• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.3
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• pp.144-151
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• 2010

In this study, it is investigated the mechanical chemical properties of cement matrix using phosphogypsum and kaolin as a admixture for the substitutive materials to silica fume which is so expensive. For the test, phosphogypsum is modified as dihydrate, hemihydrate, type III anhydrite, and type II anhydrite, respectively and furnaced kaolin at $900^{\circ}C$ was also manufactured into meta kaolin by air cooling and water cooling method. The chemical characteristic and mechanical properties of various type of blended cements contained above mentioned gypsum and meta kaolin materials analyzed and compared with those characteristics of cement matrix with silica fume. From the test, the cement mixed meta kaolin made in water cooling has more excellent quality than other material.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.53-56
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• 2005

This paper investigates the effect of ductile deformation behavior of high performance hybrid fiber-reinforced cement composites (HPHFRCCs) on the shear behavior of coupling beams to lateral load reversals. The matrix ductility and the reinforcement layout were the main variables of the tests. Three short coupling beams with two different reinforcement arrangements and matrixes were tested. They were subjected to cyclic loading by a suitable experimental setup. All specimens were characterized by a shear span-depth ratio of 1.0. The reinforcement layouts consisted of a classical scheme and diagonal scheme without confining ties. The effects of matrix ductility on deflections, strains, crack widths, crack patterns, failure modes, and ultimate shear load of coupling beams have been examined. The combination of a ductile cementitious matrix and steel reinforcement is found to result in improved energy dissipation capacity, simplification of reinforcement details, and damage-tolerant inelastic deformation behavior. Test results showed that the HPFRCC coupling beams behaved better than normal reinforced concrete control beams. These results were produced by HPHFRCC's tensile deformation capacity, damage tolerance and tensile strength.

• Environmental Engineering Research
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• v.12 no.3
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• pp.101-108
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• 2007

Fixation of lead contaminants in the solidification/stabilization using Portland cement has been investigated by X-ray diffraction, scanning electron microscopy and compressive strength. The presence of lead was observed to produce lead carbonate sulfate hydroxide ($Pb_4SO_4(CO_3)_2(OH)_2$), lead carbonate hydroxide hydrate ($3PbCO_3{\cdot}2Pb(OH)_2{\cdot}H_2O$) and two other unidentified lead salts in cavity areas and was observed to significantly retard the hydration of cement. By 28 days, howevere, the XRD peaks of most of the lead precipitates have essentially disappeared with only residual traces of lead carbonate sulfate hydroxide and lead carbonate hydroxide hydrate evident. After 28 days of curing, hydration appears well advanced with a strong portlandite peak present though C-S-H gel peaks are not particularly evident. Lead species produced with the dissolution of lead precipitates are fixed into the cement matrix to be calcium lead silicate hydrate (C-Pb-S-H) during cement-based solidification.

• Restorative Dentistry and Endodontics
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• v.37 no.4
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• pp.194-200
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• 2012

Objectives: New resin cement (NRC) has been developed as a root repairing material and the material is composed of organic resin matrix and inorganic powders. The aim of this study was to compare the rat subcutaneous tissue response to NRC and mineral trioxide aggregate (MTA) cement and to investigate the tissue toxicity of both materials. Materials and Methods: Sixty rats received two polyethylene tube-implants in dorsal subcutaneous regions, MTA and NRC specimens. Twenty rats were sacrificed respectively at 1, 4 and 8 wk after implantation and sectioned to 5 ${\mu}m$ thickness and stained with Hematoxylin-Eosin (H-E) or von-Kossa staining. The condition of tissue adjacent to the implanted materials and the extent of inflammation to each implant were evaluated by two examiners who were unaware of the type of implanted materials in the tissues. Data were statistically analyzed with paired t-test (p < 0.05). Results: In specimens implanted with both NRC and MTA, severe inflammatory reactions were present at one wk, which decreased with time. At eighth wk, MTA implanted tissue showed mild inflammatory reaction, while there were moderate inflammatory reactions in NRC implanted tissue, respectively. In NRC group, von-Kossa staining showed more calcification materials than MTA group at eighth wk. Conclusions: It was concluded that the calcium reservoir capability of NRC may contribute to mineralization of the tissues.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.6
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• pp.1298-1303
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• 2009

The effect of blending weight and fiber length on the tensile and flexural strength for Basalt fiber reinforce cement composites is discussed. The increase of physical properties is mainly affected by blending quantity of fibers instead of the fiber length. Also it is believed that the interfacial adhesion between Basalt fiber and cement matrix gives positive influence to the physical strength. Basalt fiber in saturated $Ca(OH)_2$ solution, which is similar to the alkaline hydration environment of cement, shows very low weight loss even after 3 weeks of immersion.

• Advances in environmental research
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• v.3 no.4
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• pp.337-353
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• 2014

The determination of the effectiveness of the immobilization of blasting dust (waste generated in galvanic activities) in cement matrix, as well of mechanical, physical and microstructural properties of concrete paving blocks produced with partial replacement of cement was the objective of this work. The results showed that blasting dust has high percentage of silica in the composition and very fine particle size, characteristics that qualify it for replacement of cement in manufacturing concrete blocks. The replacement of Portland cement by up to 5% residues did not cause a significant loss in compressive strength nor increase in water absorption of the blocks. Chemical tests indicated that there is no problem of leaching or solubilization of contaminants to the environment during the useful life of the concrete blocks, since the solidification/stabilization process led to the immobilization of waste in the cement mass. Therefore, the use of blasting dust in the manufacture of concrete paving blocks is promising, thus being not only an alternative for proper disposal of such waste as well as a possibility of saving raw materials used in the construction industry.

