• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.47 no.2
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• pp.42-52
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• 2015

In this study, cellulose nanofibrils (CNF) were modified through carboxymethylation or TEMPO-mediated oxidation and their effects on ionicity and characteristics of sheet, film, and foam were investigated. Carboxymethylation was carried out on pulp fibers as a pre-treatment before preparation of CNF. The gel-like and translucent CNF hydrogel was obtained by grinding of carboxymethylated cellulose fibers. Carboxymethylated CNF film and freeze dried sheet showed higher transparency than that of untreated CNF. The CNF sheet with high strength and the CNF foam without large ice crystals were obtained by using the carboxymethylated CNF. TEMPO-mediated oxidation was carried out as a post-treatment of CNF. The zeta potential and charge demand of TEMPO-oxidized CNF were increased with an increase in oxidation time and addition amount of NaClO. The density of sheet made of TEMPO oxidized CNF was increased with the amount of oxidizing agent. The TEMPO oxidized cellulose nanofiber (TOCN) which was obtained from supernatant after centrifugation could be converted to transparent film.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.44 no.4
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• pp.43-50
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• 2012

The crystallinity index is an important characteristic of cellulose. The crystallinity value is different depending on the adopted instrument. In this study, we determined a crystallinity index of cotton and wood celluloses using wide-angle X-ray scattering (WAXS), powder X-ray diffractometer (PXRD), and cross polarization/magic angle spinning solid-state $^{13}C$ nuclear magnetic resonance spectroscopy (CP/MAS solid-state $^{13}C$ NMR). The specimen was prepared in forms of powder, sheet and pallet. With the comparison of the obtained crystallinity indices of the cellulose, the effects of the analysis instrument, the sample preparation and analysis method were investigated. Among three instruments, the crystallinity indices by PXRD and NMR had a good relationship and reproducibility, and WAXS gave the crystallinity index with poor reproducibility. In the case of analysis methods of crystallinity indices, the Segal method showed higher value than that of the Ruland-Vonk method. We expect that this study would be applicable to evaluate the crystallinity index of various cellulose materials with accuracy and reproducibility.

• Journal of the Korean Wood Science and Technology
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• v.49 no.2
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• pp.169-180
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• 2021

Inherent crystalline domains present in low formaldehyde to urea (F/U) molar ratio urea-formaldehyde (UF) resins are responsible for their poor adhesion in wood-based composite panels. To modify the crystallinity of low molar ratio (LMR) UF resins, this study investigates the additional effect of cellulose nanomaterials (CNMs), such as cellulose microfibrils (CMFs), cellulose nanofibrils (CNFs), and TEMPO-oxidized CNFs (TEMPO-CNFs) on the crystallinity of modified LMR UF resins. First, two modification methods (post-mixing and in situ) were compared for modified LMR UF resins with TEMPO-CNFs. The modified UF resins with TEMPO-CNFs decreased the nonvolatile solid contents, while increasing the viscosity and gel time. However, the in situ modification of UF resins with TEMPO-CNFs showed lower crystallinity than that of post-mixing. Then, the in situ method was compared for all CNMs to modify LMR UF resins. The modified UF resins with CMFs using the in situ method increased nonvolatile solid contents and viscosity but decreased the gel time. The crystallinity of UF resins modified with TEMPO-CNFs was the lowest even though the crystalline domains were not significantly changed for all modified UF resins. These results suggest that these CNMs should be modified to prevent the formation of crystalline domains in LMR UF resins.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.36 no.1
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• pp.24-29
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• 2004

Alkaline cellulolytic enzymes from cultured medium of Coprinus cinereus 2249 were purified with gel and ion-exchange chromatography and characteristics of those enzyme proteins were investigated. A fiber length distribution and a crystallinity of cellulose and sugar composition of enzyme treated Mixed Office Wastepaper(MOW) and Unbleached Kraft Pulp(UKP) were analysed. The conclusion could summarized as follows; \circled1 Alkaline and acidic, endo- and exo-glucanases were purified from cultured medium of Coprinus cinereus 2249. \circled2 The approximate molecular weight of alkaline endo-glucanase was 42 kDa, and also that of alkaline exo-glucanase was 50 kDa. A fiber length distribution and a crystallization of cellulose and sugar composition of enzyme treated MOW and UKP were not so much changed with original paper and pulp.

