• 제목/요약/키워드: Cathodes

검색결과 269건 처리시간 0.023초

The triple layer anode for flexible top emission organic lightemitting devices

  • Chung, Sung-Mook;Hwang, Chi-Sun;Lee, Jeong-Ik;KoPark, Sang-Hee;Yang, Yong-Suk;Do, Lee-Mi;Chu, Hye-Yong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.698-701
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    • 2007
  • A top emission organic light emitting diode comprising of a triple anode on polycarbonate $film/TNATA/NPB/Alq_3:C545T/cathodes$ has been fabricated. The triple layer structure of Cr/Al/Cr allowed for fabrication of a crack-free anode and provided better higher work function than ITO anode.The anode showed compatibility with flexible plastic substrate and no crack was formed during bending test while ITO anode showed crack.

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은 담지한 흑연을 부극 활물질로 이용한 Lithium ion 2차전지의 충방전 특성 (Charge/Discharge Characteristics of Lithium ion Secondary Battery Using Ag-deposited Graphite as Anode Active Material)

  • 김상필;조정수;박정후;윤문수
    • 한국전기전자재료학회논문지
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    • 제11권9호
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    • pp.727-732
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    • 1998
  • Ag-deposited graphite powder was prepared by a chemical reduction method of metal particles onto graphite powder. X-ray diffraction observation of Ag-deposited graphite powder revealed that silver existed in a metallic state, but not in an oxidized one. From SEM measurement, ultrafine silver particles were highly dispersed on the surface of graphite particles. Cylindrical lithium ion secondary battery was manufactured using Ag-deposited graphite anodes and $LiCoO_2$ cathodes. The cycleability of lithium ion secondary battery using Ag-deposited graphite anodes was superior to that of original graphite powder. The improved cycleability may be due to both the reduction of electric resistance between electrodes and the highly durable Ag-graphite anode.

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마그네트론 2원 동시 방전법을 이용하여 증착한 ISZO 및 IZSO 박막의 특성에 관한 연구 (Characteristics of ISZO and IZSO films deposited using magnetron co-sputtering system by two cathodes)

  • 이동엽;이정락;이건환;송풍근
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2007년도 추계학술대회 논문집
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    • pp.91-92
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    • 2007
  • In-Sn-Zn-O (ISZO)박막과 In-Zn-Sn-O (IZSO)박막은 상온에서 2개의 캐소드 (DC, RF)를 이용하여 마그네트론 2원 동시 방전법에 의해 polyethylene terephthalate (PET)기판 위에 실온에서 증착되었다. ISZO 박막의 경우, Zn함량이 증가함에 따라 비저항은 증가하였지만, Zn원자의 도입에 의해 표면 조도는 개선되었다. 반면, IZSO 박막의 경우, 최저비저항 ($3.17$ ${\times}$ $10^{-4}$ ${\Omega}cm$)은 $SnO_2$ 타켓의 RF power 40W에서 얻어졌지만, Sn원자의 도입에 의해 표면 조도는 거칠어졌다. XRD 측정 결과 모든 박막은 비정질 구조로 사료되고, 가시광선 영역에서 80% 이상의 높은 투과율을 보였다.

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DC 스퍼터링 증착에 의한 AI 전극을 갖는 전계발광소자 제작 (Fabrication of the Electroluminescence Devices with Al electrode deposited by DC sputtering)

  • 윤석범
    • 한국전기전자재료학회논문지
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    • 제13권5호
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    • pp.376-382
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    • 2000
  • We successfully fabricated OLED(Organic Light Emitting Diodes) with Al cathodes electrode deposited by the DC magnetron sputtering. The effects of a controlled Al cathode layer of an Indium Tin Oxide (ITO)/blended single polymer layer (PVK Bu:PBD:dye)/Al light emitting diodes are described. The PVK (Poly(N-vinylcarbazole)) and Bu-PBD (2-(4-biphenyl-phenyl)-1,3,4-oxadiazole) are used hole transport polymer and electron transport molecule respectively. We found that both current injection and electroluminescence output are significantly different with a variable DC sputtering power. The difference is believed to be due to the influence near the blended polymer layer/cathode interface that results from the DC power and H$\sub$2//O in a chamber. And DC sputtering deposition is an effective way to fabricate Al electrodes with pronounced orientational characteristics without damage occurring to metal-organic interface during the sputtering deposition.

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Top Emission OLED를 위한 금속을 이용한 투명전극 형성 (Formation of Transparent Metal Electrode for Top Emission OLEDs)

  • 김소연;하미영;문대규;이찬재;한정인
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.457-458
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    • 2006
  • Transparent metal cathodes using Ca/Ag, Ba/Ag double layers have been fabricated to investigate its optical transmission. The transmission spectra show that Ca/Ag and Ba/Ag double layers result in higher transmittance compared to Ag single layer. The Ba/Ag double layer shows over 80% transmittance at 400 nm and 70% at 700 nm. The electroluminescence efficiency of fluorescent TEOLED using Ba/Ag transparent metal cathode was 10 ~ 15 cd/A.

