• Title/Summary/Keyword: Cell-centered

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Luminescence Properties of Ag Doped ZnO as Quantum Dot Materials for Improving Efficiency of Dye-sensitized Solar Cell (염료감응형 태양전지에서 효율 향상을 위한 Quantum Dot 재료로서 Ag가 도핑된 ZnO의 발광 특성 연구)

  • 김현주;이동윤;송재성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.9
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    • pp.988-993
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    • 2004
  • Luminescence characteristics of Ag-doped ZnO as the quantum dot materials to increasing the efficiency on dye-sensitized solar cells (DSC) have been studied. Ag doped ZnO powder was produced by the self-sustaining combustion process using ultrasonic spraying heating method. Luminescence wavelength region of the ZnO by Ag doping was shifted to longer wavelength. Tn the case of the Ag doped ZnO powder, broad luminescence spectrum centered on 600nm was observed. On the other hand, we compared PL data of RTA treated ZnO:Ag film at various temperatures because the front electrode of solar cell was in need of the sintering process. In XRD and PL data for RTA treated film at the 500$^{\circ}C$ showed good property. And, it was found that the grain size wasn't growing but only optical property was changed. According to the result of XRD, PL, absorption, emission spectrum and DV-X${\alpha}$ used in theoretical calculation, it is considered to be possible to use Ag doped ZnO as quantum dot material for improving DSC efficiency.

Synthesis of Carbon Nanotubes Supported PtCo Electrocatalysts and Its Characterization for the Cathode Electrode of PEMFC (탄소나노튜브에 담지된 PtCo 촉매 제조 및 PEMFC Cathode 전극 특성)

  • Jung, Dong-Won;Park, Soon;Kang, Jung-Tak;Kim, Jun-Bom
    • Korean Journal of Materials Research
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    • v.19 no.5
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    • pp.233-239
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    • 2009
  • The electrocatalytic behavior of the PtCo catalyst supported on the multi-walled carbon nanotubes (MWNTs) has been evaluated and compared with commercial Pt/C catalyst in a polymer electrolyte membrane fuel cell(PEMFC). A PtCo/MWNTs electrocatalyst with a Pt:Co atomic ratio of 79:21 was synthesized and applied to a cathode of PEMFC. The structure and morphology of the synthesized PtCo/MWNTs electrocatalysts were characterized by X-ray diffraction and transmission electron microscopy. As a result of the X-ray studies, the crystal structure of a PtCo particle was determined to be a face-centered cubic(FCC) that was the same as the platinum structure. The particle size of PtCo in PtCo/MWNTs and Pt in Pt/C were 2.0 nm and 2.7 nm, respectively, which were calculated by Scherrer's formula from X-ray diffraction data. As a result we concluded that the specific surface activity of PtCo/MWNTs is superior to Pt/C's activity because of its smaller particle size. From the electrochemical impedance measurement, the membrane electrode assembly(MEA) fabricated with PtCo/MWNTs showed smaller anodic and cathodic activation losses than the MEA with Pt/C, although ohmic loss was the same as Pt/C. Finally, from the evaluation of cyclic voltammetry(CV), the unit cell using PtCo/MWNTs as the cathode electrocatalyst showed slightly higher fuel cell performance than the cell with a commercial Pt/C electrocatalyst.

A Study on The Optimum Structure of Dye-sensitized Solar Cell for Upscaling (염료감응형 태양전지의 대면적화를 위한 최적 구조 연구)

  • Seo, Hyun-Woong;Kim, Mi-Jeong;Hong, Ji-Tae;Kim, Hee-Je
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1295-1296
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    • 2007
  • A lot of researches about dye-sensitized solar cell (DSC) are recently being conducted. Because DSC has several advantages to pass the limits of silicon solar cells such as a low manufacturing expense, a simple manufacturing process and its transparency. But most researches on DSC are still conducted about the unit cell and laboratory-centered. That is, present researches on DSC are not practical. Therefore, researches about large area cells and modules have to be prerequisites for DSC to have the practicality. Characteristics of large area DSC are so different from those of small area DSC in aspect of fill factor and efficiency. In this study, we made an experiment on finding suitable size of DSC that has the most effective power according to the variation of active area. In detail, the experiment was conducted about the optimum ratio of length to width and we introduced the ratio of active area to non-active area to find the active area which has the best output. Because small DSC doesn‘t have the best output in comparison with total area of cell although the smaller DSC has the better efficiency. As a result, we achieved the optimum ratio of length to width of 8:3 and active area of $8cm^2$ as the optimum size for upscaling DSC.

