• Journal of Korean Society for Atmospheric Environment
• /
• v.1 no.1
• /
• pp.43-51
• /
• 1985

This study is concerned with the oxidation of carbon monoxide on platinum and platinum-palladium catalysts. Catalysts were made by the impregnation method and flow reactor was used in the catalytic reaction. As for the mixed gases, carbon monoxide concentration varied from 1 to 4% and that of oxygen from 1 to 4%. $N_2$ was used as carrier gas and GHSV varied from 24, 000 $h^{-1} to 60, h^{-1}$. The temperature range was from 200 to $600^\circ$C. It was also taken into consideration that the heat and mass transfer resistance of our catalysts was negligible in the study. Experimental results showed that platinum-palladium catalyst was about 1.5-3.9% superior to platinum catalyst in conversion yield. When we used platinum-palladium catalyst, we observed that carbon monoxide oxidation was found to be 1 st order with respect to carbon monoxide concentration. Activation energy of the catalyst was 23.5 kcal/mol.

• Textile Coloration and Finishing
• /
• v.15 no.2
• /
• pp.76-85
• /
• 2003

In this study, a continuous stabilization process is used to make high-performance carbon fiber from polyacrylonitrile(PAM)-based fibers. The effect of oxygen content of PAN-based fiber on the stabilization process and the properties of the resultant carbon fibers is investigated. In order to research the progress of stabilization reaction FT-IR, elemental analysis, density, DSC, etc are used. Stabilization is carried out in air atmosphere from the 200 to $300^\circ{C}$ temperature range. An increase of PAN-based fibers diameter reduces the oxygen content during the continuous stabilization process. A higher oxygen content increase the density, tensile strength and modulus in the resultant carbon fibers. The most appropriate oxygen content in the stabilized fiber should be about 12%. Fibers having more than 2% oxygen content yield carbon fibers with inferior properties. Those carbon fibers also have sufficient commercial availability.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.02a
• /
• pp.201-201
• /
• 2012

Using materials with high thermal conductivity is a matter of great concern in the field of thermal management. In this study, we present our experimental results on an important physical property of carbon nanotube (CNT) films, two-dimensional thermal conductivity obtained by using an optical method based on Raman spectroscopy. We prepared four kinds of CNT films to investigate the effect of CNT type on heat spreading performance of films. This first comparative study using the optical method shows that the arc-discharge single-walled carbon nanotubes yield the best heat spreading film. And we observed thermal conductivity values of CNT films with various transmittances and found that the Raman method works as long as the sample is a transparent film. This study provides useful information on characterization of thermal conduction in transparent CNT films and could be an important step toward high-performance carbon-based heat spreading films.

• Journal of the Korean Society of Industry Convergence
• /
• v.26 no.6_3
• /
• pp.1333-1339
• /
• 2023

To produce activated carbon fibers, the process is carried out through either physical activation method or chemical activation method. In this study, we present the results regarding the characteristics of activated carbon fibers manufactured under various conditions through the quantitative control of steam. The yield after activation indicates a decreasing trend with the increase in steam quantity and activation time. Additionally, specific surface area characteristics exhibit variations based on activation time and steam flow rate. The SEM analysis results reveal that higher steam flow rates lead to the presence of both mesopores and macropores on the surface of activated carbon fibers (ACF).

• Carbon letters
• /
• v.16 no.1
• /
• pp.1-10
• /
• 2015

In recent years, flame synthesis has absorbed a great deal of attention as a combustion method for the production of metal oxide nanoparticles, carbon nanotubes, and other related carbon nanostructures, over the existing conventional methods. Flame synthesis is an energy-efficient, scalable, cost-effective, rapid and continuous process, where flame provides the necessary chemical species for the nucleation of carbon structures (feed stock or precursor) and the energy for the production of carbon nanostructures. The production yield can be optimized by altering various parameters such as fuel profile, equivalence ratio, catalyst chemistry and structure, burner configuration and residence time. In the present report, diffusion and premixed flame synthesis methods are reviewed to develop a better understanding of factors affecting the morphology, positioning, purity, uniformity and scalability for the development of carbon nanotubes along with their correlated carbonaceous derivative nanostructures.

