• Title/Summary/Keyword: CeO2

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Manufacturing of YBCO coated conductor deposited on RABiTS by pulsed laser deposition method (RABiTS 위에 PLD 방법으로 증착된 YBCO 초전도 박막 선재의 제조)

  • Ko Rock-Kil;Shi Dongqi;Chung Jun-Ki;Ha Hong-Soo;Kim Ho-Soup;Song Kyu-Jeong;Park Chan;Moon Seung-Hyun;Yoo Sang Im;Kim Young-Cheol
    • Progress in Superconductivity
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    • v.6 no.1
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    • pp.74-78
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    • 2004
  • YBCO coated conductor is one of the most promising materials as a new generations wire especially for practical power applications. In this work, $YBa_2$$Cu_3$$O_{7}$ -$\delta$/(YBCO) coated conductors (CC) were deposited by pulsed laser deposition (PLD) from buffer layers to superconducting layer on hi-axially textured metal tape. The oxide multilayer buffered substrate of architectures of $CeO_2$/$YSZ/Y_2$$O_3$ was fabricated by PLD at steady status. Then YBCO layer was deposited on RABiTS substrate by stationary and reel-to-reel (R2R) continuous process and we compared with deposition conditions of both processes. The degree of texture of each layer was investigated using X-ray diffraction including $\theta$-2$\theta$ scans, $\omega$-scans and $\Phi$-scans analysis. Their surface morphology was observed by scanning electron microscopy (SEM). The FWHM of the X-ray $\Phi$-scans and $\Phi$-scans indicated that YBCO and buffer layers closely replicate the in-plane and out-of-plane texture of metal tape. Critical current (Ic) at 77 K, self-field of 75.8 A/cm-width, critical temperature (Tc) of 85 K, and critical current density (Ic) of 3.7 MA/$\textrm{cm}^2$ were measured from coated conductor deposited by stationary process. And coated conductor deposited by R2R continuous process had Ic of 57.5 A/cm-width, Tc of 86.5 K and Jc of 2.0 MA/$\textrm{cm}^2$. The film also exhibits a homogeneous and dense surface morphology.

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Overview of the Effect of Catalyst Formulation and Exhaust Gas Compositions on Soot Oxidation In DPF

  • Choi Byung Chul;FOSTER D.E.
    • Journal of Mechanical Science and Technology
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    • v.20 no.1
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    • pp.1-12
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    • 2006
  • This work reviews the effects of catalyst formulation and exhaust gas composition on soot oxidation in CDPF (Catalytic Diesel Particulate Filter). DOC's (Diesel Oxidation Catalysts) have been loaded with Pt catalyst (Pt/$Al_{2}O_3$) for reduction of HC and CO. Recent CDPF's are coated with the Pt catalyst as well as additives like Mo, V, Ce, Co, Fe, La, Au, or Zr for the promotion of soot oxidation. Alkali (K, Na, Cs, Li) doping of metal catalyst tends to increase the activity of the catalysts in soot combustion. Effects of coexistence components are very important in the catalytic reaction of the soot. The soot oxidation rate of a few catalysts are improved by water vapor and NOx in the ambient. There are only a few reports available on the mechanism of the PM (particulate matter) oxidation on the catalysts. The mechanism of PM oxidation in the catalytic systems that meet new emission regulations of diesel engines has yet to be investigated. Future research will focus on catalysts that can not only oxidize PM at low temperature, but also reduce NOx, continuously self-cleaning diesel particulate filters, and selective catalysts for NOx reduction.

Sintering and Grain Growth of Rare Earth-Doped Ceria Particles

  • Sameshima, Soichiro;Higashi, Kenji;Hirata, Yoshihiro
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.65-86
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    • 2000
  • Rare earth-doped ceria powders with a composition of Ce0.8R0.2O1.9(R=Yb, Y, Gd, Sm, Nd and La) were prepared by heating the oxalate coprecipitate. The green compacts began to shrink at 600$^{\circ}$-700$^{\circ}C$. The relative density after the sintering at 1200$^{\circ}$ and 1400$^{\circ}C$ became higher for the higher green density. The samples were densified above 98% relative density by the sintering ant 1600$^{\circ}C$ for 4 h and the grain sizes (4.7-7.6$\mu\textrm{m}$) showed a tendency to become larger with increasing ionic radius of doped-rare earth element. In the intial stag of sintering at 700$^{\circ}$-800$^{\circ}C$, the dominant mass transport process changed from lattice diffusion to grain boundary diffusion to grain boundary diffusion with heating time. The porosity during the intermediated and final stage of the sintering at 1200$^{\circ}$ and 1400$^{\circ}C$ decreased by the mass transport through lattice diffusion with grain growth.