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A NEW PRESSURE GRADIENT RECONSTRUCTION METHOD FOR A SEMI-IMPLICIT TWO-PHASE FLOW SCHEME ON UNSTRUCTURED MESHES (비정렬 격자 기반의 물-기체 2상 유동해석기법에서의 압력기울기 재구성 방법)

  • Lee, H.D.;Jeong, J.J.;Cho, H.K.;Kwon, O.J.
    • Journal of computational fluids engineering
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    • v.15 no.2
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    • pp.86-94
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    • 2010
  • A thermal-hydraulic code, named CUPID, has been developed for the analysis of transient two-phase flows in nuclear reactor components. A two-fluid three-field model was used for steam-water two-phase flows. To obtain numerical solutions, the finite volume method was applied over unstructured cell-centered meshes. In steam-water two-phase flows, a phase change, i.e., evaporation or condensation, results in a great change in the flow field because of substantial density difference between liquid and vapor phases. Thus, two-phase flows are very sensitive to the local pressure distribution that determines the phase change. This in turn puts emphasis on the accurate evaluation of local pressure gradient. This paper presents a new reconstruction method to evaluate the pressure gradient at cell centers on unstructured meshes. The results of the new scheme for a simple test function, a gravity-driven cavity, and a wall boiling two-phase flow are compared with those of the previous schemes in the CUPID code.

Mechanics behind Breast Cancer Prevention - Focus on Obesity, Exercise and Dietary Fat

  • Alegre, Melissa Marie;Knowles, McKay Hovis;Robison, Richard A.;O'Neill, Kim Leslie
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.4
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    • pp.2207-2212
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    • 2013
  • Cancer prevention is rapidly emerging as a major strategy to reduce cancer mortality. In the field of breast cancer, significant strides have recently been made in the understanding of underlying preventive mechanisms. Currently, three major strategies have been linked to an increase in breast cancer risk: obesity, lack of physical exercise, and high levels of saturated dietary fat. As a result, prevention strategies for breast cancer are usually centered on these lifestyle factors. Unfortunately, there remains controversy regarding epidemiological studies that seek to determine the benefit of these lifestyle changes. We have identified crucial mechanisms that may help clarify these conflicting studies. For example, recent reports with olive oil have demonstrated that it may influence crucial transcription factors and reduce breast tumor aggressiveness by targeting HER2. Similarly, physical exercise reduces sex hormone levels, which may help protect against breast cancer. Obesity promotes tumor cell growth and cell survival through upregulation of leptin and insulin-like growth factors. This review seeks to discuss these underlying mechanisms, and more behind the three major prevention strategies, as a means of understanding how breast cancer can be prevented.

Synthesis, characterization and dose dependent antimicrobial and anticancerous efficacy of phycogenic (Sargassum muticum) silver nanoparticles against Breast Cancer Cells (MCF 7) cell line

  • Supraja, Nookala;Dhivya, J.;Prasad, T.N.V.K.V.;David, Ernest
    • Advances in nano research
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    • v.6 no.2
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    • pp.183-200
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    • 2018
  • In the present study silver nanoparticles (AgNPs) were successfully synthesized using aqueous extract of Sargassum muticum. The aqueous extract (10%) treated with 1 mM silver nitrate solution resulted in the formation of AgNPs and the surface plasmon resonance (SPR) of the formed AgNPs was recorded at 360 nm using UV-Visible spectrophotometer. The molecules involved in the formation of AgNPs were identified by Fourier transform infrared spectroscopy (FT-IR), surface morphology was studied by using scanning electron microscopy (SEM), SEM micrograph clearly revealed the size of the AgNPs was in the range of 40-65 nm with spherical, hexagonal in shape and poly-dispersed nature, and X-ray diffraction spectroscopy (XRD) was used to determine the crystalline structure. High positive Zeta potential (36.5 mV) of formed AgNPs indicates the stability and XRD pattern revealed the crystal structure of the AgNPs by showing the Bragg's peaks corresponding to (111), (200), (311) and (222) planes of face-centered cubic crystal phase of silver. The synthesized AgNPs exhibited effective anticancerous activity (at doses 25 and $50{\mu}g/ml$ of AgNPs) against Breast cancer cell line (MCF7).

