• 한국건축시공학회지
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• 제6권4호
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• pp.61-68
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• 2006

Recently, there have been many studies about recycling cementitious powder from concrete waste(hereinafter referred to as waste powder), generated after recycle aggregate production. Previous studies showed that when the heating process of waste powder at $700^{\circ}C,\;Ca(OH)_2$ in paste is dehydrated making possible the restoration of hydraulic properties. Recycled cement with hydraulic properties restored is thought to be re-hydrated through the mechanism of hydration, which is almost similar in Portland cement. This clearly suggests that the hydrate of recycled cement is alkali in type. Like in general concrete, if recycled cement is used as a structural material, resistance performance against carbonation or neutralization by $CaCO_3$ in air probably would be most influential to the life of steel-reinforced concrete structure. Thus the purpose of this study is to make an experimental review on chemical properties of recycled cement, manufactured with concrete waste as base material, and investigate the durability of concrete using recycled cement through evaluating the cement's performance of resistance to carbonation in accordance with its accelerating age. Based on its results, further, the study seeks to provide basic information about ways of utilizing recycled cement.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2015년도 추계 학술논문 발표대회
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• pp.103-104
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• 2015

This study is an experiment about what affects the compressive strength by using a reducing agent (PNS based admixtures) to play cement using the cement paste based Waste Concrete Powder of waste concrete, which accounts for more than 60% of construction waste around the latest domestic and international It was. Securing the replacement of cement with Waste Concrete Powder and, by varying the admixture was to compensate for the low absorption of liquidity and obtain a fine powder. And the experiment was conducted with a constant water cement ratio and aggregate usage for the purpose of lowering the water cement ratio promoting strength development. When substituted with the experimental results of 0.3% based on 3 ~ 28 days as strength 36Mpa exhibited the highest strength.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표회 논문집(I)
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• pp.185-190
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• 1998

Corrosion of steel reinforcement is the most significant factor of deterioration in reinforced concrete structures. Chloride ion is considered one of the most common culprits on the corrosion of steels in concrete. The main objective of this study is understanding behavior of chloride ion in hardened cement pastes at different stages of curing. Cement pastes with water-cement ratio of 0.5 are allowed to hydrate in sealed containers for 28, 70, 180 days. And than pore solution is expressed. It was found that the $Cl^-$ concentrations in pore solution is decreased with increasing curing time in all Nacl addition level, the $OH^-$ concentrations is increased to 70 days but decrease at 180 days in all Nacl addition level. The $Cl^-$/$OH^-$ in pore solution is increased with increasing curing time in all Nacl addition level, however $Cl^-$/$OH^-$ of maximum Nacl addition level(Nacl 0.54% by weight of cement) is under the onset of depassivation level 0.3.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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• pp.409-414
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• 2001

The hydration of cement paste occurs when the cement is mixed with water. During the hydration, hydration heat causes the thermal stress depending on the size of concrete and the cement content. Especially in the high-strength concrete, we must give care to the concrete due to its large cement content. In this study, conduction calorimeter and concrete insulation hydration heat meter were used to investigate the hydration heat characteristics of cement and concrete. To reduce hydration heat of high-strength concrete, several types of replacement of fly-ash and blast-furnace slag powder were used in this experiment.

• 콘크리트학회지
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• 제6권5호
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• pp.149-157
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• 1994

보통 포틀랜드 시멘트와 수용성 고분자 물질인 hydroxy propyl methyl cellulose(HPMC), 미세골재 및 혼화재료를 사용하여 W/C=0.1이 되도록 물을 첨가하고 twin roll mill로 혼합 성형한 후 60일간 양생하여 고강도 시멘트 경화체를 제조하였다. 이 경화체에 대한 휨강도 및 파괴인성을 검토하였다. SiC 분말 및 백색시멘트를 첨가한 경우 휨강도는 약 100MPa정도, 탄성계수는 80-95GPa의 값을 나타내었다. 실리카흄을 첨가한 경우 휨강도는 80MPa, 탄성계수는 60GPa의 값을 나타내었다.

• The Korean Journal of Ceramics
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• 제6권3호
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• pp.286-290
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• 2000

The hydration behavior of fly ash and slag on cement paste were investigated. Early stage of hydration reaction was delayed by mixing fly ash and/or slag with cement, but production of C-S-H hydrates by pozzolanic reaction densified the microstructure. The Ca/Si ratio of C-S-H hydrates in OPC and blended cement of fly ash 50%, slag 50%, fly ash+slag 50% were 2.24, 1.80, 1.82 and 1.97, respectively. The C-S-H gel with low Ca/Si ratio showed rather reticulate than needle-like structure.

• 한국세라믹학회지
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• 제36권12호
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• pp.1342-1349
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• 1999

In order to improve the density and the mechanical strength without change in chemical composition the hardened pastes of hydroxyapatite cement were reinforced with powders and/or whiskers of hydroxyapatite. The powders behaved as a seed of hydroxyapatite formation rather than a filler while the whiskers were mrerly dispersed in matrix and capillary pores of the hardened bodies leading to increase in mechanical strength. But the increase in strength But the increase in strength was nnt enough owing to the lack of homogeneous dispersion of the fibers. The highest diametral tensile strength of 18.5 MPa was measured at the hardened hydroxyapatite body in which well-dispersed whisker phase formed uniformly during hydro-thermal curing of power-added and dry-formed hydroxyapatite cement.