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Effect of Pressure on Microstructures and Mechanical Properties in Al-5%Ni-5%Mg-(Mm) Alloy Manufactured by Direct Squeeze Casting (직접가압주조한 Al-5%Ni-5%Mg-(Mm)합금의 조직 및 기계적 성질에 미치는 가압력의 영향)

  • Woo, Kee-Do;Chung, Dong-Suk;Hwang, In-O;Kim, Sug-Won
    • Journal of Korea Foundry Society
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    • v.21 no.2
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    • pp.127-134
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    • 2001
  • Misch metal (rare earth element, Ce, La, Nd, Pr) which has large influence on high-temperature stability and toughness was added to the Al-5%Ni-5%Mg alloy, and squeeze casting was used for Al-5%Ni-5%Mg-(Mm) alloys. The effect of applied pressure and misch metal additions on mechanical properties in Al-5%Ni-5%Mg alloy by direct squeeze casting has been investigated. The applied pressure were 0 MPa(gravity casting), 25, 50 and 75 MPa. Squeeze-cast Al-5%Ni-5%Mg-(Mm) alloys had better mechanical properties than those of non-pressurized cast alloys because of the increased cooling rate by the application of pressure during solidification. By the addition of misch metal in Al-5%Ni-5%Mg alloy, better combination of strength and elongation was obtained. The addition of 0.3%Mm in Al-5%Ni-5%Mg alloy improved the heat resistant property due to the formation of fine eutectic phases.

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The Study of a-Si Film Crystallization using an XeCl Laser Annealing on the Plastic Substrate

  • Kim, Do-Young;Suh, Chang-Ki;Shim, Myung-Suk;Kim, Chi-Hyung;Yi, Jun-Sin;Lee, Min-Chul;Han, Min-Gu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.634-638
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    • 2003
  • We reported the a-Si crystallization using a XeCl excimer laser annealing on the plastic substrate. The poly-Si film is able to grow in the low temperature and light substrate like a plastic. For the preparation of sample, substrate is cleaned by organic liquids. The film of $CeO_{2}$ layer as the buffer layer was grown by sputtering methods. After a-Si film deposition using ICPCVD, the film was crystallized by XeCl excimer laser. In this paper, we present the crystallization properties of a-Si on the plastic substrate

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Characterization of YBCO do SQUID fabricated on sapphire substrate for biomagnetic applications (생체자기 응용을 위한 사파이어 기판 위에 제작된 YBCO dc SQUID 의 특성)

  • Lim, Hae-Ryong;Kim, In-Seon;Kim, Dong-Ho;Park, Yong-Ki;Park, Jong-Chul
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.155-159
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    • 2000
  • YBCO step-edge dc SQUID magnetometers on sapphire substrates have been fabricated. CeO2 buffer layer and YBCO films were deposited in situ on the low angle (${\sim}$35$^{\circ}$) steps formed on the sapphire substrates. Typical 5-${\mu}$m-wide junction has R$_n$ of 5 ${\omega}$ and I$_c$ of 50 ${\mu}$A with large I$_c$R$_n$ product of 250 ${\mu}$V at 77K. According to applied bias current, depth of voltage modulation was changed and maximum voltage was measured 16 ${\mu}$V. Field noise of do SQUID was measured 100${\sim}$300 fT/${\surd}^{Hz}$ in the 1 $^{kHz}$, and about 1.5 pT/${\surd}^{Hz}$ in the 1/f region. For ac bias reversal method, field noise was decreased in the 1/f region. The QRS peak of magnetocardiogram was measured 50 pT in the magnetically shielded room.

