• Title/Summary/Keyword: Cell durability

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Development of An Accelerated Durability Test Mode for Fuel Cell (연료전지 가속내구모드 개발)

  • LEE, YONGHEE;OH, DONGJO;JEON, UISIK;LEE, JONGHYUN
    • Journal of Hydrogen and New Energy
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    • v.26 no.5
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    • pp.493-498
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    • 2015
  • The fuel cell vehicle is a type of hydrogen vehicle which uses a fuel cell to produce electricity, powering its on-board electric motor. The fuel cell vehicle driving principle is completely different from the internal combustion engine vehicle. In order to ensure the durable quality of the fuel cell vehicle, durability test mode considering the characteristics of the fuel cell must be developed. In this study, we derived the durability test mode profile through collecting and analyzing fuel cell vehicle driving data. Then, the accelerated durability test mode is developed by adding degradation conditions and is experimentally validated to have an acceleration factor of 5~6.

Synthesis and Durability of Carbon-Supported Catalysts for PEMFC (내구성 향상을 위한 연료전지 촉매 개발)

  • YI, MI HYE;CHOI, JIN SUNG;RHO, BUMWOOK
    • Journal of Hydrogen and New Energy
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    • v.26 no.4
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    • pp.318-323
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    • 2015
  • For commercialization of fuel cell electric vehicles, one of the key objectives is to improve durability of MEA and electrocatalysts. Regarding electrocatalysts, the major issue is to reduce carbon corrosion and dissolution of Pt caused by harsh conditions, for example, SU/SD (Start-up/Shut-down). In this research, OER (Oxygen Evolution Reaction) catalyst has been developed improvement of durability. A modified polyol process is developed by controlling the pH of the solvent to synthesize the PtIr nanocatalysts on carbon supports. Each performance of the MEAs applying PtIr and Pt are equivalent because PtIrnanocatalysts have both ORR and OER activity. Breadboard test for catalyst durability in harsh conditions and high potentialsis found that the MEA applying PtIrnanocatalysts durability is improved more than the MEA applying Pt nanocatalysts.

Preparation and Characterization of the Polymeric Antioxidant for Improving the Chemical Durability of Polymer Electrolyte Membranes (고분자 전해질 막의 화학적 내구성 향상을 위한 고분자형 산화방지제 제조 및 특성 분석)

  • LEE, BYEOL-NIM;KODIR, ABDUL;LEE, HYEJIN;SHIN, DONGWON;BAE, BYUNGCHAN
    • Journal of Hydrogen and New Energy
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    • v.32 no.5
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    • pp.308-314
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    • 2021
  • Chemical durability issue in polymer electrolyte membranes has been a challenge for the commercialization of polymer electrolyte membrane fuel cells (PEMFCs). In this study, we proposed a manufacturing method of Nafion composite membrane containing a stable polyimide antioxidant to improve the chemical durability of the membrane. The thermal casting of the Nafion solution with poly (amic acid) induced polyimide reaction. We evaluated proton conductivity, oxidative stability with ex-situ Fenton's test, and fluoride ion emission to analyze the effect of polyimide antioxidants. We confirmed that incorporating the polyimide antioxidant improves the chemical durability of the Nafion membrane while maintaining inherent proton conductivity.

Durability Evaluation Study of Re-manufactured Photovoltaic Modules (재 제조 태양광모듈의 내구성능 평가 연구)

  • Kyung Soo Kim
    • Current Photovoltaic Research
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    • v.12 no.1
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    • pp.17-23
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    • 2024
  • Photovoltaic (PV) power generation is the world's best and largest renewable energy that generates electricity with infinite sunlight. Solar cell modules are a component of photovoltaic power generation and must have a long-term durability of at least 25 years. The development of processes and equipment that can be recovered through the recycling of metals and valuable metals when the solar module's lifespan is over has been completed to the level of commercialization, but few processes have been developed that require repair due to initial defects. This is mainly due to the economic problems caused by remaking. However, if manufacturing processes such as repairing solar cell modules that have been proven to be early defects are established and the technical review of long-term reliability and durability reaches a certain level, it is considered that it will be a recommended process technology for environmental economics. In this paper, assuming that a defective solar cell module occurs artificially, a manufacturing process for replacement of solar cells was developed, and a technical verification of the manufacturing technology was conducted through long-term durability evaluation in accordance with KS C 8561. Through this, it was determined that remanufacturing technology for solar cell replacement of solar cell modules that occurred in a short period of time after installation was possible, and the research results were announced through a journal to commercialize solar modules using manufacturing technology in the solar market in the future.

Coating Durability of Metal Bipolar plate for Low Temperature PEMFC (저온 PEMFC용 금속분리판 코팅의 내구 특성 연구)

  • Kang, Sungjin;Jeon, Yootaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.82.2-82.2
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    • 2010
  • The development of bipolar plate having high efficiency and chemical properties has a major impact on fuel cell applications commercialization. Even though graphite bipolar plate has high electric conductivity and chemical resistance, it has demerits about mass production and brittle property for commercialization. Hence, metallic bipolar plate can be substitute for fuel cell bipolar plate. Although its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions, metallic bipolar plate for PEMFC is more suitable for automotive and residential power generation system because of its high mechanical strength, low gas permeability and applicability to mass production. Therefore, several types of coating has been applied to prevent corrosion and oxide film growth and to achieve more high durability. This work presents durability of coated metal bipolar plate for low temperature PEMFC which made for fuel cell vehicle. This results showed surface treatment increase long-term durability, even electric conductivity and corrosion resistance.

