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CHARACTERISTICS OF HETEROEPITAXIALLY GROWN $Y_2$O$_3$ FILMS BY r-ICB FOR VLSI

  • Choi, S.C.;Cho, M.H.;Whangbo, S.W.;Kim, M.S.;Whang, C.N.;Kang, S.B.;Lee, S.I.;Lee, M.Y.
    • 한국표면공학회지
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    • 제29권6호
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    • pp.809-815
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    • 1996
  • $Y_2O_3$-based metal-insulator-semiconductor (MIS) structure on p-Si(100) has been studied. Films were prepared by UHV reactive ionized cluster beam deposition (r-ICBD) system. The base pressure of the system was about $1 \times 10^{-9}$ -9/ Torr and the process pressure $2 \times 10^{-5}$ Torr in oxygen ambience. Glancing X-ray diffraction(GXRD) and in-situ reflection high energy electron diffracton(RHEED) analyses were performed to investigate the crystallinity of the films. The results show phase change from amorphous state to crystalline one with increasingqr acceleration voltage and substrate temperature. It is also found that the phase transformation from $Y_2O_3$(111)//Si(100) to $Y_2O_3$(110)//Si(100) in growing directions takes place between $500^{\circ}C$ and $700^{\circ}C$. Especially as acceleration voltage is increased, preferentially oriented crystallinity was increased. Finally under the condition of above substrate temperature $700^{\circ}C$ and acceleration voltage 5kV, the $Y_2O_3$films are found to be grown epitaxially in direction of $Y_2O_3$(1l0)//Si(100) by observation of transmission electron microscope(TEM). Capacitance-voltage and current-voltage measurements were conducted to characterize Al/$Y_2O_3$/Si MIS structure with varying acceleration voltage and substrate temperature. Deposited $Y_2O_3$ films of thickness of nearly 300$\AA$ show that the breakdown field increases to 7~8MV /cm at the same conditon of epitaxial growing. These results also coincide with XPS spectra which indicate better stoichiometric characteristic in the condition of better crystalline one. After oxidation the breakdown field increases to 13MV /cm because the MIS structure contains interface silicon oxide of about 30$\AA$. In this case the dielectric constant of only $Y_2O_3$ layer is found to be $\in$15.6. These results have demonstrated the potential of using yttrium oxide for future VLSI/ULSI gate insulator applications.

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물류 및 유통산업의 블록체인 활용과 정책 방향 (Application and Policy Direction of Blockchain in Logistics and Distribution Industry)

  • 김기흥;심재현
    • 산경연구논집
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    • 제9권6호
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    • pp.77-85
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    • 2018
  • Purpose - The purpose of this study is to subdivide trade transaction-centered structure in a logistics/distribution industry system to apply blockchain, to establish and resolve with which types of technology, and to provide policy direction of government institution and technology to apply blockchain in this kind of industry. Research design, data, and methodology - This study was conducted with previous researches centered on cases applied in various industry sectors on the basis of blockchain technology. Results - General fields of blockchain application include digital contents distribution, IoT platform, e-Commerce, real-estate transaction, decentralized app. development(storage), certification service, smart contract, P2P network infrastructure, publication/storage of public documents, smart voting, money exchange, payment/settlement, banking security platform, actual asset storage, stock transaction and crowd funding. Blockchain is being applied in various fields home and abroad and its application cases can be explained in the banking industry, public sector, e-Commerce, medical industry, distribution and supply chain management, copyright protection. As examined in the blockchain application cases, it is expected to establish blockchain that can secure safety through distributed ledger in trade transaction because blockchain is established and applied in various sectors of industries home and abroad. Parties concerned of trade transaction can secure visibility even in interrupted specific section when they provide it as a base for distributed ledger application in trade and establish trade transaction model by applying blockchain. In case of interrupted specific section by using distributed ledger, blockchain model of trade transaction needs to be formed to make it possible for parties concerned involved in trade transaction to secure visibility and real-time tracking. Additionally, management should be possible from the time of contract until payment, freight transfer to buyers through land, air and maritime transportation. Conclusions - In order to boost blockchain-based logistics/distribution industry, the government, institutionally, needs to back up adding legal plan of shipping, logistics and distribution, reviewing standardization of electronic switching system and coming up with blockchain-based industrial road maps. In addition, the government, technologically, has to support R&D for integration with other high technology, standardization of distribution industry's blockchain technology and manpower training to expand technology development.

