• Title/Summary/Keyword: Carbon-free

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Impact Behaviors of Ni-plated Carbon Fibers-reinforced Epoxy Matrix Composites (니켈도금된 탄소섬유 강화 에폭시 수지 복합재료의 충격 특성)

  • 박수진;김병주;이종문
    • Polymer(Korea)
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    • v.27 no.1
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    • pp.52-60
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    • 2003
  • In this work, two types of Ni-plating, namely electrolytical and electroless Ni-platings on carbon fiber surfaces, were carried out to enhance the impact resistance of composites. And the comparison between electrolytical and electroless methods on their impact properties of composite system was studied. The surface properties of carbon fibers were characterized using XRD, SEM, and contact angle measurements. The impact behaviors were investigated using an Izod type impact tester. As experimental results, it was observed that electrolessly plated Ni layers had Ni-P alloys on carbon fiber surfaces as revealed by XRD, and electrolytically Ni-plated carbon fibers showed higher surface free energies than those of the electrolessly Ni-plated carbon fibers. In particular, the impact strengths of electrolessly Ni-plated carbon fibers-reinforced plastics were strongly increased. These results were probably due to the difference of wettabilities according to the different types of Ni-plating methods.

Programmed Conditions of Supplying Carbon Dioxide to Keep its Desired Concentration in Kimchi Container (김치용기에서의 이산화탄소 농도 제어를 위한 주입 프로그램 조건 설정)

  • An, Duck Soon;Jo, Min Gyeong;Park, Su Yeon;Lee, Dong Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.25 no.2
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    • pp.31-35
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    • 2019
  • Kimchi is a refreshing sour food which gives sour and carbonic acid taste of carbon dioxide produced during the fermentation process. So, carbon dioxide injection was tried to raise carbonic acid taste of kimchi stored in the airtight container. First, carbon dioxide injection times of a given gas supply system were determined experimentally to attain initial concentration of 80% for different solid/liquid ratios. Since carbon dioxide is dissolved in kimchi to decrease its concentration during storage, periodical carbon dioxide injection conditions were needed and determined to keep the $CO_2$ concentration above 70%. For the initial flushing to 80% $CO_2$ concentration in model system filled with water, the injection time ranged from 40 to 89 seconds for free volumes of 2-8 L. $CO_2$ injection conditions for the under-ripened storage at $10^{\circ}C$ consisted of longer time at more frequent cycles for watery kimchi than for Chinese cabbage kimchi. At $0^{\circ}C$ of subsequent ripened stage storage of watery kimchi, the periodical injection at 3 hour interval was required because of continuous dissolution of carbon dioxide. However, Chinese cabbage kimchi did not require subsequent $CO_2$ injection during the ripened state storage and needed only flushing to 80% $CO_2$ at time of the container opening and closing. These results can be used as basic information for the programmed control of $CO_2$ injection in the kimchi container system.

RBSC Prepared by Si Melt Infiltration into the Y2O3 Added Carbon Preform (Y2O3 첨가 탄소 프리폼에 Si 용융 침투에 의해 제조한 반응 소결 탄화규소)

  • Jang, Min-Ho;Cho, Kyeong-Sik
    • Journal of Powder Materials
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    • v.28 no.1
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    • pp.51-58
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    • 2021
  • The conversion of carbon preforms to dense SiC by liquid infiltration is a prospectively low-cost and reliable method of forming SiC-Si composites with complex shapes and high densities. Si powder was coated on top of a 2.0wt.% Y2O3-added carbon preform, and reaction bonded silicon carbide (RBSC) was prepared by infiltrating molten Si at 1,450℃ for 1-8 h. Reactive sintering of the Y2O3-free carbon preform caused Si to be pushed to one side, thereby forming cracking defects. However, when prepared from the Y2O3-added carbon preform, a SiC-Si composite in which Si is homogeneously distributed in the SiC matrix without cracking can be produced. Using the Si + C → SiC reaction at 1,450℃, 3C and 6H SiC phases, crystalline Si, and Y2O3 were generated based on XRD analysis, without the appearance of graphite. The RBSC prepared from the Y2O3-added carbon preform was densified by increasing the density and decreasing the porosity as the holding time increased at 1,450℃. Dense RBSC, which was reaction sintered at 1,450℃ for 4 h from the 2.0wt.% Y2O3-added carbon preform, had an apparent porosity of 0.11% and a relative density of 96.8%.

