• Title/Summary/Keyword: Cathodic current density

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A Study on the Characteristics of Cathodic Protection by Al-Alloy Sacrificial Anode in Marine Environment (해양환경중에서 A1-합금희생양극에 의한 음극방식특성)

  • 이연호
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.28 no.1
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    • pp.53-60
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    • 1992
  • In this study, cathodic protection experiment was carried out by Al-alloy sacrificial anode in marine environments which have specific resistance($\rho$) if 25~7000$\Omega$.cm and investigated protection potential, current density and loss rate of Al-alloy sacrificial anode. The main results resistance($\rho$) of 400$\Omega$.cm, the cathodic protection potential appears high about-720 mV(SCE). But below specific resistance($\rho$) of 300$\Omega$.cm, the cathodic protection potential appears low about-770 mV(SCE) and simultaneously, cathode is protected sufficiently. 2) The loss rate of Al-Alloy sacrificial anode became large with decreasing specific resistance and increasing the ratio(A sub(c)/A sub(a) of bared surface area of anode and cathode. 3) The loss rate of Al-alloy sacrificial anode(w) to the mean current density of anode(i) is as follows. w=ai+b (a, b : experimental constants)

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Methods of Improving Operational Reliability of Oil Well Casing

  • Sergey A. Dolgikh;Irek I. Mukhamatdinov
    • Corrosion Science and Technology
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    • v.23 no.1
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    • pp.1-10
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    • 2024
  • Oil well casing leak is caused by contact of casing outer surface with formation electrolyte. It is usually associated with an aquifer with a high salt content or absence of a cement ring behind the casing. The only way to reduce external casing corrosion is through cathodic protection. Through cathodic polarization of casing structure, electron content in crystal lattice and electron density will increase, leading to a potential shift towards the cathodic region. At Tatneft enterprises, cathodic protection is carried out according to cluster and individual schemes. The main criterion for cathodic protection is the size of protective current. For a casing, the protective current is considered sufficient if measurements with a two-contact probe show that the electric current directed to the casing has eliminated all anode sites. To determine the value of required protective current, all methods are considered in this work. In addition, an analysis of all methods used to determine the minimum protective current of the casing is provided. Results show that the method of measuring potential drop along casing is one of the most reliable methods for determining the value of protective current.

An Analysis of the Protective Potential Distribution against Corrosion for Hull ICCP with Computer simulation (컴퓨터 Simulation을 통한 선체 음극방식(ICCP)의 방식전위분포해석)

  • Im, Gwan-Jin;Kim, Ki-Joon;Lee, Myung-Hoon;Moon, Kyung-Man
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.06a
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    • pp.395-400
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    • 2005
  • The ship hull part is always exposed to severe corrosive environments. Therefore, it should be protected in appropriate ways to reduce corrosion problems. So there are two effective methods in order to protect the corrosion of ship hull. One is the paint coating as a barrier between steel and electrolyte (seawater) and the other is the cathodic protection(CP) supplying protection current. In the conventional design process of the cathodic protection system the required current densities of protected materials have been used. However, the anode position of field or laboratory experiment for obtaining the required current density for CP is significantly different from anode position for real structures. Therefore, the recent CP design must consider the optimum anode position for potential distribution equally over the ship hull. The CP design companies in the advanced countries can obtain the potential distribution results on the cathodic materials by using the computer analysis module. This study would show how to approach the potential analysis in the field of corrosion engineering. The computer program can predict the under protection area on the structure when the boundary condition and analysis procedure are reasonable. In this analysis the polarization curve is converted to the boundary condition in material data.

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Corrosion Rate of Buried Pipeline by Induced Alternating Current (교류가 유도되는 매설배관에서의 교류 부식속도 측정에 관한 연구)

  • Song H. S.;Kim Y. G.;Lee S. M.;Kho Y. T.;Park Y. S.
    • 한국가스학회:학술대회논문집
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    • 2001.10a
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    • pp.45-57
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    • 2001
  • An alternating current (AC) corrosion using coupon has been studied. Coupons were applied in terms of AC voltage from high value to low value through the survey of AC voltages on buried gas transmission pipeline over the country. Parameters such as AC current density of coupon, AC voltage, cathodic protection potential, soil resistivity and frequency were monitored continually. Corrosion induced by AC was observed even under cathodically protected condition that met cathodic protection criterion(: below -850mv vs. CSE). Corrosion rate was affected mainly not by AC voltage but by both of frequency and AC current density. An experimental corrosion rate relationship could be obtained statistically, in which AC corrosion rate increased linearly with effective AC current density and its slope was 0.619.

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A Study on the Cathodic Protection Design Optimization of Steel Piles for LNG Storage Tanks by Numerical Analysis (수치해석에 의한 LNG 저장탱크용 강관파일 전기방식 설계 최적화 연구)

  • Kim, Young Keun;Song, Hong Seok
    • Corrosion Science and Technology
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    • v.16 no.6
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    • pp.294-297
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    • 2017
  • For the longer service life of steel pile, cathodic protection is selected sometimes at corrosive environment. The cathodic protection design improvement was investigated in this study. The current demand for cathodic protection was calculated from the potentiostatic current monitoring of the steel specimen in the deaerated soil samples. In this study, the current distribution was studied using the Boundary Element Method (BEM) and the Finite Element Method (FEM) numerical analysis methods. The optimum layout of the anode was developed and confirmed by numerical analysis. Under the conventional design of the anode, the length of the anode hole is same as the pile length. We found that, at the bottom end of the pile, the current density is too high. When the anode hole length was 80% of the pile length, the current consumption at the end was reduced. The construction cost of anode hole drilling was decreased about 20%, as compared to the conventional design. Furthermore, the life of the anode materials could be extended by reducing the current consumption at the end section. Using this approach, the construction cost was reduced significantly without any under-protection area on the steel piles.

