• Title/Summary/Keyword: Carbon yield

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The Effects of Sonic Waves on the Reduction of Aromatic Nitro Groups Using Iron, Hydrazine Hydrate and Activated Carbon (유기 초음파화학. 초음파가 히드라진, 철, 활성탄을 이용한 방향족 니트로기의 환원반응에 미치는 영향)

  • Dae Hyun Shin;Byung Hee Han;Sung Yun Cho
    • Journal of the Korean Chemical Society
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    • v.30 no.1
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    • pp.105-108
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    • 1986
  • Ultrasound(50KHz) accelerated the reduction reaction of aromatic nitro group to aromatic amino group in high yield with mild condition using iron, hydrazine hydrate and activated carbon under room temperature and atmospheric pressure. The activated carbon has been used as a mixing material to highly active metals. However, aromatic nitro group does not reduce at all only with iron-hydrazine witliout adding activated carbon even under ultrasonic irradiation. We also discovered that the conversion yield from nitro group to amino group is directly proportional to the amount of activated carbon.

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Effect of Free Radical Scavenging from Green Tea Extraction using Carbon Dioxide Fluid (이산화탄소 유체를 이용한 녹차의 용매 추출물의 래디칼 소거 기능)

  • Kang Ok-Ju
    • Korean journal of food and cookery science
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    • v.21 no.6 s.90
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    • pp.936-941
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    • 2005
  • Green tea was extracted with different solvents such as hot water, varying concentrations of ethanol and carbon dioxide fluid. The carbon dioxide fluid extraction of green tea was a very effective extraction method in terms of antioxidant yield and stability. At pressure of 125kgf, antioxidant extract of green tea produced a yield 1.87 and 2.8 times higher than hot water and $95\%$ ethanol extract, respectively. Antioxidant extract of carbon dioxide fluid was also very stable during 7-day storage at 35?.

Densification Behavior of C/C Composite Derived from Coal Tar Pitch with Small Amount of Iodine Addition (석탄계 피치에 요오드를 소량 첨가하여 제조한 탄소복합재의 치밀화 거동)

  • Cho, Kwang-Youn;Riu, Doh-Hyung;Shin, Dong-Geun;Joo, Heyok-Jong;Koo, Hyung-Hoi;Park, In-Seo
    • Journal of the Korean Ceramic Society
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    • v.46 no.6
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    • pp.643-647
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    • 2009
  • We investigated the viscosity behavior and the carbon yield of coal tar pitch (CTP) treated with iodine. The viscosity of iodine treated pitch showed that the fluidity of iodine treated CTP did not increase within the iodine addition of 1.4%. DTG analysis showed that cross linking was accelerated at the temperature range from $400\;to\;500{^{\circ}C}$ with iodine treatment, which is due to the accelerated dehydrogenative reaction by iodine. The iodine treatment was mainly effective for β-resin content increase of CTP. The carbon yield of CTP increased from 40 to 60% by the iodine non-treated CTP.

Optimization of Reaction Conditions for High Yield Synthesis of Carbon Nanotube Bundles by Low-Temperature Solvothermal Process and Study of their H2 Storage Capacity

  • Krishnamurthy, G.;Agarwal, Sarika
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3046-3054
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    • 2013
  • Synthesis of Carbon Nanotube bundles has been achieved by simple and economical solvothermal procedure at very low temperature of $180^{\circ}C$. The product yield obtained was about 70-75%. The optimization of reaction conditions for an efficient synthesis of CNTs has been presented. The CNTs are obtained by reduction of hexachlorobenzene in the presence of Na/Ni in cyclohexane. The X-ray diffraction, Fourier transform infrared and Raman spectral studies have inferred us the graphene structure of the products. The CNTs formed as the bundles were viewed on scanning electron microscope, transmission electron microscope and high-resolution transmission electron microscope. These are the multiwalled CNTs with outer diameter of 5-10 nm, the inner diameter 2-4 nm and cross sectional diameter up to 5 nm. Brunauer-Emmett-Teller (BET) based $N_2$ gas adsorption studies have been made to obtain BET surface area and $H_2$ storage capacity. Effect of the experimental variables such as reaction temperature, amount of catalyst and the amount of carbon source were investigated. It is found that they affect significantly on the product nature and yield.