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Hydrogen Production by Photoelectrochemical Water Splitting

  • Seo, H.W.;Kim, J. S.
    • Applied Science and Convergence Technology
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    • 제27권4호
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    • pp.61-64
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    • 2018
  • The basic principle and concept for hydrogen production via water-splitting process are introduced. In particular, recent research activities and their progress in the photoelectrochemical water-splitting process are investigated. The material perspectives of semiconducting photocatalysts are considered from metal oxides, including titanium oxides, to carbon compounds and perovskites. Various structural configurations, from conventional photoanodes with metal cathodes to tandem and nanostructures, are also studied. The pros and cons of each are described in terms of light absorption, charge separation/photoexcited electron-hole pair recombinations and further solar-to-hydrogen efficiency. In this research, we attempt to provide a broad view of up-to-date research and development as well as, possibly, future directions in the photoelectrochemical water-splitting field.

Enhanced salt coating on FeS2 surface with the addition of Li2O

  • Cheong, Hae-Won;Kang, Seung-Ho;Kim, Jong-Myong;Cho, Sung-Baek
    • Journal of Ceramic Processing Research
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    • 제13권spc2호
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    • pp.198-201
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    • 2012
  • The electrolytes in thermal batteries are nonconductive solids at ambient temperature, which prevent the self-discharge and corrosion. To meet severe environmental requirements and guarantee acceptable handling yields, all the pellets in cells should have adequate strength, especially for the cathodes due to their poor binding properties among FeS2 particles. By modifying the surface microstructure of FeS2 through molten-salt heat treatment, the inter-particle binding strength is greatly increased, resulting in the enhanced pellet strength and yield. The addition of Li2O also promoted the soft salt coating coverage of hard FeS2 particles, which can be explained by the enhanced wettability of the molten salt.

고전압 LiNi0.5Mn1.5O4 양극 고성능 바인더 개발 연구 (Development of Advanced Polymeric Binders for High Voltage LiNi0.5Mn1.5O4 cathodes in Lithium-ion batteries)

  • 윤대희;최성훈
    • 산업기술연구
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    • 제43권1호
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    • pp.43-48
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    • 2023
  • Spinel LiNi0.5Mn1.5O4 (LNMO) has been considered as one of most promising cathode material, because of its low-cost and competitive energy density. However, 4.7V vs. Li/Li+ of high operating potential facilitates electrolyte degradation on cathode-electrolyte interface during charge-discharge process. In particular, commercial polyvinylidene fluoride (PVDF) is not sutaible for LNMO cathode binder because its weak van der waals force induces thick and non-uniform coverage on the cathode surface. In this review, we study high performance binders for LNMO cathode, which forms uniform coating layer to prevent direct contact between electrolyte and LNMO particle as well as modifying high quality cathode electrolyte interphase, improved cell performace.

Temperature-Dependent Mn Substitution Effect on LiNiO2

  • Seungjae Jeon;Sk. Khaja Hussain;Jin Ho Bang
    • Journal of Electrochemical Science and Technology
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    • 제15권1호
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    • pp.161-167
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    • 2024
  • Despite the important role of manganese (Mn) in cobalt-free, Ni-rich cathode materials, existing reports on the effects of Mn as a substitute for cobalt are not consistent. In this work, we analyzed the performance of cathodes comprised of Li(Ni1-xMnx)O2 (LNMO). Both beneficial and detrimental results occurred as a result of the Mn substitution. We found that a complex interplay of effects (Li/Ni mixing driven by magnetic frustration, grain growth suppression, and retarded lithium insertion/extraction kinetics) influenced the performance and was intimately related to calcination temperature. This indicates the importance of establishing an optimal reaction temperature for the development of high-performance LNMO.

Applications and Challenges of Lithium-Sulfur Electrochemical Batteries

  • Mohammed Jasim M. Al Essa
    • Journal of Electrochemical Science and Technology
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    • 제15권1호
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    • pp.1-13
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    • 2024
  • This paper presents applications of lithium-sulfur (Li-S) energy storage batteries, while showing merits and demerits of several techniques to mitigate their electrochemical challenges. Unmanned aerial vehicles, electric cars, and grid-scale energy storage systems represent main applications of Li-S batteries due to their low cost, high specific capacity, and light weight. However, polysulfide shuttle effects, low conductivities, and low coulombic efficiencies signify key challenges of Li-S batteries, causing high volumetric changes, dendritic growths, and limited cycling performances. Solid-state electrolytes, interfacial interlayers, and electrocatalysts denote promising methods to mitigate such challenges. Moreover, nanomaterials have capability to improve kinetic reactions of Li-S batteries based on several properties of nanoparticles to immobilize sulfur in cathodes, stabilizing lithium in anodes while controlling volumetric growths. Li-S energy storage technologies are able to satisfy requirements of future markets for advanced rechargeable batteries with high-power densities and low costs, considering environmentally friendly systems based on renewable energy sources.