• 한국구조물진단유지관리공학회 논문집
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• 제20권6호
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• pp.10-19
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• 2016

본 연구의 목적은 OPC, GGBFS 그리고 FA를 사용한 삼성분계 시멘트(TBC) 페이스트의 자기치유 특성에 관한 것이다. 초음파속도(UPV)측정으로 통해 삼성분계 시멘트의 자기치유 능력에 대한 OPC-GGBFS-FA의 영향을 분석하였다. TBC 페이스트는 0.5의 일정한 물-결합재 비에 GGBFS-FA를 20%, 40% 그리고 60% 치환한 배합이다. 본 연구는 재령 28일(하중 재하 후)이후의 거동에 초점을 맞추었다. 재령 28일에 휨시험을 통해 사각형의 보 시험체에 미리 균열을 발생시켰다. 시험체들은(균열을 발생시키지 않은 것과 균열을 발생시킨) 60일까지 담수와 해수에 침지하였다. 시험결과에 따르면 TBC 페이스트의 자기치유 능력은 GGBFS의 혼합률이 증가함에 따라 증가하였다. 이는 GGBFS와 FA는 재령 28일 이후에도 계속해서 수화가 진행되는데, GGBFS와 FA의 수화반응 물질들이 미세구조의 변화와 균열을 폐합한다. 이러한 결과들로부터, 균열을 발생시킨 모든 시험체에서 자기치유가 일어났고 이는 침지 30일에서 가장 많이 발생하였다. 더구나 담수와 해수에 침지한 시험체의 치유의 대부분이 침지 30일 동안 일어났다. 해수에 침지한 시험체의 균열 치유는 담수보다 빨랐다. 해수와 담수에 침지한 시험체의 치유효과의 차이는 해수에 포함된 이온들 때문이다. 더구나 재령효과를 고려한 자기치유효과는 침지 30일까지가 가장 강력하고 그다음엔 차츰 약해졌다.

• 콘크리트학회논문집
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• 제16권2호
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• pp.147-154
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• 2004

국내의 경우 건설생산현장에서 고유동콘크리트의 제조시 주로 나프탈렌계 및 멜라민계가 적용되고 있으며, 또한 최근에는 콘크리트의 요구성능을 확보하기 위하여 이러한 두 성분을 혼합하여 적용하는 사례도 나타나고 있다. 따라서 본 연구에서는 고유동콘크리트의 유동특성에 영향을 미치는 고성능감수제의 구성비율을 비교$\cdot$분석함으로서 혼합형 고성능감수제의 현장적용시 적용방법 및 품질기준 확립을 위한 기초적인 자료를 제시하기 위하여 고성능감수제를 분산제의 구성비율에 따라 N, NM, MN, M의 4수준으로 설정하였다. 그 결과 고성능감수제 구성비율에 따른 페이스트의 유동특성은 나프탈렌의 구성비율이 증가할수록 상대플로우면적비 및 흡착률이 증가하고 있어 유동성이 우수하게 나타났으며 멜라민 구성비율이 증가할수록 점성이 높아지는 것으로 나타났다. 나프탈렌-멜라민 혼합형 고성능감수제의 경우 유동성 및 간극통과성을 포함한 고유동 특성과 응결시간에 있어서 상대적으로 양호한 성능을 나타내고 있어 고유동콘크리트 제조시 고성능감수제를 구성하는 주요성분을 적절하게 혼합하여 사용함으로서 고성능감수제의 효율적인 성능향상이 가능할 것으로 사료된다.

• 구강회복응용과학지
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• 제23권3호
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• pp.259-268
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• 2007

purpose: This study was to evaluate the shear bond strength of Lithium Disilicate Glass-Ceramic by removable method of temporary cement on the abutment tooth. Material and Method: Sixty molar teeth of human with the occlusal surface up were mounted in acrylic resin blocks. The 45 specimens were prepared to exposure dentin by diamond bur and the eugenol-containing temporary cement($Cavitec^{TM}$ ($KERR^{(R)}$, U.S.A)was applied to the dentin surfaces. After initial removal of the cement with a dental explorer, the specimens were divided into 4 groups of 15 specimens each. The dentin surfaces of the specimens were treated by rotary instrument with as follow pastes: $Zircate^{(R)}$ prophy paste(Dentsply, U.S.A), Radent Prophy Paste(Pascal company,inc. U.S.A), and Dental pumice(Wip mix corporation,U.S.A). An adhesive resin luting agent(Variolink $II^{(R)}$, Ivoclar Vivadent, Leichtenstein) including Monobond-S and $Excite^{(R)}$ was applied to all specimens. The ceramic specimens were made with an A1 ingot of IPS Empress $II^{(R)}$ (Ivoclar Vivadent, Leichtenstein). After the specimens were stored in distilled water for 48hr, the shear bond strength(MPa) was measured by a Universal testing machine(Zwick 145641, Zwick, Germany) at a 1mm/min cross-head speed. The data were statistically analyzed by one-way ANOVA and Duncan's multiple range test. Results: In all group, there were no significant differences in comparison with the control group(p>0.05). The pattern of most failure showed the mixed type of cohesive and adhesive failure. Conclusion: Resin bond strength of IPS Empress $II^{(R)}$ was not affected by removal method of the temporary cement.