Studies on Fungal Lipids Containing ${\gamma}$-Linolenic Acid 2. Influence of Cultural Conditions on The Production of ${\gamma}$-Linolenic Acid by Mucor sp. (${\gamma}$-Linolenic acid 함유 곰팡이 지질에 관한 연구 2. Mucor sp.의 ${\gamma}$-Linolenic Acid 생산에 미치는 배양조건의 영향)

  • 송근섭;김충기;권용주;양희천;이태규
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.19 no.6
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    • pp.641-645
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    • 1990
  • In order to study the influence of culture conditions on cell growth and lipid formation by Mucor sp, various carbon and nitrogen sources initial pH and C./N ratio of medium were investigated. Glucose was found to be suitable carbon source in terms of lipid yield and ${\gamma}$-linolenic acid(GLA) content. When NH4Cl and (NH4)2SO4 were used as nitrogen source lipid content was high(19-21%) but GLA content was low(15-17%) On the other hand when NaNO3 and KNO3 were used lipid content was low(about 13%) but GLA content was high(22-23%). The highest production of lipid was obtained at a C/N ratio of 40 using glucose and (NH4)2SO4 as carbon and nitrogen source respectively. it was found that lipid yield was high at pH4.6 Also this fungus did not grow at 35$^{\circ}C$ and lipid yield was highr at 15$^{\circ}C$ than $25^{\circ}C$.

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Assessment of Ecosystem services under changing climate in the Bagmati Basin of Nepal

  • Bastola, Shiksha;Seong, Yeon-Jeong;Lee, Sanghyup;Jung, Younghun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.148-148
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    • 2019
  • The 2006 Millennium Ecosystem Assessment (MA) defines ecosystem services (ES) as "the benefits people obtain from ecosystems". Identifying where ES originates, whom it benefits and how it is changing over a period of time is critical in rapidly developing country like Nepal, where the risk of ES loss is high. In the context of various ecosystem services provided by watershed, this study, particularly deals with water yield, Soil loss and Carbon sequestration computation and evaluation in Bagmati Basin of Nepal. As Bagmati Basin incorporates capital city Kathmandu of nepal, land use change is significant over decades and mapping of ES is crucial for sustainable development of Basin in future. In this regard, the objectives of this study are 1) To compute the total and sub-watershed scale water yield of the basin, 2) Computation of soil loss and sediment retention in the basin, and 3) Computation of carbon sequestration in the basin. Integrated Valuation of Environmental Services and Tradeoffs (InVEST), a popular model for ecosystem service assessment based on Budyko hydrological method is used to compute Ecosystem services. The scenario of ES in two periods of time can be referenced for various approaches of prioritization and incorporation of their value into local and regional decision making for management of basin.

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Production of Activated Carbon from Waste Walnut Shell Using Phosphoric Acid and Its Adsorption Characteristics for Heavy Metal Ion (인산활성화제에 의한 폐호도껍질을 원료로 한 활성탄제조 및 이의 중금속 이온 흡착특성)

