페이스트의 역학 특석 및 CO2 배출량 연구)

  • Chen, YuKun;Lee, HanSeung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.135-136
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    • 2021
  • This study investigated the use of different amounts of eggshell powder (ESP), namely 5%, 10%, and 15% by weight, as a substitute for Ordinary Portland Cement. The results show that its flowability and 28-day compressive strength. Meanwhile the carbon dioxide emission was though sustainable assessment analyzed It was concluded that ESP replacement level of around 5% provides the best performance to reduces environmental pollution.

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Waterproofing Mechanism of Hardened Cement Paste with Waterproofing Materials (구체방수제가 혼입된 시멘트 경화체의 방수 메카니즘)

  • Kang, Hyun Ju;Song, Myong Shin;Park, Jong Hun;Jeon, Se Hoon;Lee, Sung Hyun
    • Journal of the Korean Ceramic Society
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    • v.50 no.1
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    • pp.25-30
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    • 2013
  • The pore volume of hardened cement with waterproofing materials is lower compared to that of hardened cement without waterproofing materials. Thus, fewer gaps will appear by means of chemical reactions between $Ca^{2+}$ ions in hardened cement and water, solutes, and other ions. Due to the selective permeability, the osmotic pressure of hardened cement can change due to physical effects such as the reduction of the pore volume and the reduction in the number of pores, as well as by the electrochemical reaction between water, solutes, other ions and $Ca^{2+}$ ions in hardened cement. Of course, these factors do not have independent effects but instead a combined complex effect. Accordingly, we studied changes in the osmotic pressure due to the difference in the pore structure of hardened cement. A pore size smaller than 1 nm in hardened cement had only a slight effect on the osmotic pressure, whereas a pore size larger than 1 nm had a direct effect on the osmotic pressure.

Hydration Characteristics and Synthesis of Hauyne-Belite Cement as Low Temperature Sintering Cementitious Materials

  • Park, Sang-Jin;Jeon, Se-Hoon;Kim, Kyung-Nam;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.224-229
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    • 2018
  • OPC production requires high calorific value and emits a large amount of $CO_2$ through decarbonation of limestone, accounting for about 7% of $CO_2$ emissions. To reduce $CO_2$ emissions during the Ordinary Portland Cement (OPC) production process, there is a method of reducing the consumption of cement or lower temperature calcination for OPC product. In this study, for energy consumption reduction, we prepared Hauyne-belite cement by calcination at a low temperature compared to that used for OPC and studied the early hydration properties of the synthesized Hauyne-belite cement. We set the ratios of Hauyne and belite to 8 : 2, 5 : 5 and 3 : 7. For the hydration properties of the synthesized Hauyne-belite cement, we tested heat of hydration of paste and the compressive strength of mortar, using XRD and SEM for analysis of hydrates. As for our results, the temperature for optimum synthesis of Hauyne-belite is $1,250^{\circ}C$. Compressive strength of synthesized Hauyne-belite cement is lower than that of OPC, but it is confirmed that compressive strength of synthesized Hauyne-belite cement with mixing in of some other materials can be similar to that of OPC.

Properties and pozzolanic reaction degree of tuff in cement-based composite

  • Yu, Lehua;Zhou, Shuangxi;Deng, Wenwu
    • Advances in concrete construction
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    • v.3 no.1
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    • pp.71-90
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    • 2015
  • In order to investigate the feasibility and advantage of tuff used as pozzolan in cement-based composite, the representative specimens of tuff were collected, and their chemical compositions, proportion of vitreous phase, mineral species, and rock structure were measured by chemical composition analysis, petrographic analysis, and XRD. Pozzolanic activity strength index of tuff was tested by the ratio of the compression strength of the tuff/cement mortar to that of a control cement mortar. Pozzolanic reaction degree, and the contents of CH and bond water in the tuff/cement paste were determined by selective hydrochloric acid dissolution, and DSC-TG, respectively. The tuffs were demonstrated to be qualified supplementary binding material in cement-based composite according to relevant standards. The tuffs possessed abundant $SiO_2+Al_2O_3$ on chemical composition and plentiful content of amorphous phase on rock texture. The pozzolanic reaction degrees of the tuffs in the tuff/cement pastes were gradually increased with prolongation of curing time. The consistency of CH consumption and pozzolanic reaction degree was revealed. Variation of the pozzolanic reaction degree was enhanced with the bond water content and relationship between them appeared to satisfy an approximating linear law. The fitting linear regression equation can be applied to mutual conversion between pozzolanic reaction degree and bond water content.