• Title/Summary/Keyword: Cathode Power

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Study of performance evaluation method for SOFC (고체전해질형 연료전지의 성능평가에 관한 연구)

  • 김귀열;엄승욱;문성인
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.160-163
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    • 1997
  • The object of this study is to develop various composing material for SOFC generation system, and to test unit cell performance manufactured. So we try to present a guidance for developing mass power generation system. We concentrated on development of manufacturing process for cathode, anode and electrolyte.

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Performance evaluation method for Solid Oxide Fuel Cell (고체 전해질형 연료전지의 특성평가법 연구)

  • Kim, G.Y.;Eom, S.W.;Moon, S.I.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1389-1390
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    • 1997
  • The object of this research is to develop various composing material for Solid Oxide Fuel Cell generation system, and to test single cell performance manufactured. So we try to present a guidance for developing mass power generation system. We concentrated on development of manufacturing process for cathode, anode and electrolyte.

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Influence of Glass Tube Diameter in the Cold Cathode Fluorescent Lamps for 40-inch LCD-TVs

  • Lee, Min-Kyu;Lee, Kyoung-Ho;Han, Kyu-Hyeon;Lee, Jae-Wook
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.707-710
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    • 2009
  • As the inner diameter of CCFL is increased in the range of outer diameters 3~5 mm, the luminance efficiency is increased by the low power consumption. For the outer diameter 5 mm, the efficiency is linearly increased even at the range of a high current.

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Direct-Write Fabrication of Solid Oxide Fuel Cell by Robo-Dispensing (로보 디스펜싱을 이용하여 직접묘화방식으로 제조된 고출력 소형 고체산화물 연료전지)

  • Kim, Yong-Bum;Moon, Jooho;Kim, Joosun;Lee, Jong-Ho;Lee, Hae-Weon
    • Journal of the Korean Ceramic Society
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    • v.42 no.6 s.277
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    • pp.425-431
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    • 2005
  • Line Shaped Solid Oxide Fuel Cell (SOFC) with multilayered structure has been fabricated via direct-writing process. The cell is electrolyte of Ni-YSZ cermet anode, YSZ electrolyte and LSM cathode. They were processed into pastes for the direct writing process. Syringe filled with each electrode and electrolyte paste was loaded into the computer-controlled robe-dispensing machine and the paste was dispensed through cylindrical nozzle of 0.21 mm in diameter under the air pressure of 0.1 tow onto a moving plate with 1.22 mm/s. First of all, the anode paste was dispensed on the PSZ porous substrate, and then the electrolyte paste was dispensed. The anode/electrolyte and the PSZ substrate were co-fired at $1350^{\circ}C$ in air atmosphere for 3 h. The cathode layer was similarly dispensed and sintered at $1200^{\circ}C$ for 1 h. All the electrode/electrolyte lines were visually aligned during the direct writing process. The effective reaction area of fabricated SOFC was $0.03 cm^2$, and the thickness of anode, electrolyte and cathode was 20 $\mu$m, 15 $\mu$m, and 10 $\mu$m, respectively. The single line-shaped SOFC fabricated by direct-writing process exhibited OCV of 0.95 V and maximum power density of $0.35W/cm^2$ at $810^{\circ}C$.

Electrochemical properties of all solid state Li/LiPON/Sn-substituted LiMn2O4 thin film batteries

  • Kong, Woo-Yeon;Yim, Hae-Na;Yoon, Seok-Jin;Nahm, Sahn;Choi, Ji-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.409-409
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    • 2011
  • All solid-state thin film lithium batteries have many applications in miniaturized devices because of lightweight, long-life, low self-discharge and high energy density. The research of cathode materials for thin film lithium batteries that provide high energy density at fast discharge rates is important to meet the demands for high-power applications. Among cathode materials, lithium manganese oxide materials as spinel-based compounds have been reported to possess specific advantages of high electrochemical potential, high abundant, low cost, and low toxicity. However, the lithium manganese oxide has problem of capacity fade which caused by dissolution of Mn ions during intercalation reaction and phase instability. For this problem, many studies on effect of various transition metals have been reported. In the preliminary study, the Sn-substituted LiMn2O4 thin films prepared by pulsed laser deposition have shown the improvement in discharge capacity and cycleability. In this study, the thin films of LiMn2O4 and LiSn0.0125Mn1.975O4 prepared by RF magnetron sputtering were studied with effect of deposition parameters on the phase, surface morphology and electrochemical property. And, all solid-state thin film batteries comprised of a lithium anode, lithium phosphorus oxy-nitride (LiPON) solid electrolyte and LiMn2O4-based cathode were fabricated, and the electrochemical property was investigated.

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Performance Charateristics of Direct Borohydrides Fuel Cell with Novel Catalyst (귀금속 촉매를 사용한 직접 보로하이드라이드 연료전지의 특성 연구)

  • Jung, M.K.;Shin, D.R.;Seol, Y.K.;Jung, D.H.
    • Journal of the Korean Electrochemical Society
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    • v.8 no.1
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    • pp.6-11
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    • 2005
  • Direct borohydrides fuel cell (DBFC) was emerged to complement the problem of DMFC's low performance and methanol crossover to the cathode and to apply the fuel cell to portable and mobile devices. In this study, the characteristics of novel catalysts was tested to establish the electrode preparation process of DBFC. Pt black and carbon supported-Pt by paste method were used as the cathode catalysts. Pt black, carbon supported-Au and $AB_5$ alloy were used as the anode catalysts. The characteristics of the electrodes were analyzed by XRD, SEM, EDS. The performance test of single cell using the electrodes were carried out in order to evaluate the electrode performance. In the result, the maximum power output was obtained as 366 mW/mg when using Pt/C as anode and cathode catalysts.

