• Korean Chemical Engineering Research
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• v.54 no.1
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• pp.16-21
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• 2016

Silicon/Carbon/CNT composites as anode materials for lithium-ion batteries were synthesized to overcome the large volume change during lithium alloying-de alloying process and low electrical conductivity. Silicon/Carbon/CNT composites were prepared by the fabrication processes including the synthesis of SBA-15, magnesiothermic reduction of SBA-15 to obtain Si/MgO by ball milling, carbonization of phenolic resin with CNT and HCl etching. The prepared Silicon/Carbon/CNT composites were analysed by XRD, SEM, BET and EDS. In this study, the electrochemical effect of CNT content to improve the capacity and cycle performance was investigated by charge/discharge, cycle, cyclic voltammetry and impedance tests. The coin cell using Silicon/Carbon/CNT composite (Si:CNT=93:7 in weight) in the electrolyte of $LiPF_6$ dissolved in organic solvents (EC:DMC:EMC=1:1:1 vol%) has better capacity (1718 mAh/g) than those of other composition coin cells. The cycle performance of coin cell was improved as CNT content was increased. It is found that the coin cell (Si:CNT=89:11 in weight) has best capacity retension (83%) after 2nd cycle.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.11
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• pp.1887-1894
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• 2001

The effects of carbon black on the material properties and the fatigue life of the carbon-black filled natural rubbers were investigated. Different kinds of carbon blacks resulted in different fatigue lives, hysteresis, and critical J-values. It was noticed that the hysteresis was inversely proportional to the difference between DBPA and CTAB, and the critical J-value was almost the same regardless of the length of a precrack. In addition, different kinds of carbon blacks resulted in different fracture morphologies, and micro-scale and macro-scale roughnesses. The critical J-value was proportional to the micro-scale roughness. and it seemed relate to the size distribution of carbon black particles. By reviewing all the experimental data. it was finally noticed that the logarithmic value of the fatigue life could be linearly expressed by a multiplication of the critical J-value and the logarithmic value of the hysteresis.

• Journal of Information Technology Services
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• v.11 no.4
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• pp.123-134
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• 2012

Recently, The Bali Road Map was approved, as it demands that developing countries should also have the responsibility of greenhouse gas reduction from 2013. This suggests that the greenhouse gas and environment should be controlled across industry sectors. Accordingly, this study was conducted to identify the application and effects of the IT convergence technology to the smart farm and realize the low-carbon green industry in Korea. The smart farm technologies within and outside of Korea were comparatively analyzed for the low-carbon green industry policy. The study subjects were determined to propose the necessity of the study efficiently. First, the studies on the smart farm for low-carbon green industry policy were examined. Second, the suitable IT technology for the smart farm as well as the effect and the improvement plan of the IT technology-based smart farm system were examined. This study now aims to promote the low-carbon green industry policy and IT convergence technology and job creation. These will be achieved by providing the plan for linking the system simulator organization with the low-carbon green industry policy.

• Carbon letters
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• v.11 no.1
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• pp.38-40
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• 2010

Carbon supported electrocatalysts are commonly used as electrode materials for polymer electrolyte membrane fuel cells(PEMFCs). These kinds of electrocatalysts provide large surface area and sufficient electrical conductivity. The support of typical PEM fuel cell catalysts has been a traditional conductive type of carbon black. However, even though the carbon particles conduct electrons, there is still significant portion of Pt that is isolated from the external circuit and the PEM, resulting in a low Pt utilization. Herein, new types of carbon materials to effectively utilize the Pt catalyst are being evaluated. Carbon nanofiber/activated carbon fiber (CNF/ACF) composite with multifunctional surfaces were prepared through catalytic growth of CNFs on ACFs. Nickel nitrate was used as a precursor of the catalyst to synthesize carbon nanofibers(CNFs). CNFs were synthesized by pyrolysising $CH_4$ using catalysts dispersed in acetone and ACF(activated carbon fiber). The as-prepared samples were characterized with transmission electron microscopy(TEM), scanning electron microscopy(SEM). In TEM image, carbon nanofibers were synthesized on the ACF to form a three-dimensional network. Pt/CNF/ACF was employed as a catalyst for PEMFC. As the ratio of prepared catalyst to commercial catalyst was changed from 0 to 50%, the performance of the mixture of 30 wt% of Pt/CNF/ACF and 70wt% of Pt/C commercial catalyst showed better perfromance than that of 100% commercial catalyst. The unique structure of CNF can supply the significant site for the stabilization of Pt particles. CNF/ACF is expected to be promising support to improve the performance in PEMFC.

• Corrosion Science and Technology
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• v.16 no.4
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• pp.175-182
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• 2017

Galvanic current measurement, polarization curves, electrochemical impedance spectroscopy and weight loss test were used to study the corrosion behavior of carbon steel before and after carbon fibers coupling to the carbon steel in simulated concrete pore solutions, and the film composition on the steel surface was analyzed using XPS method. The results indicate that passive film on steel surface had excellent protective property in pore solutions with different pH values (13.3, 12.5 and 11.6). After coupling with carbon fibers (the area ratio of carbon steel to carbon fiber was 12.31), charge transfer resistance $R_{ct}$ of the steel surface decreased and the $Fe^{3+}/Fe^{2+}$ value in passive film decreased. As a result, stability of the film decreased and the corrosion rate of steel increased. Decreasing of the area ratio of steel to carbon fiber from 12.3 to 6.15 resulted in the decrease in $R_{ct}$ and the increase in corrosion rate. Especially in the pore solution with pH 11.6, the coupling leads the carbon steel to corrode easily.

