• 제목/요약/키워드: Cathodic protection method

검색결과 89건 처리시간 0.026초

A Study on Corrosion Resistance Characteristics of PVD Cr-N Coated Steels by Electrochemical Method

  • Ahn, SeungHo;Yoo, JiHong;Choi, YoonSeok;Kim, JungGu;Han, JeonGun
    • Corrosion Science and Technology
    • /
    • 제2권6호
    • /
    • pp.289-295
    • /
    • 2003
  • The corrosion behavior of Cr-N coated steels with different phases (${\alpha}-Cr$, CrN and $Cr_2N$) deposited by cathodic arc deposition on Hl3 steel was investigated in 3.5% NaCl solution at ambient temperature. Potentiodynamic polarization test, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) were the techniques applied to characterize the corrosion behavior. It was found that the CrN coating had a lower current density from potentiodynamic polarization test than others. The porosity, corresponding to the ratio of the polarization resistance of the uncoated and the coated substrate, was higher in the $Cr_2N$ coating than in the other Cr-N coated steels. EIS measurements showed, for the most of Cr-N coated steels, that the Bode plot presented two time constants. Also, the $Cr_2N$ coating represents the characteristic of Warburg behavior after 72hr of immersion. The coating morphologies were examined in planar view and cross-section by SEM analyses and the results were compared with those of the electrochemical measurement. The CrN coating had a dense, columnar grain-sized microstructure with minor intergranular porosity. From the above results, the CrN coating provided a better corrosion protection than the other Cr-N coated steels.

외면부식 직접평가법 개발 및 국내 도입 연구 (The Development and Introduction of External Corrosion Direct Assessment Measures for Urban Gas Pipelines)

  • 류영돈;이진한;윤영기;임호석
    • 한국가스학회지
    • /
    • 제18권5호
    • /
    • pp.12-19
    • /
    • 2014
  • 매설배관의 부식위험성을 최소화하고 음극방식의 효율극대화를 위해 다양한 비굴착 간접검사기법들이 수십년 전부터 이용되고 있으며, 미국에서는 굴착을 통한 매설배관 외면부식 직접평가법을 CFR 코드에서 규정하고 있다. 국내의 경우에는 도시가스사업법 관련 4개의 기준(KGS Code)에서 배관의 손상여부를 측정할 수 있는 장비를 이용하여 배관의 상태를 점검, 측정하고 이상부위에 대하여 누출검사를 한 경우 매설배관의 기밀시험을 한 것으로 보고 있을 뿐 배관외면부식 직접평가에 대한 규정은 없다. 본 논문에서는 미국, 영국 등 국외의 매설배관 건전성 관리 기준 및 방법을 조사하고, 국내의 매설배관 방식관리 실태 및 피복손상탐지 장치 이용실태 등을 조사한 후 국내 실정에 맞는 매설배관 외면부식 직접평가법을 제시하였다. 본 논문에서 제시한 매설배관 외면부식 직접 평가법은 국내에서 중압배관의 정밀안전진단 제도를 도입하는데 기초 자료로 활용되었다.

매설배관과 직류전기철도의 표유전류 간섭분석 (Analysis of Stray Current Interference between Underground Pipelines and DC Electric Railways)

  • 하윤철;배정효;하태현;이현구;김대경
    • 한국가스학회지
    • /
    • 제10권3호
    • /
    • pp.41-47
    • /
    • 2006
  • 가스배관, 상수관, 송유관 등의 지중 매설배관이 직류 전기철도와 인접해 있는 경우, 전기철도 시스템의 귀선 회로로 사용되는 레일에서 누설되는 표유전류에 의해 이들 금속배관에는 전기적 부식, 즉 전식이 발생할 수 있다. 전식에 의한 집중 부식은 전기방식으로 보호되는 배관에 있어서도 지속적인 재료의 열화와 이에 따른 파손을 일으킬 수 있어 대형사고로 발전할 소지를 가지고 있다. 국내에서는 이러한 표유전류에 대한 대책으로 배관과 레일을 전기적으로 접속하는 배류법이 적용되고 있는데 특히 가스배관을 중심으로 한 강제배류법의 급속한 증가에 의해 간섭문제가 매우 복잡해지고 있다. 본 논문에서는 직류전기철도시스템과 매설배관 사이의 전기적 간섭 문제를 서울과 부산 지역에서 수행한 현장 실태조사의 결과를 통해 살펴본다.