Effect of Y2O3 Additive Amount on Densification of Reaction Bonded Silicon Carbides Prepared by Si Melt Infiltration into All Carbon Preform (완전 탄소 프리폼으로부터 Si 용융 침투에 의해 제조한 반응 소결 탄화규소의 치밀화에 미치는 Y2O3 첨가량의 영향)

  • Cho, Kyeong-Sik;Jang, Min-Ho
    • Korean Journal of Materials Research
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    • v.31 no.5
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    • pp.301-311
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    • 2021
  • The conversion of all carbon preforms to dense SiC by liquid infiltration can become a low-cost and reliable method to form SiC-Si composites of complex shape and high density. Reactive sintered silicon carbide (RBSC) is prepared by covering Si powder on top of 0.5-5.0 wt% Y2O3-added carbon preforms at 1,450 and 1,500℃ for 2 hours; samples are analyzed to determine densification. Reactive sintering from the Y2O3-free carbon preform causes Si to be pushed to one side and cracking defects occur. However, when prepared from the Y2O3-added carbon preform, an SiC-Si composite in which Si is homogeneously distributed in the SiC matrix without cracking can be produced. Using the Si + C = SiC reaction, 3C and 6H of SiC, crystalline Si, and Y2O3 phases are detected by XRD analysis without the appearance of graphite. As the content of Y2O3 in the carbon preform increases, the prepared RBSC accelerates the SiC conversion reaction, increasing the density and decreasing the pores, resulting in densification. The dense RBSC obtained by reaction sintering at 1,500 ℃ for 2 hours from a carbon preform with 2.0 wt% Y2O3 added has 0.20 % apparent porosity and 96.9 % relative density.

The effects of stiffness strengthening nonlocal stress and axial tension on free vibration of cantilever nanobeams

  • Lim, C.W.;Li, C.;Yu, J.L.
    • Interaction and multiscale mechanics
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    • v.2 no.3
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    • pp.223-233
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    • 2009
  • This paper presents a new nonlocal stress variational principle approach for the transverse free vibration of an Euler-Bernoulli cantilever nanobeam with an initial axial tension at its free end. The effects of a nanoscale at molecular level unavailable in classical mechanics are investigated and discussed. A sixth-order partial differential governing equation for transverse free vibration is derived via variational principle with nonlocal elastic stress field theory. Analytical solutions for natural frequencies and transverse vibration modes are determined by applying a numerical analysis. Examples conclude that nonlocal stress effect tends to significantly increase stiffness and natural frequencies of a nanobeam. The relationship between natural frequency and nanoscale is also presented and its significance on stiffness enhancement with respect to the classical elasticity theory is discussed in detail. The effect of an initial axial tension, which also tends to enhance the nanobeam stiffness, is also concluded. The model and approach show potential extension to studies in carbon nanotube and the new result is useful for future comparison.

Ultimate Strength of Composite Laminates with Free-Edge Delamination (자유단 충간분리를 갖는 복합재 적층판의 최종 파괴강도)

  • 양광영;윤성운;김재열
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.11 no.2
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    • pp.59-64
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    • 2002
  • This paper presets experimental and analytical studies of ultimate strength of [$[30_2/-30_2/90]_S$ carbon/epoxy laminates with free-edge delamination under uniaxial tension. We performed tensile teat far laminates with Telflon inserted on interfaces to simulate initial free-edge delamination, The experiment reveals that extensional stiffness of the laminate decreases by the initiation of the delamination, and that strength of the laminate without delamination is smaller than that of the laminates with delamination. Generalized quasi-three delamination finite element analysis, which employs energy release rate and maximum stress criteria, predicts the ultimate strength of the laminates with sufficient accuracy.