지속가능한 생태관광을 위한 평가지표 개발 및 적용에 관한 연구 (A Study on the Development of the Indicator Sets for Evaluating the Sustainable Eco-tourism and It's Application)

  • 이재혁;이희연
    • 대한지리학회지
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    • 제47권6호
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    • pp.853-869
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    • 2012
  • 최근 환경에 대한 인식과 관광 산업이 성장하면서 세계적으로 확대되고 있는 생태관광은 지역 발전 전략을 위한 대안으로도 간주되고 있다. 더 나아가 생태관광은 지속가능한 개발을 위한 효과적인 도구로도 잠재성이 있는 것으로까지 인지되고 있다. 그러나 생태관광개발이 잘 계획되지 못하거나 잘못 실행되는 경우 생태관광이란 이름 하에서 가져온 경제적인 이익이 오히려 사회 생태적인 파괴를 가져오기도 한다, 본 연구는 생태관광의 지속가능성을 측정 평가할 수 있는 지표를 개발하고 개발된 평가지표를 한국의 10대 생태관광지에 적용하는데 목적을 두었다. 개발된 평가지표들을 사용한 결과 여러 생태관광지를 동시에 비교하여 생태관광지 마다의 지속가능성 상태와 특성을 확인할 수 있었으며, 개발된 평가지표 체계는 앞으로도 지속가능한 생태관광을 모니터링할 수 있음을 보여주었다. 특히 평가 영역별 가중치를 달리 부여한 결과 나타난 민감도 분석에서 순위 변화가 매우 작아서 평가 영역별 가중치 부여 문제가 심각하지 않을 수 있음을 확인하였다. 이러한 분석결과를 바탕으로 본 연구에서는 생태관광지의 지속가능성의 평가지표를 규범적, 분석적, 실증적 차원에서의 적용 가능성을 제시하였다.

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Methalloporphyrin(MTPP 및 M(o-Cl)TPP)과 염기성리간드(L)간의 화학평형. (M = $Zn^{2+},\;Cu^{2+},\;Ni^{2+}$:TPP = tetraphenylporphyrin, (o-Cl)TPP = tetrakis (ortho-chlorophenyl)porphyrin: L = imidazole, pyridine,1-methylimidazole, 2,6-lutidine) (Chemical Equilibrium between Metalloporphyrins (MTPP and M(o-Cl)TPP) and Basic Ligands(L). (M = $Zn^{2+],\;Cu^{2+},\;Ni^{2+}$: TPP = tetraphenylporphyrin, (o-Cl)TPP = tetrakis (ortho-chlorophenyl)porphyrin: L = imidazole, pyridine, 1-methylimidazole, 2,6-lutidine))

  • 박유철;김성수;나훈길
    • 대한화학회지
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    • 제35권5호
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    • pp.512-519
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    • 1991
  • 유기용매$(CH_2Cl_2,\;C_6H_6,\;CH_3NO_2,\;(CH_3)_2CO,\;CHCl_3,\;DMF,\;DMSO)$에서 Zn(II)-, Cu(II)- 및 Ni(II)-tetrakis(o-chlorophenyl)porphyrin(o-ClTPP)과 Zn(II)-, Cu(II)- 및 Ni(II)-tetraphenylporphyrin(TPP) 착물과 질소원자를 포함한 염기성 리간드(pyridine, imidazole, 1-methylimidazole 및 2,6-lutidine)간의 결합 반응성을 이온강도 0.01M에서 연구하였다. metalloporphyrin과 염기성 리간드간의 평형상수는 온도범위 15 ~ 35${\circ}C$에서 분광광도법을 이용하여 결정하였으며, 이 때 M(II)-TPP에서 관찰된 평형상수는 입체적 장애가 더 큰 M(II)-(o-Cl)TPP에서 보다 큰 값을 나타내었다. M(II)-TPP에서 logK값은 염기성 리간드의 pKa값이 커질수록 증가하였지만 입체적장애를 받는 M(II)-(o-Cl)TPP에서 logK는 리간드의 $pK_a$값에 비례하지 않았다. 열역학적 파라미터 분석결과 M(o-Cl)TPP의 안정도는 거의 반응엔트로피에 의존하였으나, M(II)-TPPL의 안정도는 반응엔탈피와 반응엔트로피에 거의 비슷한 영향을 나타내었다. metalloporphyrin에 대한 용매의 배위능을 DMF, DMSO, $CHCl_3,\;(CH_3)_2CO$에서 측정하였고, 이들 결과로부터 평형상수에 대한 용매효과를 논의하였다.

