• Textile Coloration and Finishing
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• 제21권3호
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• pp.1-9
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• 2009

Polycarboxylics acids are used as crosslinking agents for cotton cellulose to produce durable finished press cotton fabric. It has been observed that the strength of the cotton fabric treated with polycarboxylic acids showed significant reduction as a result of the crosslinking process. The effect of acid-catalyzed depolymerization on the tear strength of cotton fabric is investigated by evaluating the cotton fabric treated by succinic acid, which does not crosslink cotton cellulose and form little ester on the cotton fabric. We find that the tear strength of cotton fabric treated with succinic acid decreases at elevated temperature due to acid-catalyzed depolymerization of cellulose. The magnitude of fabric strength reduction increases as the acid concentration increases. At a constant acid concentration, it increases as the curing temperature and time increases. It decreases as the pH of the acid solution increases. We also find that the dissociation constant of an acid also has a significant effect on the fabric strength reduction. The magnitude of fabric tear strength reduction increases as the acid dissociation constant decreases.

• Journal of the Korean Society of Clothing and Textiles
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• 제48권3호
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• pp.511-527
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• 2024

The aim of this study was to impart color to bacterial cellulose (BC) fabric using various natural plant-based dyes-namely, gardenia jasminoides, green tea, and pomegranate peel. A protein pretreatment was also applied to improve the BC fabric's dyeability and mechanical properties. The BC fabric's dyeing and mordanting conditions when using plant-based natural dyes were determined by changes in the K/S values. The dyeability of BC samples dyed with green tea or pomegranate peel improved when they were pretreated with soy protein isolate (SPI) prior to dyeing. Moreover, the SPI pretreatment was efficient in improving the BC fabric's tensile strength and flexibility. This study proposes a method for dyeing BC fabric that uses plant-based natural dyes and confirms the effects of the protein pretreatment on the fabric's dyeability and durability.

• Journal of the Korea Fashion and Costume Design Association
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• 제16권4호
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• pp.229-235
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• 2014

This study conducted a research on burn-out printing convergence technology for cellulose blend knit fabrics. Printing technology, which forms color pattern on the fabric, can be generally classified into four according to printer or printing method, e.g. screen printing, roller printing, rotary printing, digital printing. However, these printing methods are flat in design or pattern, which have limitation to overcome monotonousness of fabric, so that recently burn-out process method, which expresses three-dimensional pattern effect by treating chemical on the surface of fabric as the method to appeal its esthetics to the customers. Particularly, in case of cellulose/polyester composite material, first, it is proceeded in 2 processes, by dyeing cellulose or polyester fabric and burning out cellulose fabric, in this process, due to pollution caused by disperse dye migration, color of polyester fabric part could be discolored, which has high falt risk. This research considered coloring burn-out technique, which simultaneously proceed dyeing and burn-out by reducing dyeing and burn-out process to 1 stage, which were proceeded in 2 stages previously. As the research result, it was confirmed that reasonable depth of roller was 0.04~0.06mm in roller printing process, heat treatment condition of burn-out far-infrared radiation was $185^{\circ}C{\times}30m/min$. Color fastness to washing was confirmed to be 4-5 grade, color fastness to rubbing, 3-4 grade, color fastness to light, 4 grade. Also, it was confirmed that energy reduction effect appeared 38.19%, in case of energy cost per yard compared to the existing production, also, 19.74%, in case of production cost.

• The Korean Journal of Community Living Science
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• 제27권4호
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• pp.795-801
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• 2016

This study was conducted to suggest the best union fabric to combine with cellulose fiber for summer and in-between seasons. Four types of union fabric, viz. silk/flax, silk/cotton, rayon/flax and rayon/cotton, were used as sample fabrics after weaving them in a local textile factory. The air permeability, moisture regain, water absorption, water vapor permeability and thermal insulation of the samples were tested. The results are as follows. The rayon/flax union fabric is the most suitable for summer clothes due to its having the best comfort property of air and water vapor permeability, and moisture and water absorption. For in-between seasons, it is recommended to use the silk/cotton union fabric because of its good thermal insulation properties.

• Textile Coloration and Finishing
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• 제15권1호
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• pp.8-14
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• 2003

The effect of pasting agent on the defibrillation of Tencel fabric was investigated. It was evaluated by the weigth loss of fabric when the fabric was treated with cellulase containing various kinds of pasting agents. The surface appearance of Tencel fabric was checked by SEM. Under the treatment condition without pasting agent, the weight loss of fabric was high at pH 5.0 and $60^\circ{C}$. This means that the cellulase activity was high at this condition. By increasing the concentration of carboxymethyl cellulose(CMC), the weight loss of fabric was decreased monotonously. This tendency was not appeared in other pasting agents. CMC is synthesized by the reaction of chloroacetic acid and cellulose. The glucose units may be remained after the reaction. So, it was considered that the degradation of glucose unit in Tencel was decreased, because cellulase had to attack both Tencel and CMC.

