• 한국군사과학기술학회지
• /
• 제11권2호
• /
• pp.43-52
• /
• 2008

The galvanic corrosion of a vessel, or systems fitted to minimize the ship's corrosion such as ICCP (Impressed Current Cathodic Protection) system and sacrificial anodes, can lead to significant electrical current flow in the sea. The presence of vessel's current sources associated with corrosion will give rise to detectable electric field surrounding the vessel and can put it at risk from mine threats. For this reason, it is necessary to design corrosion protection systems so that they don't only prevent a hull corrosion but also minimize the electric field signature. In this paper, we describe theoretical backgrounds of underwater electric field signature due to corrosion and corrosion protection system on naval vessels and analysis results of the electric field according to the ship's hull and it's propeller coating damage and ICCP anode displacement.

• 한국표면공학회지
• /
• 제42권5호
• /
• pp.203-207
• /
• 2009

Interaction between human osteoblast (hFOB 1.19) and CrN films was conducted in vitro. CrN films were produced by cathodic arc plasma deposition. The surface was characterized by atomic force microscopy (AFM). CrN films, glass substrates and TiN films were cultured with human osteoblasts for 48 and 72 hours. Actin stress fiber patterns and cell adhesion of osteoblasts were found less organized and weak on CrN films compared to those on the glass substrates and the TiN films. Human osteoblasts also showed less proliferation and less distributed microtubule on CrN films compared to those on glass substrates and TiN films. Focal contact adhesion was not observed in the cells cultured on CrN films, whereas focal contact adhesion was observed well in the cells cultured on glass substrates and TiN films. As a result, the CrN film is a potential candidate as a surface coating to be used for implantable devices which requires minimal cellular adhesion.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
• /
• pp.125-125
• /
• 2012

물리증착(physical vapor deposition; PVD)은 진공 또는 특정 가스 분위기에서 고상의 물질을 기화시켜 기판에 피막을 형성하는 방법으로 증발과 스퍼터링 그리고 이온플레이팅 등이 있다. PVD 방법으로 박막을 제작하면 대부분의 박막은 주상정 구조로 성장하게 된다. 이러한 주상정의 조직을 제어하는 방법으로 빗각 증착(oblique angle deposition; OAD) 기술이 있다. OAD는 타겟(증발원)에 대해서 기판을 평행하게 배치하는 일반적인 코팅방법과는 달리 기판의 수직성분과 타겟의 수직성분이 이루는 각도가 0도 이상이 되도록 조절하여 기판을 기울인 상태로 코팅하는 방법을 말한다. OAD 방법을 이용하면 기판으로 입사하는 증기가 초기에 생성된 핵(seed)에 의해 shadowing이 발생하면서 증기가 수직으로 입사하는 normal 증착과는 다른 형상의 성장 조직이 만들어지게 된다. 본 논문에서는 OAD 방법을 이용하여 Al과 TiN 박막을 제조하고 그 특성을 비교하였다. Al 박막은 UBM (Un-Balanced Magnetron) 스퍼터링 소스를 이용하여 빗각을 각각 0, 30, 45, 60 및 90도의 각도에서 강판 및 실리콘 웨이퍼 상에 시편을 제조하되 단층 및 다층으로 시편을 제조하고 치밀도와 함께 조도와 반사율을 비교하고 염수분무시험을 이용하여 내식성을 평가하였다. TiN 박막은 Cathodic Arc 방식을 이용하되 Al 박막과 동일한 방법으로 코팅을 하고 내식성 및 경도 등의 특성을 비교하였다. TiN 박막은 경사각이 커지면서 경도가 낮아졌으나 바이어스 전압을 이용하여 다층으로 제조함에 의해 경도는 유지하면서 modulus를 낮출 수 있어서 박막의 신뢰성을 나타내는 H3/E2 값은 증가함을 알 수 있었다.

• Corrosion Science and Technology
• /
• 제10권3호
• /
• pp.101-107
• /
• 2011

Marine ships have played an important role as a carrier, transporting much more than 80% of all international trading, and marine transportation is an internationally competitive, strategic, and great national important industry. However, those marine ships have the characteristics such as voyage of long distance, large-volume and lower speed than the other carry system. Therefore, it is important to manufacture a larger and faster ship, however, the steel plates which are consisted with most of those ships has brought about many corrosion problems in sea water such as general corrosion, localized corrosion, cavitation and erosion corrosion etc.. Most hulls of the ships have been protected with paintings, sacrificial anode, marine growth prevention system, and impressed current cathodic protection methods against numerious corrosion problems mentioned above. However, these conventional methods are not very effective because the rudder of ships stern are exposed to very severe corrosive environment such as tides, speeds of ships, cavitations and erosion corrosion, etc.. In this study, electrochemical and cavitation characteristics was investigated for the rudder material of ship which is exposed to serious corrosive environment. As a result, it is considered that the optimum cathodic protection potentials of rudder material is the range of -0.6 V ~ -0.8 V(Ag/AgCl) in static seawater.

• 한국결정성장학회지
• /
• 제9권6호
• /
• pp.590-596
• /
• 1999

염화물욕 아연도금에서 순환셀 도금장치에 3전극계를 부착하여 첨가제 효과를 조사하였다. 도금액에 폴리에틸렌글리콜(이하 PEG)의 첨가는 도금 과전압을 증가시키고 수소발생을 억제하는데 이것은 첨가제에 의하여 아연 이온의 이동을 억제하거나 음극에 첨가제 흡착에 의한 것으로 생각된다. 그러나 PEG는 사용되는 도금액의 물성(전도도, 점도, 비중)에는 영향을 미치지 않는 것으로 나타났다. 도금층에 미치는 영향은 표면 조도가 개선되고, 광택도가 감소된다. 이러한 영향은 PEG 분자수가 클수록 증가되나 분자수가 다른 PEG의 혼합첨가제에서는 광택도 감소가 줄어든다. 이러한 것은 도금층 결정면의 방향성, 입자의 크기 및 형태가 PEG 분자 수에 따라 다르게 나타나는 것에 기인하는 것으로 판단된다.

