• 제목/요약/키워드: Cathode ratio

검색결과 281건 처리시간 0.028초

고온 고분자 막 전해질 연료전지 캐소드의 가스 확산층 및 바인더 함량에 따른 완화 시간 분포(DRT) 저항 분석 (Resistance Analysis by Distribution of Relaxation Time According to Gas Diffusion Layers and Binder Amounts for Cathode of High-temperature Polymer Electrolyte Membrane Fuel Cell)

  • 김동희;정현승;박찬호
    • 한국수소및신에너지학회논문집
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    • 제34권3호
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    • pp.283-291
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    • 2023
  • The physical properties were analyzed for four gas diffusion layers, and gas diffusion electrodes (GDEs) for the cathode of high-temperature polymer electrolyte membrane fuel cell were fabricated through bar coating with three binder to carbon (B/C) ratios. Among them, The GDE from JNT30-A6P showed a significant change in secondary pore volume at a B/C ratio of 0.31, which had the largest pore volume among all GDEs. In the polarization curve, JNT30-A6P GDE showed the best membrane electrode assembly (MEA) performance with a peak power density of 384 mW/cm2 at a a B/C ratio of 0.31. From the distribution of relaxation time analysis, the peak 1 corresponding to mass transfer resistance of oxygen reduction reaction (ORR) was significantly reduced in the JNT30-A6P GDE. This is the result that when the binder content decreased, the volume of the secondary pore increased, and the mass transfer resistance of ORR decreased, which played an essential role in the MEA performance.

탄뎀 가스메탈아크 용접의 토치 극간거리에 관한 실험적 연구 (A Experiment Study of Torch Distance on Automated Tandem GMA Welding System)

  • 이지혜;김일수;정성명;이종표;김영수;박민호
    • Journal of Welding and Joining
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    • 제30권6호
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    • pp.49-55
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    • 2012
  • The tandem welding process is one of the most efficient welding processes widely used in material joining technique such as manufacturing of strong and durable structures. It facilitates high rate of joint filling with little increase in the overall rate of heat input due to the simultaneous deposition from two electrode wires. The two electrodes in tandem welding process helps in high-efficiency and high productive of welding process. In this study a automated tandem welding system is developed to determine the correlation between cathode and anode and compared with current ratio of the two electrode torch. Three different inter-electrode distances were chosen, 25mm, 35mm and 45mm to perform the experiment with three different current ratio. From the experiment results, the current ratio between two torch has a large impact on width, height and depth of penetration. In addition, a stable bead geometry is obtained when inter-electrode distance is 35mm.

EFFECT OF LOAD AND ANODE/CATHODE AREA RATIO ON WEAR OF Zr-ALLOY IN $Na_2SO_4$ SOLUTION

  • Iwabuchi, A.;Hosoya, K;Abe, K.;Shimizu, T.;Kim, S.S.
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.205-206
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    • 2002
  • In this paper we examined the contribution of mechanical and electrochemical factors in corrosive wear for Zr-alloy against $Al_2O_3$ ball in $Na_2SO_4$ solution. Normal load and the area of metallic specimen was varied to change the corrosion behavior. At the commence of sliding, the potential drop took place, which increased with load due to the great exposure of fresh surface. Wear volume was linearly proportional to load. The corrosion factor was about 15%. By increasing the Aa/Ac ratio, corrosion factor to total wear decreases and saturates above Aa/Ac=0.15.

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HTL:EML(DPVBi:NPB) 층의 조성비 변화에 따른 청색 유기 발광 소자 개발 (Development of Blue Organic Light-Emitting Diodes(OLEDs) Due to Change in Mixed Ratio of HTL:EML(DPVBi:NPB) Layers)

  • 이태성;이병욱;홍진수;김창교
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 춘계학술대회 및 기술 세미나 논문집 디스플레이 광소자
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    • pp.31-32
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    • 2008
  • The structure of OLEDs with conventional heterostructure consists of anode, hole injection layer, hole transport layer, light-emitting layer, electron transport layer, electron injection layer, and cathode. NPB used as a hole transport layer and DPVBi used as a blue light emitting layer were graded-mixed at selected ratio. Interface at heterojunction between the hole transport layer and the elecrtron transport layer restricts device's stability. Mixing of the hole transport layerand the emitting layer removes abrupt interface between the hole transport. layer and the electron transport layer. The stability of OLED with graded mixed-layer developed in this study was improved.

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PEM 연료전지시스템의 동특성 해석 (Dynamic Analysis of PEM fuel cell system)

  • 김범수;전순일;임원식;박영일
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2005년도 춘계학술대회
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    • pp.353-356
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    • 2005
  • We developed a dynamic model of PEM fuel cell system which can analyze its transient response to dynamic load current. System components such as compressor, air cooler, humidifier, and stack were modeled based on their dynamic equations and performance maps by using Matlab Simulink platform. Through this simulation model, dynamic characteristics of fuel cell system including oxygen excess rat io, stack voltage, and system efficiency were shown. In addition to that, we briefly analyzed the humidity effect on cathode pressure and system efficiency, expecting that this model can be further used to optimize fuel cell system parameters just like operating pressure and temperature, humidity and oxygen excess ratio.

