• Title/Summary/Keyword: Cathode Power

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Diamond-Like Carbon Films Deposited by Pulsed Magnetron Sputtering System with Rotating Cathode

  • Chun, Hui-Gon;You, Yong-Zoo;Nikolay S. Sochugov;Sergey V. Rabotkin
    • Journal of the Korean institute of surface engineering
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    • v.36 no.4
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    • pp.296-300
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    • 2003
  • Extended cylindrical magnetron sputtering system with rotating 600-mm long and 90-mm diameter graphite cathode and pulsed power supply voltage generator were developed and fabricated. Time-dependent Langmuir probe characteristics as well as carbon films thickness were measured. It was shown that ratio of ions flux to carbon atoms flux for pulsed magnetron discharge mode was equal to $\Phi_{i}$ $\Phi$sub C/ = 0.2. It did not depend on the discharge current in the range of $I_{d}$ / = 10∼60 A since both the plasma density and the film deposition rate were found approximately proportional to the discharge current. In spite of this fact carbon film structure was found to be strongly dependent on the discharge current. Grain size increased from 100 nm at $I_{d}$ = 10∼20 A to 500 nm at $I_{d}$ = 40∼60 A. To deposit fine-grained hard nanocrystalline or amorphous carbon coating current regime with $I_{d}$ = 20 A was chosen. Pulsed negative bias voltage ($\tau$= 40 ${\mu}\textrm{s}$, $U_{b}$ = 0∼10 ㎸) synchronized with magnetron discharge pulses was applied to a substrate and voltage of $U_{b}$ = 3.4 ㎸ was shown to be optimum for a hard carbon film deposition. Lower voltages were not sufficient for amorphization of a growing graphite film, while higher voltages led to excessive ion bombardment and effects of recrystalization and graphitization.

Technology of selective absorber coatings on solar collectors using black chromium+3 sulfate acid on substrates (흑색 황산3가크롬을 이용한 태양열 흡열판 선택흡수막 도금기술)

  • Ohm, Tae-In;Yeo, Woon-Tack;Kim, Dong-Chan
    • Journal of the Korean Solar Energy Society
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    • v.33 no.3
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    • pp.27-35
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    • 2013
  • One of the most important factors that have a large influence on performance of the solar water heater system is performance of the solar collector, more detailedly, coating technology on the surface of the solar collector, which can provide high solar absorptance and low emittance. The core of the coating technology is to coat solar selective surfaces. In this study, various performance experiments are carried out using $Cr_2(SO_4)_3{\cdot}15H_2O$ coating technology. Here, IGBT(Insulated Gate Bipolar Transistor) of 5000A-15V was used as the surface processing rectifier which can stably output power and also can control voltage and current. The plating solution mainly contains black chrome$^{+3}$ concentration, H-y Conductivity, N-u Complex, NF Additive and NC-2 Wetter. Before applying the black chrome coating on the copper plate, optimal conditions are provided by using various preprocessing methods such as removal of fat, activation, electrolytic polishing, nickel strike, copper sulfate plating and bright neckel plating, and then the automatic continuous coating experiment are performed according to plating time and cathode current density. In the experiment, after the removal of fat, chemical polishing, nickel strike and activation processes as the preprocessing methods, the black chrome coating was performed in a plate solution temperature of $28^{\circ}C$ and a cathode current density of $18A/cm^2$ for 90 seconds. The thickness of chrome and nickel on the coated plate is $0.389{\mu}m$, $159{\mu}m$ respectively. As a result of the coating experiment, it showed the most excellent performance having a high solar absorptance of 98% and a low emittance of $5{\pm}1%$ when the black chrome surface had a thickness of $0.398{\mu}m$.

Resistance Analysis by Distribution of Relaxation Time According to Gas Diffusion Layers and Binder Amounts for Cathode of High-temperature Polymer Electrolyte Membrane Fuel Cell (고온 고분자 막 전해질 연료전지 캐소드의 가스 확산층 및 바인더 함량에 따른 완화 시간 분포(DRT) 저항 분석)

  • DONG HEE KIM;HYOEN SEUNG JUNG;CHANHO PAK
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.3
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    • pp.283-291
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    • 2023
  • The physical properties were analyzed for four gas diffusion layers, and gas diffusion electrodes (GDEs) for the cathode of high-temperature polymer electrolyte membrane fuel cell were fabricated through bar coating with three binder to carbon (B/C) ratios. Among them, The GDE from JNT30-A6P showed a significant change in secondary pore volume at a B/C ratio of 0.31, which had the largest pore volume among all GDEs. In the polarization curve, JNT30-A6P GDE showed the best membrane electrode assembly (MEA) performance with a peak power density of 384 mW/cm2 at a a B/C ratio of 0.31. From the distribution of relaxation time analysis, the peak 1 corresponding to mass transfer resistance of oxygen reduction reaction (ORR) was significantly reduced in the JNT30-A6P GDE. This is the result that when the binder content decreased, the volume of the secondary pore increased, and the mass transfer resistance of ORR decreased, which played an essential role in the MEA performance.