• Journal of the Korean Society for Heat Treatment
• /
• v.21 no.2
• /
• pp.79-86
• /
• 2008

As a basic research for developing 600 MPa yield strength reinforcing steel bars, the strengthening of 0.25 wt.% carbon steel by vanadium addition was studied. The changes of microstructure and mechanical properties were investigated for the specimen V0 (0.00 wt.% V), V1 (0.03 wt.% V) and V2 (0.06 wt.% V) processed by various heat treatments. To set the heat treatment conditions, the continuous cooling transformation (CCT) curves were drawn for austenitizing temperatures of $900^{\circ}C$ and $1100^{\circ}C$. For specimens tempered at $600^{\circ}C$ after quenching from $900^{\circ}C$ and $1100^{\circ}C$, yield strength was increased by 19 MPa and 21 MPa for 0.01 wt % V addition, and tensile strength was increased by 25 MPa and 28 MPa for 0.01 wt % V addition, respectively. Also, for 0.06 wt.% V added specimens tempered after quenching and normalized, tensile strength was increased by 50 MPa and 30 MPa for increasing austenitizing temperature of $100^{\circ}C$, respectively.

• Applied Chemistry for Engineering
• /
• v.4 no.3
• /
• pp.522-529
• /
• 1993

To raise the utilization of precious platinum currently used as catalyst for PAFC's electrode, it is very important to make fine particles of platinum. This study, for preparing highly dispersed platinum catalyst on carbon black, method. And then loading yield of platinum catalyst on carbon black and the particle size were investigated by DCP and XRD and/or TEM respectively. The colloid method by which platinum particle size could be reduced as small as below $30{\AA}$ showed the best result among them, and the loading yield of platinum catalyst on carbon black was above 99%.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2005.07b
• /
• pp.1443-1446
• /
• 2005

We have synthesized thin multi-walled carbon nanotubes (t-MWCNTs) using a catalytic chemical vapor deposition (CCVD) method with FeMoMgO catalyst. The number of tube walls were 2 ${\sim}$ 6 with the corresponding diameters of 3 ${\sim}$ 6 nm. We obtained high production yield of over 3000 wt% compared to the weight of the supplied catalyst. These t-MWCNTs revealed the intermediate structural characteristics between single- and multi-walled carbon nanotubes (SWCNTs and MWCNTs). We have also characterized the field emission properties such as turn-on field and emission current, and current degradation from these t-MWCNTs together with SWCNTs and MWCNTs.

• Journal of Plant Biotechnology
• /
• v.37 no.2
• /
• pp.205-211
• /
• 2010

Yield productivity of staple crops must be increased at least 50% by 2050, in order to feed the world population which is expected to reach 90 billions. Photosynthetic carbon assimilation and carbohydrate metabolism leading to the production of starch would be the final frontier to quest for new sources of technology enabling such a drastic increase of crop productivity. In this review, attempts to genetically engineer plant photosynthetic carbon reduction cycle and metabolic pathways to increase starch production are introduced.

• KSBB Journal
• /
• v.15 no.6
• /
• pp.566-572
• /
• 2000

Experimental studies were carried out to develop an osmotolerant mutant of Candida magnoliae JH and to determine the optimum concentrations of carbon and nitrogen sources to improve erythritol yield and productivity. Mutants of C. magnoliae JH were prepared by treatment with ethylmethane sulfonate, and osmotolerant mutants were isolated from the agar plate colonies containing 2.5 M KCI. Among the mutants isolated, one mutant M26 was finally selected based on erythritol yield and productivity. In shake flask culture, glucose proved to be the best carbon source and the optimum yeast extract concentration was 5 g/L based on 100 g/L glucose. The erythritol yield and productivity of mutant M26 were greater than wild type in 100 g/L glucose medium. in the fermentation experiments, erythritol production increased with increased glucose concentration, up to a limit of 250 g/L. The maximum concentration of erythritol achieved 127.5 g/L, and the yield and productivity of erythritol production were 51.0% and 0.63 g/L-h, respectively.