• Journal of Microbiology and Biotechnology
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• v.15 no.1
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• pp.40-47
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• 2005

Modeling and simulation for simultaneous saccharification and fermentation (SSF) process in bioconversion of paper mill sludge to lactic acid was carried out. The SSF process combined the enzymatic hydrolysis of paper mill sludge into glucose and the fermentation of glucose into lactic acid in one reactor. A mathematical modeling for cellulose hydrolysis was developed, based on the proposed mechanism of cellulase adsorption deactivation. Another model for simple lactic acid fermentation was also made. A whole mathematical model for SSF was developed by combining the above two models for cellulose hydrolysis and lactic acid fermentation. The characteristics of the SSF process were investigated using the mathematical model.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.45 no.3
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• pp.27-35
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• 2013

Cotton linter pre-treatment methods using electron beam and sulfuric acid were investigated to prepare high quality regenerated fibers for fabrics. So far, NaOH was used to reduce the degree of polymerization (DP) of the cotton linter for ease of dissolving by cellulose solvent. Two pre-treatment methods were developed to reduce the consumption of the chemicals (NaOH) and to control the DP of cellulose more precisely. Changes in ${\alpha}$-cellulose contents and brightness by the pre-treatments were also important concerns. Both electron beam irradiation and sulfuric acid were shown to be effective on controlling the DP of cellulose and to reduce the chemical consumption, but reduced ${\alpha}$-cellulose contents as well in this study. Sulfuric acid pre-treatment, which needed additional washing process after the pre-treatment when comparing to the electron beam irradiation method, gave the highest brightness and the highest reduction of ${\alpha}$-cellulose content.

• Journal of the Korean Solar Energy Society
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• v.28 no.4
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• pp.10-16
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• 2008

The fire resistance of thermal insulation and interior finishing materials is recently much emphasized after the fire accident at the Icheon Cold Store in January 2008. Three kinds of thermal insulation are used in buildings. They are Organic, Non-organic and cellulosic insulation. Organic insulation such as polystyrene foam board and urethane foam has high thermal resistance but it has no fire resistance. While non-organic insulation such as rockwool and glassfiber has high fire resistance, it has lower thermal resistance than organic insulation. Cellulose insulation is primarily manufactured from recycled newsprint or cardboard using shredders and fiberizers. Despite of its environmental friendliness and high thermal resistivity, its domestic use has not much increased because of the prejudice that paper can easily burn. However, the cellulose insulation as a product is about 80 wt.% cellulosic fiber and 20 wt.% chemicals, most of which are fire retardants such as boric acid and ammonium sulfate. It is required to secure its fire safety for more consumption as a building insulation in Korea. Therefore, this study investigates the fire resistance of Korean cellulose insulation according to the rate of fire retardant and finally presents the optimum rate of fire retardant in cellulose as building insulation. The fire safety test was conducted according to the ASTM C 1485-00. The test results indicate that above 18 wt% of fire retardant is necessary to secure the fire safety of cellulose insulation.

• International Journal of Ocean System Engineering
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• v.1 no.4
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• pp.180-184
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• 2011

Nanocomposites based on cellulose nanofibers have been studied for a considerable time since its first introduction, however real applications seem to have hardly developed to these days. The high-strength of cellulose nanofibers suggests the potential to reinforce plastics to produce composites for semi-structural or even structural applications. This paper discusses some of the attempts to produce such high-strength nanocomposites and the main challenges that have to be overcome to bring them into commercial products.

• Textile Coloration and Finishing
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• v.6 no.1
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• pp.54-61
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• 1994

Acrylamidomethylated cellulose(AMC) was prepared by a reaction of N-methy-lolacrylamide(NMA) in the presence of acid catalyst, and pendent C=C double bonds are created on cellulose. Using the pendant double bonds as a site for Michael addition, a number of modified cellulose could be readily prepared. When AMC is treated in an aqueous solution containing sodium dihydrogen phospate and methylamine, the chemical structure of cellulose is represented as follow ; Cell-O-$CH_{2}$-NHCO-$CH_{2}$-$CH_{2}$-NHMe. Therefore in this paper, dyeing properties of modified cellulose for the acid dye were investigated.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2007.05a
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• pp.33-55
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• 2007

This article portrays special cellulose fibers, which are designed to be a functional additive and a carrier for papermaking chemicals. The first part of the presentation deals with the micronized $ARBOCEL^{(R)}$ cellulose fibers, which are used as a functional paper/paperboard additive. In particular as a bulk and speed aid. The detailed description of the micronized $ARBOCEL^{(R)}$ fibers, their function and effects on papermaking process and paper products are given. The second part of the study describes the concept of fiber-based papermaking chemicals. A new generation of fiber-based papermaking chemicals were presented for the first time at the PTS Pulp Technology Symposium 2005, and then several articles were published in various magazine in Asia ("Paper Asia"), the US ("Pulp & Paper"). and Europe ("Wochenblatt fuel Papierfabrikation"). The information generated quite an interest in the paper industry. Extensive studies of these papermaking additives have been made recently, new information obtained, and the compounds have gained more recognition in the industry. The company J. Rettenmaier und Soehne developed a group of fiber-based papermaking additives. They include combination of fibers with sizing agents, starch, fluorochemicals, minerals, biocides and some others. This article presents in-depth study of the AKD modified micronized cellulose as an example of the fiber-based papermaking chemicals concept. The material of the present paper is based mostly on the results of the pilot paper machine study at the Paper Research Institute PTS (Heidenau, Germany), and includes case studies from the mills, which used $ARBOCELPLUS^{(R)}-AKD$ compounds. It should be noted that the $ARBOCELPLUS^{(R)}$ compounds were not designed to replace traditional additives in paper industry. They should rather be used in those areas, where application of "normal" chemicals is especially problematic