A study on the design of triggering pulse generator for the triggered vacuum switch (진공스위치 트리거 발생기 설계에 관한연구)

  • Kim, Mu-Sang;Son, Yun-Gyu;Park, Ung-Hwa;Lee, Byeong-Jun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.201.2-201.2
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    • 2016
  • The triggered vacuum switch (TVS) is widely used as a high power switch in the field of pulsed power application. TVS can produce current of higher than 100 kA within a microsecond after being triggered. A triggering high voltage pulse generator supplies a high voltage signal to the trigger system to initiate the discharge between a trigger pin and one of main electrode. The trigger system, which consists of a tungsten trigger electrode and cylindrical ceramic insulator around it, is normally installed at the center of main cathode electrode. The discharging characteristics of the trigger system strongly depend on the geometry, electrode material, vacuum pressure and so on. In addition, we especially will focus on the developing a triggering pulse generator, which can vary not only value of voltage but also pulse duration, because its properties gives pivot influences on the TVS discharge. To verify such effects, we made a 3.3 kJ TVS set-up initially. Thus we will discuss some of prominent results from 3.3 kJ TVS system. In parallel we will show on the design of 300 kJ TVS system for the high current in the future.

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A Study on the CCFL Parallel Driving Circuit for the large LCD TV (대화면 LCD TV용 CCFL 병렬 구동에 관한 연구)

  • Jang, Young-Su;Yoon, Seok;Kweon, Gie-Hyoun;Han, Sang-Kyoo;Hong, Sung-Soo;Sakong, Suk-Chin;Roh, Chung-Wook
    • The Transactions of the Korean Institute of Power Electronics
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    • v.11 no.5
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    • pp.454-462
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    • 2006
  • To enhance the competitive edge of the material cost, various techniques lowering the material cost of inverter to drive Cold Cathode Fluorescent Lamp (CCFL) have been developed. In this paper, the theoretical analysis has been done for the existing techniques such as Jin Balance and O2Micro technique. Especially, How to design the value of magnetizing inductance to meet the specification of the lamp current tolerance between lamps has been disclosed. Based on this result, two kinds of hybrid type balancing techniques have been proposed and analyzed mathematically, Also, the accuracy of the proposed techniques has been verified through Pspice simulation.

Catalytic Oxidoreduction of Pyruvate/Lactate and Acetaldehyde/Ethanol Coupled to Electrochemical Oxidoreduction of $NAD^+$/NADH

  • Shin, In-Ho;Jeon, Sung-Jin;Park, Hyung-Soo;Park, Doo-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.14 no.3
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    • pp.540-546
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    • 2004
  • We deviced a new graphite-Mn(II) electrode and found that the modified electrode with Mn(II) can catalyze NADH oxidation and $NAD^+$ reduction coupled to electricity production and consumption as oxidizing agent and reducing power, respectively. In fuel cell with graphite-Mn(II) anode and graphite-Fe(III) cathode, the electricity of 1.5 coulomb (A x s) was produced from NADH which was electrochemically reduced by the graphite-Mn(II) electrode. When the initial concentrations of pyruvate and acetaldehyde were adjusted to 40 mM and 200 mM, respectively, about 25 mM lactate and 35 mM ethanol were produced from 40 mM pyruvate and 200 mM acetaldehyde, respectively, by catalysis of ADH and LDH in the electrochemical reactor with $NAD^+$ as cofactor and electricity as reducing power. By using this new electrode with catalytic function, the bioelectrocatalysts are engineered; namely, oxidoreductase (e.g., lactate dehydrogenase) and $NAD^+$ can function for biotransformation without electron mediator and second oxidoreductase for $NAD^+$/NADH recycling.

