• Journal of Korean Society on Water Environment
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• v.23 no.1
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• pp.46-51
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• 2007

This research work aims at treating saline wastewater generated from a fish market using four Sequencing Batch Reactors (SBR) operated under different conditions. The effect of C/N ratio (3, 6) and salt concentration (0.5~2%) on organic and nitrogen removal was studied. The synthetic wastewater prepared with glucose ($C_6H_{12}O_6$) as the primary carbon source along with ammonium chloride ($NH_4Cl$) was used in the three reactors. The fill, anoxic, aeration, settle and draw conditions were 2 hr, 4 hr, 4 hr and 2 hr respectively. The fourth reactor was operated at different conditions to investigate the practical feasibility of SBR application to handle fish market wastewater generated in Ulsan city that had fluctuating loading characteristics. Though the unacclimated sludge was initially affected by the salt concentration, the acclimated sludge removed 95% of the organics irrespective of the NaCl concentration and C/N ratio. However, the removal of nitrogen was affected more by C/N ratio than the salt concentration. While handling fish market wastewater, though the organic and nitrogen loading rate were varying between $0.009{\sim}0.259gCOD_{OH}/gVSS/day$ and 0.005~0.034 gN/gVSS/day, the effluent concentrations were far less than the effluent standard of $120mgCOD_{OH}/L$ and 60 mgN/L respectively, except when loading rates were fluctuating and 4 times higher than the average.

• Journal of Korean Society of Water and Wastewater
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• v.32 no.1
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• pp.19-25
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• 2018

The objectives of this study were to evaluate the removal characteristics of total nitrogen, the influence factor of denitrification and the optimum operating condition in the pigment wastewater treatment using PAC-A/O process. The operating conditions of PAC-A/O process were mean BOD volumetric loading $0.86kgBOD/m^3/day$, mean F/M ratio 0.072~0.13 kgBOD/kgMLVSS/day and mean C/N ratio 3.47, respectively. The conditions of anoxic process in the field plant test were mean pH 8.3~8.7 and mean temperature $34.1{\sim}44.0^{\circ}C$. The ORP bending point knee was eventually appeared in the ORP -107 mV and $NO_3{^-}-N$ removal efficiency was increased according to the ORP decrease. In the ORP -107 mV below condition, the removal efficiency of T-N and $NO_3{^-}-N$ was 92.3~95.0% and 98.5~99.7%. Denitrification rate was calculated to be 1.581~1.791 mg $NO_3{^-}-N/gMLSS/hr$. The experimental results showed that the ORP control in the PAC-A/O process could be an effective method for treatment of pigment wastewater.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.7
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• pp.299-309
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• 2019

This study was designed to assess the quality and quantity of food resources such as the chlorophyll a concentration (Chl-a), the particulate organic carbon (POC) and the particulate organic nitrogen (PON), on blood cocke (Tegillarca granosa Linnaeus) farms from May to November 2017 in the northwestern area of Yeoja Bay, Korea. The values of Chl-a, POC and PON were $1.69-7.68{\mu}g{\cdot}L^{-1}$ (average: $3.48{\mu}g{\cdot}L^{-1}$ in the surface), 0.88-2.58 mM (average: 1.97 mM) and 0.17-0.90 mM (average: 0.54 mM), respectively, and these values were higher in the spring and summer and lower in the autumn. Furthermore, Chl-a and POC had higher values on the bottom layer than those vales on the surface, while PON had higher values on the surface than those values on the bottom. The POC/PON ratio and POC/Chl-a ratio were 1.56-7.88 (average: 3.71 on the surface of the water) and 216-967 (average: 700 on the bottom of the water), respectively, with most of the carbon sources being sediment-accumulated particle organic matter, and the contribution by phytoplankton was assessed as being low. These results show that the food source of the blood cockle farms in the northwest area of Yeoja Bay seems to be abundant in quantity, but this is considered to be very poor in quality.