• Advances in concrete construction
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• v.14 no.5
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• pp.341-354
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• 2022

Treatment of solid waste building materials is a crucial method of disposal and an area of ongoing research. New standards for the treatment of solid waste building materials are necessary due to multisource features, huge quantities, and complicated compositions of solid waste. In this research, sustainable nanomaterial mixtures containing nano-paper waste (NPW) and nano-metakaolin (NMK) were used as a substitute for Portland cement. Portland cement was replaced with different ratios of NPW and NMK (0%, 4%, 8%, and 12% by weight of cement) while the cement-to-water ratio remained constant at 0.4 in all mortar mixtures. The fresh properties had a positive effect on them, and with the increase in the percentage of replacement, the fresh properties decreased. The results of compressive strength at 7 and 28 days and flexural strength at 28 days show that the nanomaterials improved the strength, but the results of NMK were better than those of NPW. The best replacement rate was 8%, followed by 4%, and finally 12% for both materials. The combination of NMK and NPW as a replacement (12% NMK + 12% NPW) showed less shrinkage than the others because of the high pozzolanic reactivity of the nanomaterials. The combination of NMK and NPW improved the microstructure by increasing the hydration volume and lowering the water in the cement matrix, as clearly observed in the C-S-H decomposition.

• Advances in concrete construction
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• v.2 no.4
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• pp.249-259
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• 2014

Mortar is a masonry product which is matrix of concrete. It consists of binder and fine aggregate and moreover, it is an essential associate in any reinforced structural construction. The strength of mortar is a special concern to the engineer because mortar is responsible to give protection in the outer part of the structure as well as at a brick joint in masonry wall system. The purpose of this research is to investigate the compressive strength and tensile strength of mortar, which are important mechanical properties, by replacing the cement and sand by stone dust. Moreover, to minimize the increasing demand of cement and sand, checking of appropriateness of stone dust as a construction material is necessary to ensure both solid waste minimization and recovery by exchanging stone dust with cement and sand. Stone dust passing by No. 200 sieve, is used as cement replacing material and retained by No. 100 sieve is used for sand replacement. Sand was replaced by stone dust of 15%, 20%, 25%, 30%, 35%, 40%, 45% and 50% by weight of sand while cement was replaced by stone dust of 3%, 5%, and 7% by weight of cement. Test result indicates that, compressive strength of specimen mix with 35% of sand replacing stone dust and 3% of cement replacing stone dust increases 21.33% and 22.76% respectively than the normal mortar specimen at 7 and 28 days while for tensile it increases up to 13.47%. At the end, optimum dose was selected and crack analysis as well as discussion also included.

• Journal of the korean academy of Pediatric Dentistry
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• v.23 no.2
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• pp.450-460
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• 1996

The purpose of this study was to compare shear bond strength of composite resin using several dentin bonding agents and light cured glass ionomer cement(Fuji II LC). 40 Bovine primary anterior teeth were used for this experiment. Labial surface of teeth were flattened. It were divided into four groups. Each group was composed of 10 teeth. The material used for this experiment were Scotchbond Multipurpose-Z-100, Allbond 2-Aelitefil, Gluma-Pekalux, light cured glass ionomer cement(Fuji II LC). Each of the materials was applied to the exposed surfaces of 10 teeth by insertion into a cylindrical shaped matrix which is 3mm diameter and 3mm in height. The completed specimens were stored at $37^{\circ}C$ under 100% humidity for 24 hours : the shear bond strength of each material to dentin surface were measured with INSTRON universal testing machine. The results were as follows : 1. Shear bond strength to dentin surface increased in order of light cured glass ionomer cement(Fuji II LC), Gluma, Allbond 2, Scotchbond Multipurpose. 2. Between shear bond strength of light cured glass ionomer cement(Fuji II LC) and Allbond 2, there was statistical significace(p<0.05) 3. Between shear bond strength of light cured glass ionomer cement(Fuji II LC) and Scotchbond Multipurpose, between shear bond strength of Gluma and Scotchbond Multipurpose, there was statistical significance.(p<0.01) The shear bond strength of dentin bonding agents were higher than light cured glass ionomer cement. The reason is that materials and quality of dentin bonding agent were enhanced. Further investigation is necessary to improve shear bond strength of light cured glass ionomer cement.

• Korean Journal of Dental Materials
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• v.44 no.1
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• pp.69-77
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• 2017

The aim of this study was to investigate the effects of chitosan powder addition on the strengthening of conventional glass ionomer cement. Two types of chitosan powders with different molecular weight were mixed with conventional glass ionomer cement (GIC): low-molecular weight chitosan (CL; 50~190 kDa), high-molecular weight chitosan (CH; 310~375 kDa). The chitosan powders (CL and CH) were separately added into the GIC liquid (0.25-0.5 wt%) under magnetic stirring, or mixed with the GIC powder by ball-milling for 24 h using zirconia balls. The mixing ratio of prepared cement was 2:1 for powder to liquid. Net setting time of cements was measured by ISO 9917-1. The specimens for the compressive strength (CS; $4{\times}6mm$), diametral tensile strength (DTS; $6{\times}4mm$), three-point flexure (FS; $2{\times}2{\times}25mm$) with flexure modulus (FM) were obtained from cements at 1, 7, and 14 days after storing in distilled water at $(37{\pm}1)^{\circ}C$. All mechanical strength tests were conducted with a cross-head speed of 1 mm/min. Data were statistically analyzed by one-way ANOVA and Tukey HSD post-hoc test. The mechanical properties of conventional glass ionomer cement was significantly enhanced by addition of 0.5 wt% CL to cement liquid (CS, DTS), or by addition of 10 wt% CH (FS) to cement powder. The CL particles incorporated into the set cement were firmly bonded to the GIC matrix (SEM). Within the limitation of this study, the results indicated that chitosan powders can be successfully added to enhance the mechanical properties of conventional GIC.