• Molecules and Cells
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• v.22 no.2
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• pp.220-227
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• 2006

Oxidative alteration of mitochondrial cytochrome c has been linked to disease and is one of the causes of proapoptotic events. We have investigated the modification of cytochrome c by $H_2O_2$. When cytochrome c was incubated with $H_2O_2$, oligomerization of the protein increased and the formation of carbonyl derivatives and dityrosine was stimulated. Radical scavengers prevented these effects suggesting that free radicals are implicated in the $H_2O_2$-mediated oligomerization. Oligomerization was significantly inhibited by the iron chelator, deferoxamine. During incubation of deoxyribose with cytochrome c and $H_2O_2$, damage to the deoxyribose occurred in parallel with the release of iron from cytochrome c. When cytochrome c that had been exposed to $H_2O_2$ was analyzed by amino acid analysis, the tyrosine, histidine and methionine residues proved to be particularly sensitive. These results suggest that $H_2O_2$-mediated cytochrome c oligomerization is due to oxidative damage resulting from free radicals generated by a combination of the peroxidase activity of cytochrome c and the Fenton reaction of free iron released from the oxidatively-damaged protein.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.241-242
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• 2022

Recently, related studies on the application of bacterial spores to self-healing concrete have been widely reported. Using the self-healing method of bacterial spores as a kind of pro-environment, the green method is very attractive, but because the living environment of bacterial spores is relatively harsh, it is necessary to have a way to separate the living environment of bacterial spores from the harsh external environment, And release bacterial spores when needed. Therefore, capsules are widely used in self-healing concrete. To enhance the self-healing effect, the capsules need to be evenly distributed in the concrete. Furthermore, we develop a CIP-based smart capsule with controllability. We determined the magnetic force of each capsule by mixing CIP in resin, then mass-fabricating the capsules for self-healing by a microfluidic method, and by measuring the kinetic distance of the capsules containing different amounts of cip under the action of a magnetic field strength. The results show that with the increase of the amount of cip, the active distance of the capsule also increases. When the cip is 8wt%, the active distance reaches 1.75cm. We believe this research can provide momentum for the development of self-healing capsule applications.

• Journal of the Korean Chemical Society
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• v.19 no.6
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• pp.454-462
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• 1975

The photodegradation of polystyrene and polyethylene was studied utilizing several additives to promote photooxidation. Polymer films with small amount of additives were irradiated with ultraviolet lamps in Rayonet Photochemical Reactor. The progress of photodegradation was followed by measuring the intensities of carbonyl and hydroxyl stretching bands in infrared spectra as well as the viscosity changes. It was found that the increase of carbonyl or hydroxyl peaks was proportional to the decrease of the molecular weight of polymers under study. Iron(II, III) complexes of dithiocarbamate and their analogs showed good results.

• Journal of the Korean Society for Precision Engineering
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• v.21 no.8
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• pp.34-42
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• 2004

A new polishing technique for three dimensional micro/meso-scale parts is suggested using a micro quill and a magnetic chain structure. The principle of this method is to polish the target surface with the collected magnetic brushes at a micro tool by the non-uniform magnetic field generated around the tool. In a typical magnetic abrasive finishing process magnetic particles and abrasive particles are unbonded each other. But, to finish the three dimensional small parts bonded magnetic abrasive have to be used. Bonded magnetic abrasives are made from direct bonding, and their polishing characteristics are also examined. Alumina, silicon carbide and diamond micro powders are used as abrasives. Base metal matrix is carbonyl iron powder. It is found that bonded magnetic abrasives are superior to unbonded one by experiment. finally, the polished surface roughness is evaluated by atomic force microscope.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2007.05a
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• pp.1137-1141
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• 2007

This paper is concerned with the experimental research of magnetorheological elastomers (MREs). The modulus of the MR elastomers can be controlled by an applied magnet field, so that it can be effectively used for vibration suppression applications. The MR elastomer in this experiment is a mixture of KE-1300 silicone, carbonyl iron powder (300mesh) and a silicone hardener (CAT-1300). Three specimens were manufactured and tested by using the vibration testing instruments. The magnetic field was generated by the permanent magnets. The experimental results show that the natural frequencies of the test article with MR elastomer changes by the applied magnetic field. The performance of the MR elastomer can be increased by stronger magnetic fields. This is under investigation.