• Corrosion Science and Technology
• /
• 제17권2호
• /
• pp.54-59
• /
• 2018

The effect of external DC electric field on atmospheric corrosion behavior of zinc under a thin electrolyte layer (TEL) was investigated by measuring open circuit potential (OCP), cathodic polarization curve, and electrochemical impedance spectroscopy (EIS). Results of OCP vs. time curves indicated that the application of external DC electric field resulted in a negative shift of OCP of zinc. Results of cathodic polarization curves measurement and EIS measurement showed that the reduction current of oxygen increased while charge transfer resistance ($R_{ct}$) decreased under the external DC electric field. Variation of OCP negative shift, reduction current of oxygen, and $R_{ct}$ increase with increasing of external DC electric field strength as well as the effect of external DC electric field on double-layer structure in the electrode/electrolyte interface and ions distribution in thin electrolyte layer were analyzed. All results showed that the external DC electric field could accelerate the corrosion of zinc under a thin electrolyte layer.

• 공업화학
• /
• 제4권4호
• /
• pp.692-700
• /
• 1993

카본 담체에 백금과 전이금속과의 합금 촉매를 제조하여 촉매의 부식성, 촉매능 및 단전지에서의 전극성능을 전기화학적으로 비교 검토하였다. 그리고 합금촉매의 분석은 XRD로 확인하였다. 본 연구에서 제조된 여러 가지 백금 합금 촉매 중 Pt-Mo/carbon, Pt-Fe-Co/carbon 및 Pt-Fe/carbon 촉매가 보다 우수한 산소 환원 전류밀도를 나타내었으나 Pt-Mo/carbon 촉매의 경우 초기 전극전류의 대부분이 촉매의 부식에 의한 전류임을 확인할 수 있었다. Pt/carbon촉매를 사용하였을 경우 나타난 전극의 전류밀도는 $120mA/cm^2$이었으나 Pt-Fe-Co/carbon 의 경우는 $200mA/cm^2$으로 순수 백금촉매보다 우수한 전극성능을 나타내었다.

• Journal of Advanced Marine Engineering and Technology
• /
• 제29권5호
• /
• pp.519-525
• /
• 2005

An electrochemical evaluation on the corrosion resistance for heavy anticorrosive paint(DFT:25um) was carried out for 5 kinds of heavy anticorrosive paints such as high solid epoxy(HE), solvent free epoxy(SE). tar epoxy(TE), phenol epoxy(PE). and ceramic epoxy(CE). Corrosion current densities obtained by Tafel extrapolation method from anodic and cathodic polarization curves didn't correspond with the values obtained by AC impedance measurement, however, the values of polarization resistance obtained from the cyclic voltammogram showed a good tendency corresponding well with the values of AC impedance measurement. Futhermore there was a good correlation against the corrosion resistance evaluation between passivity current density of the anodic polarization curve and diffusion limiting current density of the cathodic polarization curve. And corrosion resistance increased with corrosion potential shifting to noble direction. From the results discussed above. HE and CE had a relatively good corrosion resistance than other heavy anticorrosive paints.

• 한국원자력학회:학술대회논문집
• /
• 한국원자력학회 2004년도 추계학술발표회 발표논문집
• /
• pp.911-912
• /
• 2004

1. Cathodic hydrogen charging considerably reduced the tensile ductility of ODS steels and a 9Cr-2W RMS. The hydrogen embrittlement of ODS steels was strongly affected by specimen sampling orientation, showing significant embrittlement in the T-direction. This comes from the microstructural anisotropy caused by elongated grains of ODS steels in L-direction. 2. The ODS steels contained a higher concentration of hydrogen than 9Cr-2W RMS at the same cathodic charging condition, and the critical hydrogen concentration required to transition from ductile to brittle fracture was in the range of $10{\sim}12$ wppm, which approximately 10 times larger than that of a 9Cr-2W martensitic steel. 3. The ODS steels showed a typical ductile to brittle transition behavior and it strongly depended on the specimen sampling direction, namely L- and T-direction. In T-direction, the SP-DBTT was about 170 L, irrespective of the ODS materials, and L-direction showed a lower SP-DBTT than that of T-direction.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
• /
• pp.128-128
• /
• 2003

Electrochromism (EC) is defined as a phenomenon in which a change in color takes place in the presence of an applied voltage. Because of their low power consumption, high coloration efficiency, EC devices have a variety of potential applications in smart windows, mirror, and optical switching devices. An EC devices generally consist of a transparent conducting layer, electrochromic cathodic and anodic coloring materials and an ion conducting electrolyte. EC has been widely studied in transition metal oxides(e.g., WO$_3$, NiO, V$_2$O$\sub$5/) Among these materials, WO$_3$ is a most interesting material for cathodic coloration materials due to its lush coloration efficiency (CE), large dynamic range, cyclic reversibility, and low cost material. WO$_3$ films have been prepared by a variety of methods including vacuum evaporation, chemical vapor deposition, electrodeposition process, sol-gel synthesis, sputtering, and laser ablation. Sol-gel process is widely used for oxide film at low temperature in atmosphere and requires lower capital investment to deposit large area coating compared to vacuum deposition process.