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Plasma Characterization of Facing Target Sputter System for Carbon Nitride Film Deposition

  • Lee, Ji-Gong;Lee, Sung-Pil
    • Transactions on Electrical and Electronic Materials
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    • 제5권3호
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    • pp.98-103
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    • 2004
  • The plasma properties in the facing target sputtering system during carbon nitride film deposition have been investigated. The ionized nitrogen species of the deposited films increased with increasing discharge current and were independent of the nitrogen pressure. The nitrogen content in the films did not vary significantly with the variation of nitrogen gas. The electron temperature was high close to that in the inter-cathode region, reduced as the electrons moved away from the most intense region of magnetic confinement and increased again outside this region. Calculations based on the film composition showed that the ion to carbon atom ratio at the substrate was about 50 and that the ratio between the ionized and neutral nitrogen molecules was about 0.25.

전해조건에 따른 아연-크롬합금 도금층의 조성 및 조직특성 (Composition and Microstructure of Electroplated Zinc-Chromium Alloy according to Electrolysis Conditions)

  • 안덕수;김대영;예길촌
    • 한국표면공학회지
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    • 제35권4호
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    • pp.232-240
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    • 2002
  • The composition and the microstructure of the Zn-Cr alloys electroplated in chloride bath with EDTA were studied according to electrolysis conditions. The cathode current efficiency decreased with increasing both Cr/(Cr+Zn) ratio and current density. The Cr content of the alloy deposits increased with Cr/(Cr+Zn) ratio and current density The phase structure of Zn-Cr alloy deposits changed from η-Zn through η-Zn+${\gamma}$'-ZnCr to ${\gamma}$'-ZnCr with increasing Cr content of alloys. The surface morphology of Zn-Cr alloy deposits changed from fine needle shaped crystallites through the mixed structure of needle-shaped and granular one to the colony structure with fine granular crystallites according to the change of phase structure

CNT-BLU Local Dimming 구동을 이용한 LCD Contrast 향상 방법 (LCD contrast ratio enhancement method using Carbon Nanotube Back Light Unit and Local Dimming)

  • 민경원;정득석;송병권;김선일;강호석;백찬욱;정태원;김정우;진용완;조준동
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2006년도 하계종합학술대회
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    • pp.971-972
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    • 2006
  • We have demonstrated Carbon Nanotube Back Light Unit (CNT-BLU) which has a triode structure. Local dimming scheme was introduced to the BLU driving system. With this driving method, contrast ratio enhanced 20 times higher than that of conventional Cold Cathode Fluorescent Lamp (CCFL) BLU.

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LSM과 YSZ의 분말크기 및 분말크기비가 SOFC의 양극특성에 미치는 영향 (The Effect of particle size and ratio of LSM-YSZ powders on SOFC cathod properties)

  • 김재동;김구대;박지애
    • 한국세라믹학회지
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    • 제37권3호
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    • pp.227-232
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    • 2000
  • The LSM-YSZ composite electrode as a mixture of LSM and YSZ shows percolation characteristics. It was identified that the polarization resistance of LSM-YSZ composite electrode depend on YSZ connectivity by changing powder size ratio of the DLSM/DYSZ. That is, YSZ in composite electrode showed low electrochemical activity without YSZ connectivity. However, the polarization resistance decreased abruptly with YSZ connectivity due to high electrochemical activity of YSZ in composite electrode. Because the amount of three phase boundary is dependent on LSM and YSZ particle size, the polarization resistance of cathode decreases as LSM and YSZ particle size decreases.

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가스터빈-가압형 SOFC 하이브리드 시스템의 성능특성 해석 (Performance Characteristics Analysis of Gas Turbine-Pressurized SOFC Hybrid Systems)

  • 양원준;김동섭;김재환
    • 설비공학논문집
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    • 제16권7호
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    • pp.615-622
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    • 2004
  • Recently, the hybrid system combining fuel cell and gas turbine has drawn much attention owing to its high efficiency and ultra low emission. It is now on the verge of world wide development and various system configurations have been proposed. A national project funded by Korean government has also been initiated to develop a pressurized hybrid system. This work aims at presenting design performance analysis for various possible system configurations as an initial step for the system development. Study focuses are given to major design options including the power ratio between gas turbine and fuel cell, reforming method (internal or external), reforming heat source (reforming burner, cathode hot air, fuel cell heat release) and steam supply method for reformer (anode gas recirculation, external steam generator). A wide variation in performance among different configurations has been predicted.