• Corrosion Science and Technology
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• v.8 no.2
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• pp.81-88
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• 2009

Chloride induced corrosion of steel reinforcement inside concrete is a major concern for concrete structures exposed to a marine environment. It is well known that transport of chloride ions in concrete occurs mainly through ionic/molecular diffusion, as a gradient of chloride concentration in the concrete pore solution is set. In the process of chloride transport, a portion of chlorides are bound in cement matrix then to be removed in the pore solution, and thus only the rest of chlorides which are not bound (i.e. free chlorides) leads the ingress of chlorides. However, since the measurement of free/bound chloride content is much susceptible to environmental conditions, chloride profiles expressed in total chlorides are evaluated to use in many studies In this study, the capacity of chloride binding in cement matrix was monitored for 150 days and then quantified using the Langmuir isotherm to determine the portions of free chlorides and bound chlorides at given total chlorides and the redistribution of free chlorides. Then, the diffusion of chloride ion in concrete was modeled by considering the binding capacity for the prediction of chloride profiles with the redistribution. The predicted chloride profiles were compared to those obtained from conventional model. It was found that the prediction of chloride profiles obtained by the model has shown slower diffusion than those by the conventional ones. This reflects that the prediction by total chloride may overestimate the ingress of chlorides by neglecting the redistribution of free chlorides caused by the binding capacity of cement matrix. From the evaluation, it is also shown that the service life prediction using the free chloride redistribution model needs different expression for the chloride threshold level which is expressed by the total chlorides in the conventional diffusion model.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.1
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• pp.8-13
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• 2017

This experimental study is purposed to analyze the effect of alkaline aqueous solution by electrolysis on strength development in order to develop high volume cement matrix using industrial by-products. Blast furnace slag was used a binder, and an alkaline aqueous solution obtained by electrolyzing pure water was used as an alkali activator. The hydration properties of these specimens were then investigated by compressive strength test, XRD and observation of micro-structures using SEM. As a result, we found that compressive strength increased with the addition of alkaline aqueous solution which cement matrix incorporating blast furnace slag. But those strength decreased reversely when replacing ratio of blast furnace slag was increased. It is judged that results of engineering properties evaluation on the binder and alkaline aqueous solution are useful as a basic data for mixtures design and evaluation properties of high volume cement matrix using by-products.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.2
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• pp.166-171
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• 2014

This experimental study considers manufacturing method of the non-portland cement matrix for the light-weight building materials using blast furnace slag, paper ash, fly ash and polysilicon sludge the industrial by-product. For the experiment, we used paper ash by means of the foaming agent and alkali activator to make non-portland cement light-weight matrix. Various specimens were prepared with different types and addition ratios of the alkali activator. Then, the properties of these specimens were investigated by compressive strength test, bulk specific gravity. As a results, it was judged that experiment results of non-portland cement matrix with specific waste resources and alkali activators were useful as basic data for mixtures design and evaluation properties of lightweight non-portland cement building material.

• Journal of the Korea Concrete Institute
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• v.12 no.5
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• pp.141-151
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• 2000

Compressive strength, sulfate deterioration factor(SDF) and length change of 5 types of mortars immersed in sodium sulfate solution were observed. As the results of tests, it was found that the sulfate resistance of blended cement mortars were superior to that of portland cement mortars. Pore volume with diameter larger than 0.1 $\mu\textrm{m}$ of 5 types of pastes indicated that the micro-structures of blended cement pastes were denser, due to pozzolan reaction and latent hydraulic properties, than those of portland cement pastes. The XRD, ESEM, EDS and TG analyses demonstrated that the reactants such as ettringite and gypsum were significantly formed in portland cement pastes. Besides, compared with the $Ca(OH)_2$ content of ordinary portland cement pastes immersed in water and sodium sulfate solution, the $Ca(OH)_2$ contents of fly ash blended cement and ground granulated blast-furnace slag cement paste were about 58% and 28% in water, and 55% and 20% in sodium sulfate solution, respectively.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.3
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• pp.76-85
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• 2017