The Electrochemical Characterization of $LiMn_{2-y}M_{y}O_{4}$ Cathode Material. III. The Effect of Temperature on the Charge-discharge Property and AC Impedance of $LiMn_{2-y}M_{y}O_{4}$ ($LiMn_{2-y}M_{y}O_{4}$ 정극 활물질의 전기화학적 특성. III. $LiMn_{2-y}M_{y}O_{4}$의 충방전 특성과 AC 임피던스의 온도 의존성)

  • 정인성;구할본;김종욱;손명모;이헌수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.8
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    • pp.663-669
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    • 2001
  • Spinel LiM $n_2$ $O_4$ and LiM $n_{1.9}$M $g_{0.1}$ $O_4$ power was synthesized with solid-state method by calcining the mixture of LiOH.$H_2O$, Mn $O_2$ and MgO at 80$0^{\circ}C$ for 36 h in an air atmosphere. To investigate the effect of temperature on he cycle performance of cathode material during cycling, charge-discharge experiments and ac impedance measurement were performed. Initial discharge capacity was gradually increased with the increase of charge-discharge temperature. Discharge capacity at high temperature was suddenly decreased during cycling. On the other hand, discharge capacity at low temperature was almost constant during cycling. It confirmed that Mn dissolution is serious at high temperature than at low temperature. LiM $n_2$ $O_4$ and LiM $n_{1.9}$M $g_{0.1}$ $O_4$ showed the best capacity and stability at room temperature.ure.ure.

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Fabrication of Boron-Doped Activated Carbon for Zinc-Ion Hybrid Supercapacitors (아연-이온 하이브리드 슈퍼커패시터를 위한 보론 도핑된 활성탄의 제조)

  • Lee, Young-Geun;Jang, Haenam;An, Geon-Hyoung
    • Korean Journal of Materials Research
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    • v.30 no.9
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    • pp.458-464
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    • 2020
  • Zinc-ion hybrid supercapacitors (ZICs) have recently been spotlighted as energy storage devices due to their high energy and high power densities. However, despite these merits, ZICs face many challenges related to their cathode materials, activated carbon (AC). AC as a cathode material has restrictive electrical conductivity, which leads to low capacity and lifetime at high current densities. To overcome this demerit, a novel boron (B) doped AC is suggested herein with improved electrical conductivity thanks to B-doping effect. Especially, in order to optimize B-doped AC, amounts of precursors are regulated. The optimized B-doped AC electrode shows a good charge-transfer process and superior electrochemical performance, including high specific capacity of 157.4 mAh g-1 at current density of 0.5 A g-1, high-rate performance with 66.6 mAh g-1 at a current density of 10 A g-1, and remarkable, ultrafast cycling stability (90.7 % after 10,000 cycles at a current density of 5 A g-1). The superior energy storage performance is attributed to the B-doping effect, which leads to an excellent charge-transfer process of the AC cathode. Thus, our strategy can provide a rational design for ultrafast cycling stability of next-generation supercapacitors in the near future.

Enhancing Electricity Generation Using a Laccase-Based Microbial Fuel Cell with Yeast Galactomyces reessii on the Cathode

  • Chaijak, Pimprapa;Sukkasem, Chontisa;Lertworapreecha, Monthon;Boonsawang, Piyarat;Wijasika, Sutthida;Sato, Chikashi
    • Journal of Microbiology and Biotechnology
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    • v.28 no.8
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    • pp.1360-1366
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    • 2018
  • The fungi associated with termites secrete enzymes such as laccase (multi-copper oxidase) that can degrade extracellular wood matrix. Laccase uses molecular oxygen as an electron acceptor to catalyze the degradation of organic compounds. Owing to its ability to transfer electrons from the cathodic electrode to molecular oxygen, laccase has the potential to be a biocatalyst on the surface of the cathodic electrode of a microbial fuel cell (MFC). In this study, a two-chamber MFC using the laccase-producing fungus Galactomyces reessii was investigated. The fungus cultured on coconut coir was placed in the cathode chamber, while an anaerobic microbial community was maintained in the anode chamber fed by industrial rubber wastewater and supplemented by sulfate and a pH buffer. The laccase-based biocathode MFC (lbMFC) produced the maximum open circuit voltage of 250 mV, output voltage of 145 mV (with a $1,000{\Omega}$ resistor), power density of $59mW/m^2$, and current density of $278mA/m^2$, and a 70% increase in half-cell potential. This study demonstrated the capability of laccase-producing yeast Galactomyces reessii as a biocatalyst on the cathode of the two-chamber lbMFC.

An experimental study on the performance improvement of dead-end type PEMFC with pulsating effect (맥동 효과를 이용한 dead-end type 연료전지의 성능향상에 대한 실험적 연구)

  • Choi, Jong-Won;Seo, Jeong-Hoon;Hwang, Yong-Sheen;Lee, Dae-Heung;Cha, Suk-Won;Kim, Min-Soo
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.567-571
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    • 2008
  • PEM Fuel Cell operation mode can be classified into dead-end mode or open mode by whether the outlet port is blocked or not. Generally, dead-end type fuel cell has some merits on the pressure drop and system efficiency because it can generate more power than the open type fuel cell due to high operating pressure condition. However, the periodic purging process should be done for removing water which is formed as product of a reaction in the gas diffusion layer. In this study, cathode side dead-end type operation has been conducted. Moreover, pulsating flow generator at the outlet of cathode side has been suggested for increasing the period to purge the formed water because the pulsating flow can make formed water scattered uniformly over the whole channel. As a result, the purging period with pulsation increased by 1.5-2 times longer than that without pulsating.

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