Disinfection of harmful organism for ballast water using electrolytic treatment system (전해처리를 통한 밸러스트수의 유해생물 살균처리)

  • 박상호;김인수
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2004.04a
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    • pp.227-232
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    • 2004
  • Ballast water from ship harmful microorganism sterilized use of electrolytic sterilization system. The experimental methods were use of peristaltic flow pump upward on electrode pole. Due to reaction time, HRT were unlike microorganism on flow rate. In electrolysis, dioxide iridium coated titanium(Ti/IrO$_2$) and stainless steel plate were used for anode and cathode respectively. Current density controls make use of D.C Power supply on 250V 100Amper. Experimental use of current density between 0.1 and 0.5A was able to disinfect microorganism at 5 seconds by the reaction time. This study shows that the electrolyzed water has a potential for the sterilization of ballast water.

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Electrochemical Precipitation Treatment of Copper from an Heavymetal Wastewater (중금속폐수에서 구리의 전기화학적 침전처리)

  • 김재우;이재동;이우식;지은상
    • Journal of Environmental Health Sciences
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    • v.23 no.3
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    • pp.1-6
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    • 1997
  • This research was conducted in the laboratory to investigate an alternative of Copper(Cu) removal from an heavymetal wastewater using the electrochemical precipitation(ECP) process. The ECP unit consisted of an electrolytic cell made of Titanium plate and Steel plate representing anode and cathode. The DC power source applied to the ECP unit had electrical potential(E) of 50$\pm$ 1V, respectively. The synthetic wastewater used in the experiments contained Cu in the 10 mg/l concentration and the electrode separation were 2, 3, 4 cm and the initial pH were 3, 6, 9, 12, and electrolytic concentration were 0.005, 0.0125, 0.025, 0.0375 mole, and the real heavymetal wastewater used in the experiments. From the experiment for removal efficiency according to pH variation, the low pH area doesn't give the coagulation effect by Ti(OH)$_4$ because process interfere with the coagulation and oxidation reaction, therefore the optimum pH was 4-7. The removal rate was 97.75% after the lapse of 30 minutes when copper concentration and electrolytic concentration were respectively 10 mg/l and 0.025 mole. The removal rate was 96.41% after the lapse of 30minutes when the real heavymetal wastewater used. The optimum consumption of power showed 27KWh/m$^3$ when copper concentration, electrolyte concentration and cell potential were respectively 10 mg/l, 0.025 mole and 50$\pm$ 1 Volt.

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Single Cell Stacked Planar Type SOFC Assembled Using a Ag-Current Collector (Ag 집전체를 적용한 평판형 SOFC 단전지)

  • Cho, Nam-Ung;Hwang, Soon-Cheol;Lee, In-Sung
    • Journal of the Korean Ceramic Society
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    • v.44 no.12
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    • pp.720-726
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    • 2007
  • Current collectors of SOFC play a significant role on the performance of power generation. In this study a single cell stacked SOFC was assembled using Ag-mesh as a cathode current collector, and evaluated its performance. No gas leakages of the single cell stack occurred in the tests of gas detection and OCV measurement. The OCV and initial power of the stack were 1.09V and $0.45W/cm^2$, respectively, under the flow rates of air at 2,500 cc/min and $H_2$ at 1,000 cc/min at the test temperature of $750^{\circ}C$. A degradation rate of 44.0% was measured during the prolonged time of 307 h. The relatively low durability of the tested single cell stack was found to be the evaporation of Ag-mesh at the current corrector.

Optimal switching method of SI-Thyristor using internal impedance evaluation (SI-Thyristor의 내부 임피던스 계산을 통한 최적 스위칭 제어)

  • Ju, Heung-Jin;Kim, Bong-Seok;Hwang, Hwui-Dong;Park, Jeong-Ho;Ko, Kwang-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.122-122
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    • 2010
  • A Static Induction Thyristor (SI-Thyristor) has a great potential as power semiconductor switch for pulsed power or high voltage applications with fast turn-on switching time and high switching stress endurance (di/dt, dV/dt). However, due to direct commutation between gate driver and SI-Thyristor, it is difficult to design optimal gate driver at the aspect of impedance matching for fast gate current driving into internal SI-Thyristor. Thus, to penetrate fast positive gate current into steady off state of the SI-Thyristor, it is proposed and proceeded the internal impedance calculation of the SI-Thyristor at steady off state with the gate driver while switching conditions that are indicated applied gate voltage, $V_{GK}$ and applied high voltage across anode and cathode, $V_{AK}$.

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