In this study, to evaluate the mechanical properties of fiber-reinforced cement composites by strain rate, hydraulic rapid loading test system was developed. And compressive and tensile strength of the hooked steel fiber and polyamide fiber reinforced cement composite were evaluated. As a result, the compressive strength, strain capacity and elastic modulus were increased with increasing strain rate. The effect of compressive strength by type and volume fraction of fibers was not significant. The dynamic increase factor(DIF) of the compressive strength was higher than that of the CEB-FIP model code 2010 and showed a trend similar to that of ACI-349. The tensile strength and strain capacity were increased with increasing strain rate. The hooked steel fibers were drawn from the matrix. The tensile strength and strain capacity of hooked steel fiber reinforced cement composites were increased as the strain rate increased. The tensile strength and deformation capacity of the fiber reinforced cement composites were increased. And, hooked steel fibers were drawn from the matrix. On the other hand, because the bonding properties of polyamide fiber and matrix is large, polyamide fiber was cut-off with out pullout from matrix. The strain rate effect on the tensile properties of polyamide fiber reinforced cement composites was found to be strongly affected by the tensile strength of the fibers.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.711-714
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• 2003

Factors causing deterioration of concrete structures under marine environment are various, especially penetration and diffusion of chloride ion, carbon dioxide, and water through pore effects on the durability of concrete as well as mechanical properties of concrete. Pore of porous materials like concrete can be classified as micro-, meso-, and macro-pore. And pore of cement matrix is classified as pore which occupied by water, air void, and ITZ between cement paste and aggregates. In this study, to verify the relationship between pore of cement matrix and the property of chloride ion diffusivity, the regression analysis is producted. From the result of regression analysis, the average pore diameter more than total pore volume effects on the diffusivity of chloride ion.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2019.05a
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• pp.118-119
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• 2019

The exterior finish not only has a relationship to the functionality of building, but also the spatial aesthetics and visual perception. Common exterior finishes are wood, stone or acrylic based and etc. However, these finishes have different attributes which can alter the quality of the architecture, such as durability, moisture and fire resistance. To make up for the short-comings of these materials, we have used iron based resources for optimization. However, iron materials are expensive, so they have limitations in general use. In this study, we have experimented with various forms of exterior finishes using cement, which is the most efficient and widely used building material with several economic advantages. We experimented with different materials to use as the formwork for the gloss of the cement matrix. As a result, the gloss show that order of urethane, steel, and wood material.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2018.05a
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• pp.265-266
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• 2018

In recent years, active loess cement has been used instead of cement in order to reduce the amount of cement and industrial byproducts that are the main cause of environmental pollution. We also used polysilicon sludge as a by-product to reduce the amount of cement used and to improve the environmental pollution due to the reduction of carbon dioxide. Polysilicon is a raw material used in the production of panels for solar power generation. When producing 1 ton of polysilicon, 2 tons of sludge is generated. It is an experiment to reduce sludge treatment and cement usage. This study analyzed basic characteristics of polysilicon sludge and active loess cement according to replacment ratio.

• International Journal of Concrete Structures and Materials
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• v.18 no.2E
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• pp.97-102
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• 2006

In this study, the effect of supplementary materials(GGBS, PFA, SF) on sulfuric acid corrosion resistance was assessed by measuring the compressive strength, corroded depth and weight change at 7, 28, 56, 91, 180 and 250 days of immersion in sulfuric acid solution with the pH of 0.5, 1.0, 2.0 and 3.0. Then, it was found that an increase in the duration of immersion and a decrease in the pH, as expected, resulted in a more severe corrosion irrespective of binders: increased corroded depth and weight change, and lowered the compressive strength. 60% GGBS mortar specimen was the most resistant to acid corrosion in terms of the corroded depth, weight change and compressive strength, due to the latent hydraulic characteristics and lower portion of calcium hydroxide. The order of resistance to acid was 60% GGBS>20% PFA>10% SF>OPC. In a microscopic examination, it was found that acid corrosion of cement matrix produced gypsum, as a result of decomposition of hydration products, which may loose the structure of cement matrix, thereby leading to a remarkable decrease of concrete properties.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2015.05a
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• pp.164-165
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• 2015

Recently, the reason of using foamed concrete is for core of panel, filler of construction material to give lightness. However, cement causes environmental problem. The cement generates CO₂ but we normally use cement during manufacturing foamed concrete. Accordingly, this study focuses on dynamic properties of matrix according to the addition ratio of paper ash to make lightweight matrix with blast furnace slag and paper ash which are industrial by-product. The experiment progessed in order to select th optimum mixing ratio of the blast furnace slag and paper ash. There are totally 7 levels such as B100:P0, B95:P5, B90:P10, B85:P15, B80:P20, B75:P25, B70:P30 in this study. As a result of the test, B95:P5 matrix has the best density and compressive strength.