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Construction and Production of Concatameric Human TNF Receptor-Immunoglobulin Fusion Proteins

  • Yim, Su-Bin;Chung, Yong-Hoon
    • Journal of Microbiology and Biotechnology
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    • 제14권1호
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    • pp.81-89
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    • 2004
  • Tumor necrosis factor-$\alpha$ (TNF-$\alpha$) and lymphotoxin-$\alpha$ (LT-$\alpha$, TNF-$\beta$) can initiate and perpetuate human diseases such as multiple sclerosis (MS), rheumatoid arthritis (RA), and insulin-dependent diabetes mellitus (IDDM). TNFs can be blocked by the use of soluble TNF receptors. However, since monomeric soluble receptors generally exhibit low affinity or function as agonists, the use of monomeric soluble receptors has been limited in the case of cytokines such as TNF-$\alpha$, TNF-$\alpha$, interleukin (IL)-1, IL-4, IL-6, and IL-13, which have adapted to a multi component receptor system. For these reasons, very high-affinity inhibitors were created for the purpose of a TNFs antagonist to bind the TNFR and trigger cellular signal by using the multistep polymerase chain reaction method. First, recombinant simple TNFR-Ig fusion proteins were constructed from the cDNA sequences encoding the extracellular domain of the human p55 TNFR (CD120a) and the human p75 TNFR (CD120b), which were linked to hinge and constant regions of human $IgG_1$ heavy chain, respectively using complementary primers (CP) encoding the complementary sequences. Then, concatameric TNFR-Ig fusion proteins were constructed using recombinant PCR and a complementary primer base of recombinant simple TNFR-Ig fusion proteins. For high level expression of recombinant fusion proteins, Chinese hamster ovary (CHO) cells were used with a retroviral expression system. The transfected cells produced the simple concatameric TNFR-Ig fusion proteins capable of binding TNF and inactivating it. These soluble versions of simple concantameric TNFR-Ig fusion proteins gave rise to multiple forms such as simple dimers and concatameric homodimers. Simple TNFR-1g fusion proteins were shown to have much more reduced TNF inhibitory activity than concatameric TNFR-Ig fusion proteins. Concatameric TNFR-Ig fusion proteins showed higher affinity than simple TNFR-Ig fusion proteins in a receptor inhibitor binding assay (RIBA). Additionally, concatameric TNFR-Ig fusion proteins were shown to have a progressive effect as a TNF inhibitor compared to the simple TNFR-Ig fusion proteins and conventional TNFR-Fc in cytotoxicity assays, and showed the same results for collagen induced arthritis (CIA) in mice in vivo.

Avoidance of Internal Resonances in Hemispherical Resonator Assemblies from Fused Quartz Connected by Indium Solder

  • 세르게이 사라플로프;이희남;박상진
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2013년도 춘계학술대회 논문집
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    • pp.835-841
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    • 2013
  • Modern solid-state gyroscopes (HRG) with hemispherical resonators from high-purity quartz glass and special surface superfinishing and ultrathin gold coating become the best instruments for precise-grade inertial reference units (IRU) targeting long-term space missions. Designing of these sensors could be a notable contribution into development of Korea as a space nation. In participial, 40mm diameter thin-shell resonator from high-purity fused quartz, fabricated as a single-piece with its supporting stem has been designed, machined, etched, tuned, tested, and delivered by STM Co. (ATS of Ukraine) several years ago; an extremely-high Q-factor (upto 10~20 millions) has been shown. Understanding of the best way how to match such a unique sensor with inner glass assembly of the gyro means how to use the high potential in a maximal extent; and this has become the urgent task. Inner quartz glass assembly has a very thin indium (In) layer soldered the resonator and its silica base (case), but effects of internal resonances between operational modal pair of the shell-cup and its side (parasitic) modes can notable degrade the potential of the sensor as a whole, instead of so low level of resonator's intrinsic losses. Unfortunately, there are special combinations of dimensions of the parts (so-called, "resonant sizes"), when intensive losses of energy occurs. The authors proposed to use the length of stem's fixture as an additional design parameter to avoid such cases. So-called, a cyclic scheme of finite element method (FEM) and ANSYS software were employed to estimate different combinations of gyro assembly parameters. This variant has no mismatches of numerical origin due to FEM's discrete mesh. The optimum length and dangerous "resonant lengths" have been found. The special attention has been paid to analyses of 3D effects in a cup-stem transient zone, including determination of a difference between the positions of geometrical Pole of the resonant hemisphere and of its "dynamical Pole", i.e., its real zone of oscillation node. Boundary effects between the shell (cup) and 3D short "beams" (inner and outer stems) have been ranged. The results of the numerical experiments have been compared with the classic model of a quasi-hemispherical shell band with inextensional midsurface, and the solution using Rayleigh's functions of the $1^{st}$ and $2^{nd}$ kinds. To guarantee the truth of the recommended sizes to a designer of the real device, the analytical and FEM results have been compared with experimental data for a party of real resonators. The consistency of the results obtained by different means has been shown with errors less than 5%. The results notably differ from the data published earlier by different researchers.