  • PDF

매설 배관 피복 결함 탐상 정확도에 미치는 인접 정류기 및 접지 구리망 간섭의 영향 (Effects of Rectifier and Copper Grid Interference on the Detection Reliability of Coating Flaws on Buried Pipes)

  • 김민기;임부택;김기태;장현영;박흥배;김영식
    • Corrosion Science and Technology
    • /
    • 제19권4호
    • /
    • pp.211-223
    • /
    • 2020
  • The external corrosion of buried piping can be controlled using both coating and cathodic protection. Several factors are involved in the damage and deterioration of the coating on pipes. There are many detection methods for coating defects on pipes and the direct current voltage gradient (DCVG) method is one of the most powerful methods. However, the detection reliability of DCVG can be affected by interferences such as stray current, metal objects connected to rectifiers, and copper grids. Therefore, this study focused on the interference effects of rectifiers and a copper grid on the reliability of coating flaw detection. As the length of the interference pipe connected to the rectifier increased, the reliability decreased. In contrast, as the distance between the pipe and the copper grid increased, the reliability of the coating flaw detection increased. The detection results produced by the DCVG method were discussed using current and potential simulations for a pipe with a rectifier and copper grid interference in the soil.

다전극 탐상을 통한 토중 매설배관 피복결함 탐상 정확도의 개선 (Enhancing the Reliability of Coating Flaw Detection for Pipes Buried in Soil Using a Multi-Electrode Detector)

  • 김민기;임부택;김기태;장현영;박흥배;김영식
    • Corrosion Science and Technology
    • /
    • 제19권5호
    • /
    • pp.265-280
    • /
    • 2020
  • External corrosion of buried pipes can be controlled using both coating and cathodic protection. However, deterioration of the coating can occur due to several reasons. The detection reliabilty of coating flaw detection methods is affected by interference such as metal objects connected to rectifiers and copper grids. When performing parallel direct current voltage gradient (DCVG) inspection, a sine wave form without potential reversal in voltage gradient appears in the area where the interference exists. However, this area may be not identified using existing methods. The objective of this study was to determine the effect of analyzing direction on the reliability of coating flaw detection of pipes buried in soil using a multi-electrode detector. DCVG on the buried pipe was measured along the buried pipe. This measurement parallel to the pipe was repeated. Measured data were analyzed for parallel, vertical, and diagonal directions. The reliability of coating flaw detection was improved by up to 46.4% compared to the conventional method.

쇄석을 가스배관 채움재로 사용시 배관피복에 미치는 영향 연구 (Study on the damage effect to the Gas pipeline coating by the crashed stone backfill material)

  • 조성호;전경수;이선엽;조용범;고영태
    • 한국가스학회지
    • /
    • 제2권1호
    • /
    • pp.23-27
    • /
    • 1998
  • 음극방식 시스템의 방식전류에 의한 압입구간내의 압입관과 배관의 부식거동에 관한 수학적 모델링을 경계요소법을 이용하여 수행하였다. 모델은 비선형 경계조건(Tafel 방정식)을 가진 라플라스 방정식으로 이루어져 있으며 압입관의 혼합전위를 구하기 위하여 혼합전위 이론을 응용한 반복법을 사용하였으며 그 위에 비선형 경계조건에 대한 해석을 위하여 이중 반복법을 사용하였다. 모델은 정상적인 압입구간 뿐만 아니라 압입관과 배관과의 금속간 접촉(metal touch)이나 외부환경과 압입구간 내부를 격리시키는 절연부위의 손상과 같은 결함들을 가진 비정상적인 압입구간에서의 각각의 경우에 대해서도 적용되었다. 수학적 모델링의 결과로부터 압입구간내의 전위분포나 전류분포를 계산할 수 있었다. 모델링의 타당성을 증명하기 위하여 모사실험을 수행하였으며 실험조건내에서 이론적인 결과와 실험결과는 정상적으로 잘 일치하였다.