• Textile Coloration and Finishing
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• 제4권2호
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• pp.69-75
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• 1992

This study was carried out to compare the effect of caustic soda with the effect of caustic potash on cotton fabric. Instead of caustic potash, sodium carbonate similar in chemical composition to caustic potash was used. The damage of cotton cellulose by repeated washing in various alkaline solutions at 8$0^{\circ}C$, 60 rpm was examined. The damage of cotton cellulose by the variation of copper number, carboxyl content, degree of polymerization and retained tensile strength was estimated. The results obtained at this study are as follows; 1. The damage of cotton by caustic soda was severer than caustic potash. The retained tensile strength at 50 washing cycle in caustic soda was 59% and in sodium carbonate was 80%. 2. By adding soap to caustic soda, the damage of cotton fabric decreased because contact area between fabric and air diminished by foam. 3. Detergency of EMPA 101 in caustic soda was lower than sodium carbonate. Consequently, using caustic soda that damage fabric severely and have lower detergency for caustic potash is unreasonable.

• Fashion & Textile Research Journal
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• 제24권2호
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• pp.260-266
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• 2022

Cellulose fiber is a material used in various fields. It is the most used type of fiber because of its excellent hygroscopicity and dyeability. Recently, as natural fiber materials have been highlighted due to the influence of eco-friendliness and well-being, bamboo fiber has become a commonly used eco-friendly fiber. Cellulose fibers are part of the -OH hydroxyl group, which means they are more chemically reactive than synthetic fibers. In this study, the cationization properties of bamboo-cotton blended fabrics cationized using CHPTAC (3-chloro-2-hydroxypropyl trimethyl ammonium chloride) in the PDC (padding-drying-curing) method were investigated. Various characteristics according to cationization were studied through elemental analysis, FT-IR (fourier-transform infrared spectroscopy) analysis, X-ray diffraction analysis, TGA (thermogravimetric) analysis, and SEM (scanning electron microscope) analysis. The nitrogen content of the cationized bamboo-cotton blended fabric increased with an increase in the concentration of the cationizing agent CHPTAC, and it was seen to be highly bound to cellulose molecules. As a result of the FT-IR analysis, both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics were seen to be typical cellulose. As a result of the X-ray diffraction analysis, both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics showed typical cellulose I structures. As a result of the X-ray diffraction analysis, both 100% pure cotton fabrics and CHPTAC-0 and CHPTAC-150 fabrics showed typical cellulose I structures. As the cationization progressed, micropores appeared on the surface of the blended fabric.

• Textile Coloration and Finishing
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• 제6권1호
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• pp.8-18
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• 1994

In one bath dyeing system of silk/cellulose acetate fiber blend fabric with acid /disperse dyes, adsorption behavior of acid dyes and disperse dyes on silk and cellulose acetate fabrics were examined. In the dyeing of cellulose acetate with C. I. Disperse Red 19(Red 19) and C. I. Disperse Red 60(Red 60) at 8$0^{\circ}C$ and 10$0^{\circ}C$, dye uptake with Red 19 was higher than that with Red 60. When the silk/cellulose acetate dyed with Red 19 and Red 60 at 10$0^{\circ}C$, dye uptake on cellulose acetate was influenced by affinity of the dye to the silk fabric dyed together. When the silk/cellulose acetate dyed with Blue 80/Red 19 and Blue 80/Red 60 at 10$0^{\circ}C$, color of cellulose acetate dyed with Red 19 and Red 60 was not influenced by Blue 80 but silk dyed with Blue 80 was influenced by Red 19 and Red 60. Interrelation of K/S value and Munsell value was scarcely any but showed the change tendency of K/S value.

• Textile Coloration and Finishing
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• 제32권3호
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• pp.135-141
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• 2020

The primary and secondary alcohols in cellulose reacted with acrylonitrile(AN) in the presence of strong alkalis to form cyanoethylated cellulose. The partially cyanoethylated cotton(CEC) fabric with AN in the presence of aqueous sodium hydroxide solution was described, including effects of treatment time and reagent concentrations. The weight increases of cotton fabric were shown to be linearly related to the treatment time, temperature and concentration of sodium hydroxide. The physical properties such as shrinkage ratio and tensile strength were proportional to the weight increases without significant impact on elongation. But the moisture regain decreased with decreasing hydrophilicity. The degree of substitution(DS) and transfer ratio were linearly related to the weight increases. In the CEC with increasing weight up to 24.9%, it has been obtained with DS up to 0.63-0.67 cyanoethyl groups per anhydroglucose and transferring ratio up to 87.7%. The color fastness to washing by sublimation transfer printing was improved by the cyanoethylation.

• Journal of the Korean Society of Clothing and Textiles
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• 제33권5호
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• pp.817-826
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• 2009

As UV radiation to the earth increased over recent years, many adverse effects of UV radiation have been reported. There are needs to develop UV-protective apparel and accessaries to protect skin from these harmful effects. Cellulose is one of the most frequently worn fiber during summer time. However, celllulose shows very low UV-protective property especially in case of thin and low fabric content. In this study, UV-protective cellulose textiles were developed using chiotsan mordanting and green tea dyeing. The repetition effect of chitosan and green tea treatment were focused. Three different cellulose fibers, cotton, linen, and ramie, were used for this study. All chitosan mordanted and green tea dyed fabrics showed increases in UV-protective property. The color of fabrics tended to darker as the numbers of mordanting process and green tea dyeing increased. UV-protective property did not increase significantly upon the repetition of mordanting and green tea dyeing treatment except ramie fabric. UV protective property was persisted upon washfastness test in all three cellulose fiber types.