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모야모야병과 동반된 신 동맥 협착에 따른 신성 고혈압을 보인 1례 (A Case of Renovascular Hypertension Due to Renal Artey Stenosis Related to Moyamoya Disease)

  • 김정아;김승;김효선;신재일;정일천;김동석;김명준;이도연;이재승
    • Childhood Kidney Diseases
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    • 제11권2호
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    • pp.294-298
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    • 2007
  • 모야모야병은 주로 뇌혈관 협착을 유발하여 측부순환을 생성하는 질환으로 최근 뇌혈관 이외의 혈관에도 침범할 수 있음이 보고되고 있다. 지금까지 모야모야병에서 폐동맥, 관상동맥, 말초동맥 및 신동맥의 협착을 동반한 증례들이 발표되고 있다. 이 중 신동맥 협착을 동반한 경우 이로 인한 신성고혈압을 보이는 증례들이 보고되고 있으며 이는 모야모야병에서 지속적인 고혈압을 보여 2차적인 뇌경색이나 뇌출혈 등의 합병증을 유발할 수 있으므로 모야모야 환자의 치료에 있어서 항상 면밀하게 평가되어야 할 부분이다. 저자들은 모야모야병으로 양측 뇌경질막동맥간접문합술을 시행 받고 경과관찰 하던 환아에서 지속되는 고혈압으로 인해 발견된 신동맥 협착 및 이로 인한 신성 고혈압을 경험하였기에 이를 보고하는 바이다.

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전자상거래하에서의 하이브리드 마케팅 채널의 믹스 전략에 관한 연구 (Optimal Strategy of Hybrid Marketing Channel in Electronic Commerce)

  • 천세학;김재철
    • Asia pacific journal of information systems
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    • 제17권2호
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    • pp.83-95
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    • 2007
  • We are motivated by how offline and online firms compete. The Internet made many conventional offline firms build a dynamic online business as another sales channel using their advantages such as brand equity, an existing customer base with comprehensive purchasing data, integrated marketing, economies of scale, and longtime experience with the logistics of order fulfillment and customer service. Even though the hybrid selling using both offline and online channel seems to have advantages over a pure online retailer, all the conventional offline firms are not seen to create an online business. Many conventional offline firms began to launch online business since the Internet era, however, just being online business is not likely to guarantee success. According to Bizate.com's report whether the hybrid channel strategy is successful is still under investigation. For example, consider the classic case of Barnes and Noble versus Amazon.com, Barnes and Noble was already the largest chain of bookstores in the U,S., when Amazon.com was established in 1995, BarnesandNoble.com followed suit in 1997, After suffering losses in its initial years, Amazon finally turned profitable in 2003. In 2004, Amazon's net income was $588 million on revenues of $6.92 billion, while Barnes and Noble earned $143 million on revenues of $4.87 billion, which included BarnesandNoble.com's loss of $21 million on revenues of $420 million. While these examples serve to motivate our thinking, it does not explain when offline firms should venture online. It also does not provide an analytical framework that can generalized to other competitive online-offline situations. We attempt to do this in this paper and analyze a hybrid channel model where a conventional offline firm competes against online firms using its own direct online channels. We are particularly interested in an optimal channel strategy when a conventional offline firm sells its products through its own direct online channel to compete with other rival online firms. We consider two situations where its direct online channel and other online firms are symmetric and asymmetric in the brand effect. The analysis of this paper presents several findings. In the symmetric model where a hybrid firm's online channel is not differentiated from a pure online firm, (i) a conventional offline firm will not launch its online business. In the asymmetric model where a hybrid firm's online channel is differentiated from a pure online firm, (ii) a conventional offline firm can launch its online business if its brand effect is greater than a certain threshold. (iii) there is a positive relationship between its brand effect and online customer costs showing that a conventional offline firm needs more brand effect in order to launch online business as online customer costs decrease. (iv) there is a negative relationship between its brand effect and the number of customers with access to the Internet showing that a conventional offline firm tends to launch its online business when customers with access to the Internet increases.