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Study on the Abrasive Capsulation Pad in Interlayer Dielectric Chemical Mechanical Polishing (층간절연막 화학기계연마에서 입자코팅패드에 관한 연구)

  • Kim, Ho-Yun;Park, Jae-Hong;Jeong, Hae-Do;Seo, Hyeon-Deok;Nam, Cheol-U;Lee, Sang-Ik
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.11
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    • pp.168-173
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    • 2001
  • The chemical mechanical polishing (CMP) is generally consisted of pad, slurry including abrasives and so on. However, there are some problems in a general CMP: defects, a high Cost of Consumable (CoC), an environmental problem. The slurry including abrasives especially gives rise to not only increase a CoC, but also prohibition from achieving an eco-process. This paper introduces an abrasive capsulation pad to achieve an eco-process decreasing abrasives used is CMP. The binder wth a water a water swelling and a water soluble characteristic is used for an auto-conditioning, and the $CeO_2$abrasive is selected for an abrasive capsulation pad. Comparing with a conventional CMP, an abrasive capsulation pad appears good characteristics in ILD CMP and is able to achieve an eco-process decreasing wasted slurry.

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Interaction of Rare Earth Chloride Salts to Alumina and Mullite in LiCl-KCl at 773 K

  • Horvath, David;Warmann, Stephen;King, James;Marsden, Kenneth;Hoover, Robert
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.3
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    • pp.337-346
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    • 2020
  • Two commonly used ceramics in molten salt research are alumina and mullite. The two ceramics were exposed to a combination of rare earth chlorides (YCl3, SmCl3, NdCl3, PrCl3, and CeCl3; each rare earth chloride of 1.8 weight percent) in LiCl-KCl at 773 K for approximately 13 days. Scanning electron microscopy with wave dispersion spectra was utilized to investigate a formation layer or deposition of rare earths onto the ceramic. Only the major constituents of the ceramics (Al, Si, and O2) were observed during the wave dispersion spectra. X-ray fluorescence was used as well to determine concentration changes in the molten salt as a function of ceramic exposure time. This study shows no evidence of ionic exchange or layer formation between the ceramics and molten chloride salt mixture. There are signs of surface tension effects of molten salt moving out of the tantalum crucible into secondary containment.

High Luminance 3D Built-In PDP Panel with Fast-Decaying Phosphor

  • Kim, Young-Kwan;Yoo, Young-Gil;Lee, Soon-Rewl;Kim, Min-Kyu;Kim, Jeong-Hee;Chung, Kyeong-Woon;Choi, Ick-Kyu;Song, Jay-Hyok;Song, Yu-Mi;Kim, Yoon-Chang;Heo, Eun-Gi;Zang, Dong-Sik;Chung, Chong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.127-130
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    • 2009
  • High luminance 3D built-in PDP panel was developed with newly adopted fast-decaying phosphor. Luminance of 3D PDP was increased about 40% by reducing the particle size of RGB phosphors and using $Y_3(Al,Ga)_5O_{12}:Ce^{3+}$ phosphor. Decay time of developed 3D PDP was 5.2ms/4.9ms for Red/Green color.

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The Study of Metal CMP Using Abrasive Embedded Pad (고정입자 패드를 이용한 텅스텐 CMP에 관한 연구)

  • Park, Jae-Hong;Kim, Ho-Yun;Jeong, Hae-Do
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.12
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    • pp.192-199
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    • 2001
  • Chemical mechanical planarization (CMP) has emerged as the planarization technique of choice in both front-end and back-end integrated circuit manufacturing. Conventional CMP process utilize a polyurethane polishing pad and liquid chemical slurry containing abrasive particles. There hale been serious problems in CMP in terms of repeatability and deflects in patterned wafers. Especial1y, dishing and erosion defects increase the resistance because they decrease the interconnection section area, and ultimately reduce the lifetime of the semiconductor. Methods to reduce dishing & erosion have recently been interface hardness of the pad, optimization of the pattern structure as dummy patterns. Dishing & erosion are initially generated an uneven pressure distribution in the materials. These defects are accelerated by free abrasives and chemical etching. Therefore, it is known that dishing & erosion can be reduced by minimizing the abrasive concentration. Minimizing the abrasive concentration by using CeO$_2$is the best solution for reducing dishing & erosion and for removal rate. This paper introduce dishing & erosion generating mechanism and a method fur developing a semi-rigid abrasive pad to minimize dishing & erosion during CMP.

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