• Journal of Adhesion and Interface
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• v.11 no.2
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• pp.76-83
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• 2010

The extensive use of fossil resources over the past century resulted in dwindling supply and surging price of oil and it is strongly suspected that irreversible global climate change might be due to carbon dioxide emitted from combustion of fossil carbons. With this regard, much attention is recently paid to renewable and sustainable resources as alternatives to petroleum. In this review, we considered a range of efforts to replace petroleum-derived chemicals, particularly adhesive materials with renewable and sustainable plant-based biomass feedstock.

• Environmental Engineering Research
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• v.23 no.3
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• pp.301-308
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• 2018

We investigated simultaneous removal of heavy metals such as Cr, Ni, and Zn by adsorption onto powdered activated carbon (PAC) and PAC modified with sodium diethyldithiocarbamate (PAC-SDDC). Modification of PAC was confirmed by Fourier transform infrared spectroscopy and Scanning electron microscopy and energy dispersive X-ray spectroscopy. Both PAC and PAC-SDDC reached adsorption equilibrium within 48 h, and the adsorption kinetics followed a pseudo-second order reaction kinetics. The removal of metals was enhanced with increasing both adsorbent dosage and followed the descending order of Cr > Ni > Zn for PAC and Cr > Zn > Ni for PAC-SDDC, respectively. Adsorption kinetics followed pseudo-second order kinetics. Adsorption kinetic results were well fitted by the Freundlich isotherm except for Cr adsorption onto PAC. The optimum pH for heavy metal adsorption onto PAC was 5, whereas that for PAC-SDDC ranged from 7 to 9, indicating that modification of PAC with SDDC significantly enhanced heavy metal adsorption, especially under neutral and alkaline pH conditions. Our results imply that SDDC modified PAC can be applied to effectively remove heavy metals especially Cr in plating wastewaters without adjusting pH from alkaline to neutral.

• Journal of Korean Society of Water and Wastewater
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• v.37 no.6
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• pp.335-345
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• 2023

In Korea, as part of the Green New Deal project toward a carbon-neutral society, it is necessary to build a climate-resilient urban environment to green the city, space, and living infrastructure. To this end, SWMM-ING was improved and the model was modified to analyze the carbon reduction effect. In addition, I plan to select target watersheds where urbanization is rapidly progressing and evaluate runoff, non-point pollution, and carbon reduction effects to conduct cost estimation and optimal design review for domestic rainwater circulation green infrastructure. In this study, green infrastructure facilities were selected using SWMM-ING. Various scenarios were presented considering the surface area and annual cost of each green infrastructure facility, and The results show that the scenario derived through the APL2 method was selected as the optimal scenario. In this optimal scenario, a total facility area of 190,517.5 m² was applied to 7 out of 30 subwatersheds to achieve the target reduction. The target reduction amount was calculated a 23.50 % reduction in runoff and a 26.99 % reduction in pollutant load. Additionally, the annual carbon absorption was analyzed and found to be 385,521 kg/year. I aim to achieve additional carbon reduction effects by achieving the goal of reducing runoff and non-point pollution sources and analyzing annual carbon absorption. Moreover, considering the scale-up of these interventions across the basin, it is believed that an objective assessment of economic viability can be conducted.

• Proceedings of the Korean Vacuum Society Conference
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• 2007.08a
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• pp.76-76
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• 2007

• Journal of Korean Society of Environmental Engineers
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• v.34 no.6
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• pp.382-390
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• 2012

Global warming has been hot issue world wide. Korea has been dealing with the global issue under the slogan of low carbon and green-growth such as setting national greenhouse gas (GHG) reduction targets and allocation to each industrial sector. Infrastructure construction, in which enormous social overhead capital (SOC) is input, has great role as one of the actions. Road is one of the representative infrastructure and large amount of resources is utilized in its construction, operation and maintenance stage. The estimation methodology of life cycle carbon emissions was developed and applied to a case study of highway currently under construction in this study. Also, total carbon emissions of all the highway in South Korea at present (2009) and cumulative carbon emissions from 2009 to 2020 were estimated using the results of case study.