일반화염에 의해 소손된 정수기의 연소 확산 패턴 및 화재위험성 평가 (Assessment of the Combustion Diffusion Pattern and Fire Risk of a Water Purifier Damaged by a General Fire)

  • 최충석
    • 한국화재소방학회논문지
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    • 제26권3호
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    • pp.35-39
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    • 2012
  • 본 논문에서는 정수기의 외부 및 내부에서 인위적으로 착화시켰을 때의 연소 확산 패턴을 분석하고, 소손된 정수기의 화재원인 규명을 위한 자료를 제공하는데 있다. 정수기의 연소 확산 속도는 외부에서 착화시켰을 때보다 내부에서 착화시켰을 때 화염의 진행은 빠른 것으로 분석되었다. 외부에서 착화되어 정수기가 반소 이상 되는데 소요되는 시간은 360 sec 정도이었고, 내부에서 착화시켰을 때는 180 sec 정도가 소요되었다. 즉, 내부에서 착화되면 발생된 열이 내부에 축적되었다가 일순간에 방사되기 때문에 연소가 빠른 것으로 판단된다. 외부에서 착화시켜 소손된 것은 균일한 탄화 패턴을 보이며, 바닥면에 탄화물은 순차적으로 퇴적되었다. 내부에서 착화시켜 소손된 것은 탄화면의 경계가 비교적 선명하였으며, 발화점을 기준으로 브이패턴을 형성하였다. 따라서 연소 패턴의 차이를 통해서 어느 쪽에서 화재가 진행되었는지를 판단할 수 있는 객관적 근거가 제시되었다. 정수기가 화염의 공격을 받아 반소될 때까지 내장된 퓨즈의 용단 및 전원 보호 장치의 작동 등은 발생하지 않았다. 또한 일반화염을 공격 받아 소손된 퓨즈는 금속 홀더 부분에서 탄화가 발생하는 것이 확인됨에 따라 사고원인 판정의 근거로 활용할 수 있을 것으로 판단된다.

농촌문화마을 조성 및 활성화 방안연구(1) - 김제시 대산마을(현황분석 및 기본구상)을 중심으로 - (A Study on the Creation and Activation Program of Cultural Rural Village - Focused on the Case in Dae -San Village, Kimje-si, Chonbuk Province -)

  • 최만봉
    • 농촌계획
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    • 제6권1호
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    • pp.19-28
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    • 2000
  • Now in order to overcome the weakest points of the rural areas of the city of Kimje and, transform them into rural cultural villages which have local governing systems suitable to new localization age and activate this plan, we selected Daesan Village as a model village which had shown a lot of potentials in the basic research and studied it dividing it into the former part and the latter part. We studied Daesan village in the former part focusing on state analysis and basic ideas and in the latter part focusing on master plan and detail planning. We can summarize the conclusion like the followings. 1. Daesan Village located 8 kilometer away from the downtown Kimje and the city of Iksan respectably has comparatively good environment of good sunny place as an open field whose surrounding configuration of the ground consists of farming lands and low hills in front and rear. It has 38 farming households in all. 2. Human environment(인문환경); the village road whose width is about 4 meters is forming a flow system forking off into three. There is a route bus which operates three times a day even into the inside of the village. The main sources of revenue are vegetables in facilities, fruits and floriculture. Their average revenue is about 10.5 million won. 3. Here in DaeSan Village a legend dealing with Teasan literally meaning a big mountain consist of th village's tradition and you can see the tombs of a very faithful son and Anwi an army general in the age of the Japanese Invasion of Korea of 1592 to 1598 inside the village. 4. 85 out of the eitire population 141 whose age are over 20 showed very positive attitudes in a questionnaire about, making the village a cultural one and its development. 5. The basic of planned ideas is to increase the revenue of the farming household by making the village a professional farming one which has a state-of the-art production facility and agricultural technique. It is to make the village the one where people can enjoy the sense of the rural life and the farmer can enjoy their lives through consumptive and consistant leisure and resting activities. 6. We are planning to make entrance space, life space, rest and sport space, and cultural space considering the characteristics of the village and the demand of the resident. We are also planning to make tile entire city of Kimje an information transmitting base in short and long term perspectives. 7. DaeSan Village was planned as a place where tradition and the future exist together. On the basis of this concept we planned future programs for Daesan Village and in the latter part of the study master plans and detail plans will be continued.the regional agricultural condition. The development permissions were only during the period of restricted to use ($1979.12{\sim}1993.11$). We propose that the authority of development permission should be given to the local autonomy government, because the local government has the knowledge of its individual agricultural conditions.

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