Design approach for a FRP structural formwork based steel-free modular bridge system

  • Cheng, Lijuan;Karbhari, Vistasp M.
    • Structural Engineering and Mechanics
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    • v.24 no.5
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    • pp.561-584
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    • 2006
  • The paper presents results of parametric studies, and an overall approach for the design of a modular bridge system which incorporates a steel-reinforcement free concrete slab cast on top of carbon FRP stiffened deck panels which act as both structural formwork and flexural reinforcement, spanning between hollow box type FRP girders. Results of the parametric studies are highlighted to elucidate important relationships between critical configurational parameters and empirical equations based on numerical studies are presented. Results are discussed at the level of the individual deck and girder components, and as a slab-on-girder bridge system. An overall design methodology for the components and bridge system including critical performance checks is also presented.

3-D Vibration analysis of FG-MWCNTs/Phenolic sandwich sectorial plates

  • Tahouneh, Vahid
    • Steel and Composite Structures
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    • v.26 no.5
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    • pp.649-662
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    • 2018
  • In this study, based on the three-dimensional theory of elasticity, free vibration characteristics of sandwich sectorial plates with multiwalled carbon nanotube-(MWCNT)-reinforced composite core are considered. Modified Halpin-Tsai equation is used to evaluate the Young's modulus of the MWCNT/epoxy composite samples by the incorporation of an orientation as well as an exponential shape factor in the equation. The exponential shape factor modifies the Halpin-Tsai equation from expressing a straight line to a nonlinear one in the MWCNTs wt% range considered. In this paper, free vibration of thick functionally graded sandwich annular sectorial plates with simply supported radial edges and different circular edge conditions including simply supported-clamped, clamped-clamped, and free-clamped is investigated. A semi-analytical approach composed of two-dimensional differential quadrature method and series solution are adopted to solve the equations of motion. The material properties change continuously through the core thickness of the plate, which can vary according to a power-law, exponentially, or any other formulations in this direction. This study serves as a benchmark for assessing the validity of numerical methods or two-dimensional theories used to analysis of laminated sectorial plates.

Ag Nanowires와 혼합물을 이용한 ITO-free 유기태양전지 연구

  • Jang, So-Ra;Yang, Hye-Jin;Go, Geum-Jin;Choe, Cheol-Ho;Choe, Ju-Hwan;Sin, Jin-Guk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.467.2-467.2
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    • 2014
  • 유기태양전지는 친환경 에너지 소스로써 저가 대량 생산이 가능하고 특히 유연한 기판에 적용이 가능하여 많은 관심을 받고 있다. 그럼에도 불구하고 기존에 사용되는 indium tin oxide (ITO)의 사용으로 인한 유연성 부족으로 대체되는 투명전극의 개발이 요구되어지고 있다. 이로 인해 carbon nanotubes, graphene, thin metals, metal grids, and conducting polymers 등이 연구되고 있으며, 이중 Silver nanowires (Ag NWs)를 이용한 방식도 많은 관심과 함께 전기광학적 특성에 대한 연구가 진행되고 있다. 하지만 유기전자소자에 사용되기에는 몇 가지 문제점이 발생하는데 이를 해결하기 위한 노력이 다양하게 이루어지고 있다. 특히 다양한 물질의 혼합을 통해 개선하고자 하는 노력이 증가하고 있는데 적층구조의 전도성필름 형성을 통해 ITO-free OPVs에서 Ag nanowire를 transparent conductive electrodes로 활용하였다. Ag NWs층과 PEDOT:PSS layer의 복합화를 통해 저가의 ITO-free OPVs용 transparent anodes가 가능해졌다.

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