• Journal of the Korean Chemical Society
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• v.26 no.1
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• pp.7-17
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• 1982

In order to predict substituent and Lewis acid effects on the regiospecificity of the Diels-Alder reaction, and to investigate the competition for the complexation of Lewis acid between diene and dienophile, frontier orbital theory has been applied to thermal and catalyzed Diels-Alder reaction by means of CNDO/2 MO method. It has been found that: (1) Lewis acid coordinated preferentially with diene rather than dienophile when carbonyl oxygen of acetoxy substituted diene had larger negative atomic charges than that of dienophile. (2) Most of the reaction were neutral electron demand type, and hence 4-C, 2-C and quantitative secondary orbital interacion methods were generally in good accord with experiments. (3) Sulfur activated the adjacent terminal carbon atom greatly to increase diene LUMO-dienophile HOMO interaction through vacant-d-orbital participation, and played an important role in controlling regioselectivity of neutral electron demand reaction type.

• Journal of the Korean Electrochemical Society
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• v.26 no.4
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• pp.56-63
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• 2023

The development of renewable energy technologies, such as solar, wave, and wind power, has led to the diversification of water electrolysis technologies, which can be easily coupled with renewable energy sources in terms of economics and scale. Water electrolysis technologies can be classified into three types based on operating temperature: low-temperature (<100 ℃), medium-temperature (300-700 ℃), and high-temperature (>700 ℃). It can also be classified by the type of electrolyte membrane used in the system. However, the concepts of thermodynamic and thermo-neutral voltages calculations and are very important factors in the evaluation of energy consumption and efficiency of water electrolysis technologies, are often confused. This review aims to contribute to a better understanding of the calculation of operating voltage and efficiency of PEM water electrolysis technologies and to clarify the differences between thermodynamic voltage and thermo-neutral voltage.

• Journal of Environmental Science International
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• v.28 no.3
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• pp.321-328
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• 2019

This study aimed to analyze the growth and physical responsees of Dracaena braunii in response salt accumulation in ornamental water culture and to examine the effect of activated carbon on this growth response. The experiment was conducted in a plant growth chamber and the indoor environmental conditions of the chamber were set at $23{\pm}1^{\circ}C$ temperature, $70{\pm}3%$ humidity, and 1,000 lux brightness. The observation of the growth response of plants in the presence of activated carbon showed that the pH with activated carbon maintained sub-acidic to neutral (6.27~7.32) conditions and showed decreased electric conductivity in the media. As the treatment with added activated carbon showed good growth and physical responses, this indicated that absorption effect of activated carbon had a positive influence on the growth of plants. However, as the absorption effect of activated carbon may decrease over time and the use of high concentrations of activated carbon might cause nutrition shortage, various concentration of activated carbon and their absorption effects need to be investigated in the future.

• Journal of Environmental Impact Assessment
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• v.31 no.6
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• pp.465-474
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• 2022

In order to achieve carbon neutrality, it is necessary to commercialize and popularize carbon dioxide capture technology, so the purpose of this study is to put forward the design of public facilities suitable for public environment. In the design direction of public facilities for carbon capture and environmental purification, the application of carbon capture technology in air, the application of carbon capture and adsorption materials, and carbon reduction recycling are selected for development. In order to achieve carbon neutrality, this study develops a new concept of public facility design which is different from the existing public facilities in public space. From this point of view, it has great enlightenment significance. Public facilities adopting carbon-neutral technology are environmentally friendly public facilities that conform to the times, and can be installed in parks, roads and other spaces. With the rest of citizens and the role of communities, it is expected to contribute to popularization and activation.

• Atmosphere
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• v.31 no.5
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• pp.625-635
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• 2021

South Korea established the 2050 Carbon Neutral Plan in response to the climate crisis, and to achieve this policy, it is very important to monitor domestic carbon emissions and atmospheric carbon concentration. Both CO₂ and CO are emitted from fossil fuel combustion processes, but the relative ratios depend on the combustion efficiency and the strength of local emission regulations. In this study, the relationship between CO₂ and CO was analyzed using ground observation data for the period of 2018~2020 at Anmyeon-do site and the CO/CO₂ ratio according to regional origin during high CO₂ cases was investigated based on the footprint simulated from Stochastic Time-Inverted Lagrangian Transport (STILT) model. CO₂ and CO showed a positive correlation with correlation coefficient of 0.66 (p < 0.01), and averaged footprints during high CO₂ cases confirmed that air particles mainly originated from eastern and north-eastern China, and inland of Korean Peninsula. In addition, it was revealed that among the cases of high CO₂ concentration, when the CO/CO₂ ratio is high, the industrial area of eastern China is greatly affected, and when the ratio is low, the contribution of the domestic region is relatively high. The ratio of CO₂ and CO in this study is significant in that it can be used as a useful factor in determining the possibility of domestic and foreign origins of climate pollutants.