  • PDF

차량을 이용한 원격전위 측정방법 개발에 관한 연구 (A Study on the Development of Remotely CP Potential Measuring Method by using Vehicle)

  • 류영돈;조영도;김진준;서민성
    • 한국가스학회지
    • /
    • 제20권5호
    • /
    • pp.64-71
    • /
    • 2016
  • 도시가스사업법령에 따라 지하에 매설된 도시가스 배관에는 전기부식 방지조치를 하도록 하고 있으며, 테스트 박스에서 배관의 방식전위를 1년마다 측정하도록 하고 있다. 그런데, 도심에 설치된 테스트 박스(T/B)의 경우 대부분 차량이 통행하는 도로위에 설치되어 있어 전위를 측정할 때 어려움이 있다. 즉, 전위를 측정하기 위해서는 차량을 통제하거나, 교통량이 적은 심야에 실시해야 하는 등 어려움이 있다. 본 연구에서는 이러한 방식전위 측정의 문제점을 해결하기 위하여 차량을 타고 이동하면서 테스트박스의 전위를 측정하는 방법을 연구하였다. 도로위에 설치된 테스트박스 하부에 기준전극과 데이터로거를 설치하고, 차량이 이동하면서 데이터로거로부터 방식 전위를 수신하는 방법으로 시험 연구를 진행하였다. 테스트 박스가 도로위에 설치되어 있어 전파를 송수신하는 데 어려움이 있어 안테나 방식을 변경해 가면서 가장 효과적인 방법을 채택하기로 하였다. 개발한 방법을 도시가스사의 실제 테스트박스에 적용한 결과 이 방법은 기존의 측정방법보다 20배 이상 시간을 절약할 수 있었다.

Seawater ballast tank 환경에서 저합금강의 내식성에 미치는 합금원소의 영향 (Effects of Alloying Elements on Corrosion Resistance of Low Alloyed Steels in a Seawater Ballast Tank Environment)

  • 김동우;김희산
    • 대한금속재료학회지
    • /
    • 제48권6호
    • /
    • pp.523-532
    • /
    • 2010
  • Co-application of organic coating and cathodic protection has not provided enough durability to low-alloyed steels inseawater ballast tank (SBT) environments. An attempt has made to study the effect of alloy elements (Al, Cr, Cu, Mo, Ni, Si, W) on general and localized corrosion resistance of steels as basic research to develop new low-allowed steels resistive to corrosion in SBT environments. For this study, we measured the corrosion rate by the weigh loss method after periodic immersion in synthetic seawater at $60^{\circ}C$, evaluated the localized corrosion resistance by an immersion test in concentrated chloride solution with the critical pH depending on the alloy element (Fe, Cr, Al, Ni), determined the permeability of chloride ion across the rust layer by measuring the membrane potential, and finally, we analyzed the rust layer by EPMA mapping and compared the result with the E-pH diagram calculated in the study. The immersion test of up to 55 days in the synthetic seawater showed that chromium, aluminium, and nickel are beneficial but the other elements are detrimental to corrosion resistance. Among the beneficial elements, chromium and aluminium effectively decreased the corrosion rate of the steels during the initial immersion, while nickel effectively decreased the corrosion rate in a longer than 30-day immersion. The low corrosion rate of Cr- or Al-alloyed steel in the initial period was due to the formation of $Cr_2FeO_4$ or $Al_2FeO_4$, respectively -the predicted oxide in the E-pH diagram- which is known as a more protective oxide than $Fe_3O_4$. The increased corrosion rate of Cr-alloyed steels with alonger than 30-day exposure was due to low localized corrosion resistance, which is explained bythe effect of the alloying element on a critical pH. In the meantime, the low corrosion rate of Ni-alloyed steel with a longer than 30-day exposure wasdue to an Ni enriched layer containing $Fe_2NiO_4$, the predicted oxide in the E-pH diagram. Finally, the measurement of the membrane potential depending on the alloying element showed that a lower permeability of chloride ion does not always result in higher corrosion resistance in seawater.