• Smart Structures and Systems
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• v.5 no.5
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• pp.517-529
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• 2009

This paper presents the development of a new Adaptive Tuned Dynamic Vibration Absorber (ATDVA) working with magnetorheological elastomers (MREs). The MRE materials were fabricated by mixing carbonyl iron particles with silicone rubber and cured under a strong magnetic field. An ATDVA prototype using MRE as an adaptable spring was designed and manufactured. The MRE ATDVA worked in a shear mode and the magnetic field was generated by a magnetic circuit and controlled through a DC power supply. The dynamic performances or the system transmissibility at various magnetic fields of the absorber were measured by using a vibration testing system. Experimental results indicated that this absorber can change its natural frequency from 35Hz to 90Hz, 150% of its basic natural frequency. A real time control logic is proposed to evaluate the control effect. The simulation results indicate that the control effect of MRE ATDVA can be improved significantly.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.1832-1835
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• 2003

This paper suggests the selective ultra precision polishing techniques for micro die and mold parts using magnetic-assisted machining. Fabrication of magnetic abrasive particle and their polishing performance are key technology at ultra precision polishing process of micro parts. Conventional magnetic abrasives have disadvantages. which are missing of abrasive particle and inequality between magnetic particle and abrasive particle. So, bonded magnetic abrasive particles are fabricated by several method. For example, plasma melting and direct bonding. Ferrite and carbonyl iron powder are used as magnetic particle where silicon carbide and Al$_2$O$_3$ are abrasive particle. Developed particles are analyzed using measurement device such as SEM. Possibility of magnetic abrasive and polishing performance of this magnetic abrasive particles also have been investigated. After polishing, surface roughness of workpiece is reduced from 2.927 $\mu\textrm{m}$ Rmax to 0.453 $\mu\textrm{m}$ Rmax.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.557-560
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• 2003

Magnetorheological finishing(MRF) is a newly developed and recently commercialized for finishing optical components. The magnetorheological fluid consists of a water based suspension of carbonyl iron, nonmagnetic polishing abrasives, and small amounts of stabilizer. This magnetorheological fluid is pumped from conditioner on the rotating wheel and suctioned back to the conditioner, where it cooled to setpoint temperature and evaporative losses are replaced. This method could produce some problems in suction. So newly designed MRF tools is proposed in which MR fluid is not circulated and conditioned by the slurry. The new polishing mechanism is experimented. Measured surface roughness supports the validity of this mechanism.

• Korea-Australia Rheology Journal
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• v.18 no.3
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• pp.121-126
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• 2006

A carbonyl iron-based magneto-rheological suspension was compressed in the direction of the applied magnetic field and the change in rheological properties was measured. It was found that the compression did not have a large effect on the magneto-rheological response, which is in contrast to recent reports in the literature describing an almost order of magnitude increase in the shear yield stress. The difference can be attributed to the latter test's use of a sliding wedge apparatus which imparts considerable shearing to the sample during the compression.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2008.04a
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• pp.753-753
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• 2008

Magneto-rheological elastomers(MRE) are similar to magnetorheological fluids. Thus, rheological properties of MRE can be also controlled by an applied magnetic field. The MRE in this experiment is a mixture of natural rubber(NR), carbonyl iron powder(CIP), ZnO, and sulfur. Three specimens were prepared and tested by using the vibration testing instruments. The magnetic field was generated by the electromagnets. Natural frequencies of the oscillator were changed by the applied magnetic field. The properties of the MRE were increased due to magnetic field strength.