• Korean Journal of Ecology and Environment
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• v.41 no.spc
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• pp.27-34
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• 2008

The vertical distribution and origin of particulate organic matter (POM) were investigated in Shingu reservoir on 4th July (pre-monsoon) and 7th August (post-monsoon) 2006. High turbid water (120 NTU) were found at 4.5 m water depth in postmonsoon period. The average C/N ratio of POM was about 5.70 and 6.96 in surface water and bottom water, respectively in pre-monsoon period, exhibiting the close values to its ratio in phytoplankton cell. However, the average C/N ratio was 7.10 in surface water and 12.81 in bottom water in post-monsoon period. In addition, the ${\delta}^{13}C$ values of POM in pre-monsoon period ranged from -25.1%o to -26.1%o in whole water column, but the ${\delta}^{13}C$ values of POM in post-monsoon period showed relatively wide range between -23.2%o and -27.5%o. The apparently lighter values (average -27.5%o) in near bottom water (4.5 m water depth) demonstrate that POM in high turbid water in post-monsoon period may be derived from the outside terrestrial plants through heavy rainfall during the summer monsoon period. The present study suggests that carbon and nitrogen stable isotope ratios as well as C/N ratios should be useful indexes to clarify the origin of POM.

• Transactions on Electrical and Electronic Materials
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• v.14 no.5
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• pp.246-249
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• 2013

Graphene was obtained on Cu foil by thermal decomposition method. A gas mixture of $H_2$ and $CH_4$ and an ambient annealing temperature of $1,000^{\circ}C$ were used during the deposition for 30 Min., and for the transfer onto $SiO_2/Si$ and Si substrates. The physical properties of graphene were investigated with regard to the effect ofnitrogen atom doping and the various substrates used. The G/2D ratio decreased when the graphene became monolayer graphene. The graphene grown on $SiO_2/Si$ substrate showed a low intensity of the G/2D ratio, because the polarity of the $SiO_2$ layer improved the quality of graphene. The intensity of the G/2D ratio of graphene doped with nitrogen atoms increased with the doping time. The quality of graphene depended on the concentration of the nitrogen doping and chemical properties of substrates. High-quality monolayer graphene was obtained with a low G/2D ratio. The increase in the intensity of the G/2D ratios corresponded to a blue shift in the 2D peaks.

• Transactions of the Korean Society of Automotive Engineers
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• v.18 no.1
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• pp.37-43
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• 2010

The purpose of this paper is to investigate the effect of air-fuel ratio on the combustion and emissions characteristics of spark ignition (SI) gasoline engine fueled with bio-ethanol. A 1.6L SI engine with 4 cylinders was tested on EC dynamometer. In addition, lambda sensor and lambda meter were connected with universal ECU to control the lambda value which is varied from 0.7 to 1.3. The engine performance and combustion characteristics of bio-ethanol fuel were compared to those obtained by pure gasoline. Furthermore, the exhaust emissions such as carbon monoxide (CO), unburned hydrocarbon (HC), oxides of nitrogen ($NO_X$) and carbon dioxide ($CO_2$) were measured by emission analyzers. The results showed that the brake torque and cylinder pressure of bio-ethanol fuel were slightly higher than those of gasoline fuel. Brake specific fuel consumption (BSFC) of bio-ethanol was increased while brake specific energy consumption (BSEC) was decreased. The exhaust emissions of bio-ethanol fuel were lower than those of gasoline fuel under overall experimental conditions. However, the specific emission characteristics of the engine with bio-ethanol fuel were influenced by air-fuel ratio.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.8 no.2
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• pp.77-88
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• 1988

This research investigated the effect of COD/N ratio on nitrogen removal, and the use of organics in raw wastewater as a carbon source for denitrification in SBR(Sequencing Batch Reactor) systems. Four laboratory scale reactors were operated in three modes. Only the difference between modes were; Mode I operated in aerated condition during fill while Mode II in anoxic condition and Mode III operated on two fills per cycle in anoxic condition. When COD/N ratio increased, total nitrogen removal efficiencies increased from 8.7 to 57.7 percent in Mode I, from 28.9 to 83.2 percent in Mode II and from 42.7 to 97.8 percent in Mode III, respectively. COD removal efficiencies ranged from 93 to 98 percent throughout the study. SBR operation in Mode III of feeding twice per cycle in anoxic condition was an effective operating method for nitrogen removal and nitrogen concentration in effluent can be estimated using influent COD and nitrogen concentrations.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.29 no.6
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• pp.787-796
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• 1996