Redox Reaction on Polarization Curve Variations of Polymer with Enzymes

  • Park, Chil-Nam
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.3
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    • pp.165-171
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    • 2000
  • Experiments were carried out to measure variations in the oxidation potential and current density using the polarization curves of polycarbonate. The results were then examined to identify the influences affecting the oxidation potential related to various conditions, such as temperature, pH, and oxydase(citrate and lipase). The lines representing the active anodic and cathodic dissolution shifted only slightly in the potential direction relative to temperature, pH, and the effect of the enzyme. The Tafel slope for the anodic and cathodic dissolution was determined such that the reversibility polarization was indicated as being effected by various conditions. The slope of the polarization curves describing the active-to-passive transition region shifted noticeably in their direction. Also, by varying the conditions, the optimum conditions for the most ready transform were identified, including temperature, pH, oxidation rate, and resistance of oxidation potential. The critical oxidation sensitivity(I(sub)r/I(sub)f) of the anodic current density peak and maximum passive current density was also determined, which is used in measuring the critical corrosion sensitivity of a polycarbonate.

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Regional Cathodic Protection Design of a Natural Gas Distribution Station

  • Yabo, Hu;Feng, Zhang;Jun, Zhao
    • Corrosion Science and Technology
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    • v.16 no.5
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    • pp.235-240
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    • 2017
  • Regional cathodic protection has significant impact on pipeline integrity management. After risk analyses of a newly built gas distribution station constructed in an area with large dwelling density, risk score was high because of potential threat caused by galvanic corrosion. Except reinforced steel in concrete, there are four kinds of metal buried under earth: carbon steel, galvanized flat steel, zinc rod and graphite module. To protect buried pipeline from external corrosion, design and construction of regional cathodic protection was proposed. Current density was measured with potential using potential dynamic test and boundary element method (BEM) was used to calculate current requirement and optimize best anode placement during design. From our calculation on the potential, optimized conditions for this area were that an applied current was 3A and anode was placed at 40 meters deep from the soil surface. It results in potential range between $-1.128V_{CSE}$ and $-0.863V_{CSE}$, meeting the $-0.85V_{CSE}$ criterion and the $-1.2V_{CSE}$ criterion that no potential was more negative than $-1.2V_{CSE}$ to cause hydrogen evolution at defects in coating of the pipeline.

A Study of Optimizing Cathodic Protection in Comparison of Design Methodologies

  • Choi, Young-Kwan;Choi, Sang-Yule;Shin, Myong-Chul
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.11
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    • pp.23-29
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    • 2010
  • The principal factor determining an optimum design method for cathodic protection is finding the protection current for preventing the corrosion of existing, already laid pipe. Some factors currently used to test designs include the sizes and lengths of pipes, soil resistivity, and the coating damage rate. We believe this method and current formulae are not optimum due to the uncertainty of determining the coating damage rate and the corrosion protection current's density. This paper analyzes the amount of protection current obtained by performing a temporary current test using data describing existing laid pipe. We then propose determining the corrosion protection current by using the temporary current test after modifying the formula. In addition, we suggest a way to choose optimized cathodic protection and the process of design by executing the design and taking account of such factors as a site condition of 34km-long non-protected water supply pipe lines (stages I and II) in ${\bigcirc}{\bigcirc}$ region, climate, interferences, and durability.

The effect of cathodic protection system by means of zinc sacrificial anode on pier in Korea

  • Jeong, Jin-A;Jin, Chung-Kuk
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.10
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    • pp.1206-1211
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    • 2014
  • This study has been conducted to confirm the effect of sacrificial anode cathodic protection system for 90 days to protect corrosion on pier that is located in Korea. The cathodically protected structure was a slab and a pile cap. Before the construction of cathodic protection system, the macrography was carried out. As a result of the macrography, many corrosion traces were confirmed in this structure. The trace was mainly focused on joint and zones that concrete cover was eliminated. To apply the cathodic protection system, many onsite techniques have been adopted. In addition, to confirm the inner state of steel in concrete properly, a corrosion monitoring sensor (DMS-100, Conclinic Co. Ltd) has been applied. Test factors were corrosion & cathodic protection potential, 4 hour depolarization potential, resistivity and current density. After 90 days from the installation of cathodic protection system, it could confirm that proper corrosion protection effect was obtained by considering the result of tests.

Fundamental Study on Cathodic Protection and Material Development as Erosion-Control Methods of Oceanic Centrifugal Pump(1) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구 1)

  • 이진열;임우조
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.2
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    • pp.56-66
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    • 1995
  • Recently, with theraped advancement in th oceanology such an ocean-going vessel and oceanic structures, there is a need to study the cavitation erosion-corrosion control of pump impeller, the partial element of ocean machinery, for more effective operation. Especially, the cathodic protection (impressed current method & Al-sacrificial anode method) was applied to sea water, and Cu-alloy material mixed Zn & Al was used as a control method of cavitation erosion-corrosion. In this study, used the piezoelectric vibrator with 20KHz, 24.mu.m to cavity generation apparatus, and investigated the weight loss, weight loss rate, electrode potential & current density etc. under this condition. According to test result, thos describes how to indentify an influence of the cathodic protection and Al & Zn addition in material development for the control of cavitation erosion-corrosion, and those will serve as fundamental data on the cavitation erosion-corrosion control of oceanic centrifugal pump.

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