• Journal of Environmental Science International
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• v.22 no.11
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• pp.1509-1517
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• 2013

So far, most studies associated with soil carbon sequestration have been focused on long term aspect. However, information regarding soil carbon sequestration in short term aspect is limited. This study was conducted to determine changes of soil organic carbon content and stability of carbon in response to compost application rate and tillage management during rice growing season(150 days) in short term aspect. Under pot experiment condition, compost was mixed with an arable soil at rates corresponding to 0, 6, 12, and 24 Mg/ha. To determine effect of tillage on soil carbon sequestration, till and no-till treatments were set up in soils amended with application rate of 12 Mg/ha. Compost application and tillage management did not significantly affect soil organic carbon(SOC) content in soil at harvest time. Bulk density of soil was not changed significantly with compost application and tillage management. These might result from short duration of experiment. While hot water extractable organic carbon(HWEOC) content decreased with compost application, humic substances(HS) increased. Below ground biomass of rice increased with application of compost and till operation. From the above results, continuos application of compost and reduce tillage might improve increase in soil organic carbon content and stability of carbon in long term aspect.

• Asian Journal of Innovation and Policy
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• v.11 no.1
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• pp.1-29
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• 2022

Climate action is at the top of the agenda in the international community, as demonstrated at the 2021 G7 Summit and the 2021 UN Climate Summit. Major developed countries are scrambling to make a transition to a green economy and create a new growth momentum. Following the Paris Climate Agreement in 2016, they focus on "carbon neutrality" as an effective means of tackling climate change. The Republic of Korea, a high-carbon economy, submitted its second Nationally Determined Contribution and announced carbon neutrality as a top policy priority. Accordingly, the country increases government budget in research and development (R&D) and science and technology (S&T) policies. Against this backdrop, this study analyzed policies on carbon-neutral S&T and R&D in major advanced countries. The analysis was made by identifying globally pending issues in carbon-neutral policies and climate technology. In addition, focus group interviews were conducted six times with 10 experts to come up with three R&D strategies and action plans for government-funded research institutes to achieve carbon neutrality. To be specific, the following measures were suggested. First, creative and innovative R&D programs are required to solve the problem of carbon emissions. Second, it is necessary to establish carbon neutrality policies and infrastructure which are sustainable to run and manage. Third, it is crucial to promote cooperation in climate technology based on excellence. In conclusion, the strategies proposed in this study are expected to provide directions and implications for policymakers, researchers, and scholars in science and technology to develop effective strategies to achieve national carbon neutrality.

• Journal of Environmental Science International
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• v.31 no.11
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• pp.951-958
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• 2022

The aim of this study was to determine the optimum level of carbon dioxide to maximize the quality and yields of strawberries cultivated in a greenhouse. Specifically, two strawberry cultivars, namely, 'Seolhyang' and 'Maehyang', were subjected to varying concentrations of carbon dioxide and patterns linked to their productivity were noted. Both cultivars showed improvements across various physical variables (i.e., leaf area, crown diameter, plant height, fresh weight, and dry weight) when carbon dioxide concentrations were at 1,500 ppm. The optimum carbon dioxide concentration for increased fruit yields and quality was 1,000 ppm. When carbon dioxide was at 1,000 ppm the yields of 'Seolhyang' and 'Maehyang' increased by 1.99 and 1.78 times, respectively, compared to control plants. The influence of carbon dioxide on fruit color was negligible. However, the carbon dioxide increased the sugar content and sugar-acid ratio of the experimental fruits compared to control plants. Specifically, the sugar-acid ratio, which is directly related to taste, was at its highest when the concentration of carbon dioxide was at 1,000 ppm (i.e., for both 'Seolhyang' and 'Maehyang'). Overall, the application of carbon dioxide culminated in improved yields and fruit quality for both cultivars of interest.

• Carbon letters
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• v.15 no.3
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• pp.162-170
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• 2014

Pitch is an attractive raw material for carbon fiber precursors due to its low cost stemming from its availability as a residue of coking and petroleum processes. Ford Motor Company reported a carbon fiber target price of $11.0/kg by using a fast cycle-time manufacturing method with carbon fiber in an inexpensive format, allowing for an average retail price of gasoline of $3.58/gallon. They also recommended the use of carbon fiber with strength of 1700 MPa, modulus of 170 GPa, and 1.5% elongation. This study introduced a ca. $5.5{\mu}m$ carbon fiber with 2000 MPa tensile strength obtained from a precursor through simple distillation of petroleum residue. Petroleum pitch based carbon nanofibers prepared via electrospinning were characterized and potential applications were introduced on the basis of their large specific surface area and relatively high electrical conductivity.

• Carbon letters
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• v.1 no.1
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• pp.12-16
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• 2000

Carbon fiber was reacted with gaseous silicon monoxide which is produced from pack-powder mixture at elevated temperature. As a result of the reaction, two kinds of SiC fiber were obtained. The first one was SiC fibers which were converted from carbon fiber. The fiber is constituted with polycrystal like fine grains or monolithic crystals that have a size from sub-micron to $10\;{\mu}m$. Their size depends on the temperature during the conversion reaction. The second one was ultra-fine SiC fibers that were found on the surface of the converted SiC fibers. The ultra-fine fibers have diameters from 0.08 to $0.2\;{\mu}m$ and their aspect ratio were larger than 100. The chemical composit ion of the ultra-fine fibers was analyzed using an Auger electron spectroscopy. In result, the fibers consist of 51% silicon, 38% carbon and 11% oxygen by weight.