The biodegradation experiment, the TOD analysis and the element analysis for dispersant, Bunker-A oil and Bunker-B oil were conducted to study the biodegradation characteristics of a mixture of Bunker-A oil with dispersant and a mixture of Bunker-B oil with dispersant in the seawater. The results of biodegradation experiment showed 1mg of dispersant to be equivalent to 0.26 mg of $BOD_5$ and to 0.60 mg of $BOD_{20}$ in the natural seawater. The results of TOD analysis showed each 1 mg of dispersant, Bunker-A oil and Bunker-B oil to be equivalent to 2.37 mg, 2.94 mg and 2.74 mg of TOD, respectively. The results of element analysis showed carbon, hydrogen, nitrogen and phosphorus contents of dispersant to be $82.1\%,\;13.8\%,\;1.8\%\;and\;2.2\%$, respectively. Carbon and hydrogen contents of Bunker-A oil were found to be $73.3\%\;and\;13.5\%$, respectively, and carbon, hydrogen and nitrogen contents of Bunker-B oil to be $80.4\%,\;12.3\%\;and\;0.7\%$, respectively. Accordingly, the detection of nitrogen and phosphorus in dispersant shows that dispersants should be used with caution in coastal waters, with relation to eutrophication. The biodegradability of dispersant expressed as the ratio of $BOD_5/TOD$ was found to be $11.0\%$. As the mix ratios of dispersant to Bunker-A oil (3 mg/l) and a mixture of Bunker-B oil (3mg/l) were changed from 1 : 10 to 5 : 10, the biodegradabilities of a mixture of Bunker-A oil with dispersant and Bunker-B oil with dispersant increased from $2.1\%\;to\;7.2\%$ and from $1.0\%\;to\;4.4\%$, respectively. Accordingly, the dispersant belongs to the organic matter group of middle-biodegradability while mixtures in the mix ratio range of $1:10\~5:10$ belong to the organic matter group of low-biodegradability. The deoxygenation rate constant $(K_1)$ and ultimate biochemical oxygen demand $(L_0)$ obtained from the biodegradation experiment and Thomas slope method were found to be 0.125/day and 2.487 mg/l for dispersant (4 mg/l), respectively. $K_1\;and\;L_0$, were found to be $0.079\~0.131/day$ and $0.318\~2.052\;mg/l$ for a mixture of Bunker-A oil with dispersant and to be $0.106\~0.371/day$ and $0.262\~1.106\;mg/l$ for a mixture of Bunker-B oil with dispersant, respectively, having $1:10\~5:10$ mix ratios of dispersant to Bunker-A oil and Bunker-B oil. The ultimate biochemical oxygen demands of the mixtures increased as the mix ratio of dispersant to Bunker-A, B oils changed from 1 : 10 to 5 : 10. This suggests that the more dispersants are applied to the sea for the cleanup of Bunker-A oil or Bunker-B oil, the more decreases the dissolved oxygen level in the seawater.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.4
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• pp.451-457
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• 2011

Purple non-sulfur (PNS) bacterium $Rhodobacter$ $sphaeroides$ KD131 was studied with the aim of achieving maximum hydrogen production using various carbon and nitrogen sources at different pH conditions. Cells grew well and produced hydrogen using $(NH_4){_2}SO_4$ or glutamate as a nitrogen source in combination with a carbon substrate, succinate or malate. During 48h of photo-heterotrophic fermentation under 110$W/m^2$ illumination using a halogen lamp at $30^{\circ}C$, 67% of 30mM succinate added was degraded and the hydrogen yield was estimated as 3.29mol $H^2$/mol-succinate. However, less than 30% of formate was consumed and hydrogen was not produced due to a lack of genes coding for the formate-hydrogen lyase complex of strain KD131. Initial cell concentrations of more than 0.6g dry cell weight/L-culture broth were not favorable for hydrogen evolution by cell aggregation, thus leading to substrate and light unavailability. In a modified Sistrom's medium containing 30mM succinate with a carbon to nitrogen ratio of 12.85 (w/w), glutamate produced 1.40-fold more hydrogen compared to ammonium sulfate during the first 48h. However, ammonium sulfate was 1.78-fold more effective for extended cultivation of 96h. An initial pH range from 6.0 to 9.0 influenced cell growth and hydrogen production, and maintenance of pH 7.5 during photofermentation led to the increased hydrogen yield.

• Journal of the Korean Ceramic Society
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• v.24 no.2
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• pp.147-154
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• 1987

Silicon nitride powders were prepared by the simultaneous reduction and nitridation from powder mixtures of Kim cheon quartzite and carbon (graphite or carbon black) at1400$^{\circ}C$ for 10 hours in nitrogen atmosphere. The effects of the reaction variables on the yield of products and on the ${\alpha}$/${\beta}$ ratio were examined. The average particle size, density, and the ${\alpha}$/${\beta}$ ratio of the obtained si3N4 were 1.0$\mu\textrm{m}$, 3.10g/㎤ and 90/10, respectively. It was found that the Si3N4 powders obtained in this work were comparable to the foreign commercial products.