  • Lee Go-Eun;Ahn Ju-Hyun;Kim Dong-Su
    • Resources Recycling
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    • v.12 no.3
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    • pp.13-24
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    • 2003
  • The production characteristics of activated carbon from waste walnut shell have been investigated by taking activation temperature, activation time, amount of activating agent, and kind of activating agent as the major influential factors. The adsorption capacity of the activated carbon which was produced using phosphoric acid as the activating agent increased with activation temperature and showed its greatest value at about $550^{\circ}C$. Yield for activated carbon was observed to decrease continuously as the activation temperature was raised. The optimal activation time for the highest adsorption capacity was found to be about 2 hr, and as the activation time increased the yield for activated carbon was showed to decrease continuously. The increase in the amount of activating agent resulted in the increase of the yield for activated carbon, however, excessive amount of activating agent deteriorated its adsorption capacity reversely. The variations of the microstructure of activated carbon observed by SEM with several influential factors, correlated very well with its changes in the adsorbability with the same factors and the kind of activating agent was found to play an important role in the determination of the adsorption capacity of activated carbon. To investigate the adsorption characteristics of the produced activated carbon, the adsorption reactions of $Cu^{2+}$ ion were examined using the produced activated carbon as the adsorbent. In general, the kinetics of the adsorption of $Cu^{2+}$ ion was observed to follow a 2nd-order reaction and the rate constant for adsorption reaction increased as the initial concentration of adsorbate was diminished. The equilibrium adsorption of $Cu^{2+}$ was explained well with Freundlich model and its adsorption reaction was found to be endothermic. The activation energy for adsorption was calculated to be 13.07 kcal/mol, which implied that the adsorption reaction was very irreversible, and several thermodynamic parameters of adsorption reaction were estimated using van't. Hoff equation and thermodynamic relationships.

Leveling of Aged Low Carbon Steel Sheets in order to Prevent Shape Defects after Stamping (시효 발생한 저탄소 냉연강판의 가공형상 불량 방지를 위한 판재 교정기술 활용)

  • Park, K. C.
    • Transactions of Materials Processing
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    • v.24 no.4
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    • pp.241-247
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    • 2015
  • In order to prevent shape defects such as fluting and stretcher strains during press forming of aged low carbon steel sheets, roller leveling conditions for reducing yield point elongation were studied. Yield point elongations of leveled sheets were determined as a function of leveling, which is defined as the plastic fraction or the ratio of plastically deformed part in sheet thickness section to the whole thickness of the sheet. By adjusting this plastic fraction during leveling to more than 78%, yield point elongation in the leveled sheets was reduced so no fluting occurred during subsequent tangential bending. Stretcher strains can be avoided by leveling the sheet to an 84% plastic fraction condition.

MCMB Synthesis using Coal Tar Pitch

  • Seo, Hyeon-Kwan;Suh, Jeong-Kwon;Hong, Ji-Sook;Suh, Dong-Hack;Lee, Jung-Min
    • Carbon letters
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    • v.4 no.2
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    • pp.79-85
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    • 2003
  • MCMB (mesocarbon microbeads) has been synthesized from coal tar pitch, petroleum pitch and polymer compound generally. But yield of MCMB was low about 20~40 wt% and was not above 50 wt%. Neither MCMB was replaced with natural graphite because of economic performance, refining MCMB, and control of the particle size distribution. This study was performed to elevate yield of MCMB and to develop technique of particle size distribution. As the result, yield of MCMB that was synthesized from coal tar pitch increased more than 60 wt% about raw material and particle size of MCMB was restrained according to control of QI (quinoline insoluble) ingredient in raw pitch, heat treatment temperature and time.

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A Study of Mechanical Properties of Carbon Nanotubes through TBMD Simulation (TBMD SIMULATION을 이용한 탄소 나노튜브의 역학적 특성 연구)

  • 박문필;이강환;황호정
    • Proceedings of the IEEK Conference
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    • 2001.06b
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    • pp.169-172
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    • 2001
  • We have investigated the mechanical deformation of carbon nanotube using TBMD(tight-binding molecular dynamics) simulation. We have studied four carbon nanotubes, armchair (6, 6), (7, 7), (8, 8), and (9, 9) carbon nanotubes whose length were same. As a result of study, we have known that the nanotube's yield force increases with incresing their diameter. It is similar between (6, 6) and (8, 8) CNT's force-strain curves. Also force-strain curve between (7,7) and (9, 9) CNTs are nearly same.

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