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Experimental Analysis of GDL Degradation in PEM Fuel Cell (고분자전해질형 연료전지 가스확산층의 내구 성능 저하에 관한 실험적 분석)

  • Ha, Tae-Hun;Park, Jae-Man;Cho, Jun-Hyun;Min, Kyoung-Doug;Lee, Eun-Suk;Jung, Ji-Young;Kim, Do-Hun;Jin, Yong-Won;Lee, Dae-Han
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.132-132
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    • 2009
  • To achieve the commercialization of PEM fuel cell, the durability problem must be solved. Recently, many researchers have focused on this durability problem and degradation studies about membrane and electrode have been reported. But durability characteristics of gas diffusion layer is not much reported yet. Durability of GDL is very important to maintain the performance of PEM fuel cell because the main function of GDL is a path of fuel and water and the GDL degradation causes the loss of the GDL function. In this study, the degradation of GDL, especially, the mechanical degradation process was investigated with the leaching test. The effect of water dissolution was observed through the test and the amount of GDL degradation was measured with various measurement methods such as weight measurement, static contact angle measurement, scanning electron microscope. After 2,000 hours test, the GDL showed structural damage and loss of hydrophobicity.

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A Study on the Vibratory Characteristics of the Stack in Fuel Cell Vehicle at Driving Condition (연료전지 차량 주행시 스택의 진동 특성 연구)

  • Ju, Hyung-Jun;Kim, Gi-Hoon;Park, Jae-Yong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.5
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    • pp.50-55
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    • 2010
  • In recent years, the development of fuel cell vehicles has further accelerated because of environmental problem and petroleum resources shortage. The fuel cell vehicles have the stack which converts fuel to electricity. The stack is usually mounted by bush to isolate the vibration of chassis and body. This paper analyzed the vibratory characteristics of stack and chassis, body system. The wheel forces of fuel cell vehicle are measured to estimate the road load data. And the paths of vibration from wheel to stack are analyzed by CAE. According to the test and CAE results, the improvement of stack vibration are evaluated.

Development of Air Cutoff Valve for Improving Durability of Fuel Cell (연료전지 내구성능 향상을 위한 공기차단밸브 개발)

  • Park, Jeonghee;Lee, Changha;Kwon, Hyuckryul;Kim, Chimyung;Choi, Kyusung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.1
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    • pp.49-55
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    • 2015
  • In this study, among in various scenarios of the duration degradation of the fuel cell, countermeasures for the cathode carbon carrier oxidation and the deactivation of catalyst by hydrogen / air interface formation have been studied. so the system was applied to the air cutoff valve. In terms of the component, the cold start performance, electrical stability, the airtight performance were mainly designed and their performance was confirmed. And in terms of the system, the air electrode flow is blocked off, so the oxygen concentration drops when system is powered off, As a result, By reducing unit cell voltage which affect the durability of the fuel cell reached up to 0.8V, the improved durability of the fuel cell was confirmed.

Developing Sealing Material of a Dye-Sensitized Solar Cell for Outdoor Power (실외 발전을 위한 염료감응형 태양전지의 봉지재 개발)

  • Ki, Hyun-Chul;Hong, Kyung-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.12
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    • pp.819-823
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    • 2016
  • DSSC (dye-sensitized solar cell) is expected to be one of the next-generation photovoltaics because of its environment-friendly and low-cost properties. However, commercialization of DSSC is difficult because of the electrolyte leakage. We propose thermal curable base on silicon resin and apply a unit cell and large area ($200{\times}200mm$) dye-sensitized solar cell. The resin aimed at sealing of DSSC and gives a promising resolution for sealing of practical DSSC. In result, the photoelectric conversion efficiency of the unit cell and the module was 6.63% and 5.49%, respectively. In the durability test result, the photoelectric conversion efficiency of the module during 500, 1,000, 1,500 and 2,000 hours was 0.73%, 0.73%, 1.82% and 2.36% respectively. It was confirmed that the photoelectric conversion efficiency characteristics are constant. We have developed encapsulation material of thermal curing method excellent in chemical resistance. A sealing material was applied to the dye-sensitized solar cell and it solved the problem of durability the dye-sensitized solar cell. Sealing material may be applied to verify the possibility of practical application of the dye-sensitized solar cell.

The Optimimum Gel Content Characteristics for Cell Cracks Prevention in PV Module (PV모듈의 cell crack 방지를 위한 EVA Sheet의 최적 Gel content 특성)

  • Kang, Kyung-Chan;Kang, Gi-Hwan;Kim, Kyung-Soo;Huh, Chang-Su;Yu, Gwon-Jong
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1108-1109
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    • 2008
  • To survive in outdoor environments, photovoltaic modules rely on packaging materials to provide requisite durability. We analyzed the properties of encapsulant materials that are important for photovoltaic module packaging. Recently, the thickness of solar cell gets thinner to reduce the quantity of silicon. And the reduced thickness make it easy to be broken while PV module fabrication process. Solar cell's micro cracks are increasing the breakage risk over the whole value chain from the wafer to the finished module, because the wafer or cell is exposed to tensile stress during handling and processing. This phenomenon might make PV module's maximum power and durability down. So, when using thin solar cell for PV module fabrication, it is needed to optimize the material and fabrication condition which is quite different from normal thick solar cell process. Normally, gel-content of EVA sheet should be higher than 80% so PV module has long term durability. But high gel-content characteristic might cause micro-crack on solar cell. In this experiment, we fabricated several specimen by varying curing temperature and time condition. And from the gel-content measurement, we figure the best fabrication condition. Also we examine the crack generation phenomenon during experiment.

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