A Study on the Use of Momentum Interpolation Method for Flows with a Large Body Force (바디포오스가 큰 유동에서 운동량보간법의 사용에 관한 연구)

  • Choi Seok-Ki;Kim Seong-O;Choi Hoon-Ki
    • Journal of computational fluids engineering
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    • v.7 no.2
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    • pp.8-16
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    • 2002
  • A numerical study on the use of the momentum interpolation method for flows with a large body force is presented. The inherent problems of the momentum interpolation method are discussed first. The origins of problems of the momentum interpolation methods are the validity of linear assumptions employed for the evaluation of the cell-face velocities, the enforcement of mass conservation for the cell-centered velocities and the specification of pressure and pressure correction at the boundary. Numerical experiments are performed for a typical flow involving a large body force. The numerical results are compared with those by the staggered grid method. The fact that the momentum interpolation method may result in physically unrealistic solutions is demonstrated. Numerical experiments changing the numerical grid have shown that a simple way of removing the physically unrealistic solution is a proper grid refinement where there is a large pressure gradient. An effective way of specifying the pressure and pressure correction at the boundary by a local mass conservation near the boundary is proposed, and it is shown that this method can effectively remove the inherent problem of the specification of pressure and pressure correction at the boundary when one uses the momentum interpolation method.

Analysis of Natural Convection Heat Transfer and Solidification of a Two-Layered Pool (2층으로 성층화된 풀 내에서의 자연대류 열전달과 고화현상에 대한 연구)

  • Kim J.;Kang K. S.;Kim S. B.;Kim H. D.
    • Journal of computational fluids engineering
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    • v.6 no.1
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    • pp.1-13
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    • 2001
  • The natural convection heat transfer and solidification in a stratified pool are studied. The flow and heat transfer characteristics in a heat generating pool are compared between single-layered and double-layered pools. And local Nusselt number distributions on outer walls are obtained to consider thermal loads on a vessel wall. The cooling and solidification of Al₂O₃/Fe melt in a hemispherical vessel are simulated to study the mechanism of heat transfer and temperature distribution. A unstructured mesh is chosen for this study because of the non-orthogonality originated from the boundaries of double-layered pool. Interface between the layers is modeled to be fixed. With this assumption mass flux across the interface is neglected, but shear force and heat flux are considered by boundary conditions. The colocated cell-centered finite volume method is used with the Rhie-Chow interpolation to compute cell face velocity. To prevent non-physical solutions near walls in case body force is large the wall pressure is extrapolated by the way to include body force. The numerical solutions calculated by current method show that averaged downward heat flux of the double-layered pool increases compared to single-layered pool and maximum temperature occurs right below the interface of the layers.

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CFD CODE DEVELOPMENT FOR THE PREDICTION OF THE SHIP RESISTANCE USING OPEN SOURCE LIBRARIES (소스공개 라이브러리를 활용한 선박 저항계산 CFD 코드 개발)

  • Park, Sun-Ho;Park, Se-Wan;Rhee, Shin-Hyung;Lee, Sang-Bong;Choi, Jung-Eun;Kang, Seon-Hyung
    • Journal of computational fluids engineering
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    • v.17 no.2
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    • pp.21-27
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    • 2012
  • Reynolds-averaged Navier-Stokes equations solver based on a pressure-based cell-centered finite volume method was developed using OpenFOAM libraries, which was an open source and providing computational continuum mechanics libraries. For the reasonable development of the turbulent boundary layer on the bow of the ship, specified library was developed. Grid sensitivities, such as skewness and aspect ratio of a cell, were tested for the solution convergence. Pressure, turbulent kinetic energy, turbulent dissipation rate contours on the ship surface computed by the developed CFD code were compared with those computed by the commercial CFD code, Fluent.

Dynamic Behavioral Prediction of Escherichia coli Using a Visual Programming Environment (비쥬얼 프로그래밍 환경을 이용한 Escherichia coli의 동적 거동 예측)

  • Lee, Sung-Gun;Hwang, Kyu-Suk;Kim, Cheol-Min
    • Proceedings of the Korean Society for Bioinformatics Conference
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    • 2004.11a
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    • pp.39-49
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    • 2004
  • When there is a lack of detailed kinetic information, dFBA(dynamic flux balance analysis) has correctly predicted cellular behavior under given environmental conditions with FBA and different ial equations. However, until now, dFBA has centered on substrate concentration, cell growth, and gene on/off, but a detailed hierarchical structure of a regulatory network has not been taken into account. For this reason, the dFBA has limited the represen tation of interactions between specific regulatory proteins and genes and the whole transcriptional regulation mechanism with environmental change. Moreover, to calculate optimal metabolic flux distribution which maximizes the growth flux and predict the b ehavior of cell system, linear programming package(LINDO) and spreadsheet package(EXCEL) have been used simultaneously. thses two software package have limited in the visual representation of simulation results and it can be difficult for a user to look at the effects of changing inputs to the models. Here, we descirbes the construction of hierarchical regulatory network with defined symbolsand the development of an integrated system that can predict the total control mechanism of regulatory elements (opero ns, genes, effectors, etc.), substrate concentration, growth rate, and optimal flux distribution with time. All programming procedures were accoplished in a visual programming environment (LabVIEW).

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