탄소계 경질 박막의 연구 및 산업 적용 동향 (Trend in Research and Application of Hard Carbon-based Thin Films)

  • 이경황;박종원;양지훈;정재인
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2009년도 춘계학술대회 논문집
    • /
    • pp.111-112
    • /
    • 2009
  • Diamond-like carbon (DLC) is a convenient term to indicate the compositions of the various forms of amorphous carbon (a-C), tetrahedral amorphous carbon (ta-C), hydrogenated amorphous carbon and tetrahedral amorphous carbon (a-C:H and ta-C:H). The a-C film with disordered graphitic ordering, such as soot, chars, glassy carbon, and evaporated a-C, is shown in the lower left hand corner. If the fraction of sp3 bonding reaches a high degree, such an a-C is denoted as tetrahedral amorphous carbon (ta-C), in order to distinguish it from sp2 a-C [2]. Two hydrocarbon polymers, that is, polyethylene (CH2)n and polyacetylene (CH)n, define the limits of the triangle in the right hand corner beyond which interconnecting C-C networks do not form, and only strait-chain molecules are formed. The DLC films, i.e. a-C, ta-C, a-C:H and ta-C:H, have some extreme properties similar to diamond, such as hardness, elastic modulus and chemical inertness. These films are great advantages for many applications. One of the most important applications of the carbon-based films is the coating for magnetic hard disk recording. The second successful application is wear protective and antireflective films for IR windows. The third application is wear protection of bearings and sliding friction parts. The fourth is precision gages for the automotive industry. Recently, exciting ongoing study [1] tries to deposit a carbon-based protective film on engine parts (e.g. engine cylinders and pistons) taking into account not only low friction and wear, but also self lubricating properties. Reduction of the oil consumption is expected. Currently, for an additional application field, the carbon-based films are extensively studied as excellent candidates for biocompatible films on biomedical implants. The carbon-based films consist of carbon, hydrogen and nitrogen, which are biologically harmless as well as the main elements of human body. Some in vitro and limited in vivo studies on the biological effects of carbon-based films have been studied [$2{\sim}5$].The carbon-based films have great potentials in many fields. However, a few technological issues for carbon-based film are still needed to be studied to improve the applicability. Aisenberg and Chabot [3] firstly prepared an amorphous carbon film on substrates remained at room temperature using a beam of carbon ions produced using argon plasma. Spencer et al. [4] had subsequently developed this field. Many deposition techniques for DLC films have been developed to increase the fraction of sp3 bonding in the films. The a-C films have been prepared by a variety of deposition methods such as ion plating, DC or RF sputtering, RF or DC plasma enhanced chemical vapor deposition (PECVD), electron cyclotron resonance chemical vapor deposition (ECR-CVD), ion implantation, ablation, pulsed laser deposition and cathodic arc deposition, from a variety of carbon target or gaseous sources materials [5]. Sputtering is the most common deposition method for a-C film. Deposited films by these plasma methods, such as plasma enhanced chemical vapor deposition (PECVD) [6], are ranged into the interior of the triangle. Application fields of DLC films investigated from papers. Many papers purposed to apply for tribology due to the carbon-based films of low friction and wear resistance. Figure 1 shows the percentage of DLC research interest for application field. The biggest portion is tribology field. It is occupied 57%. Second, biomedical field hold 14%. Nowadays, biomedical field is took notice in many countries and significantly increased the research papers. DLC films actually applied to many industries in 2005 as shown figure 2. The most applied fields are mold and machinery industries. It took over 50%. The automobile industry is more and more increase application parts. In the near future, automobile industry is expected a big market for DLC coating. Figure 1 Research interests of carbon-based filmsFigure 2 Demand ratio of DLC coating for industry in 2005. In this presentation, I will introduce a trend of carbon-based coating research and applications.

  • PDF