• Title/Summary/Keyword: Carbon soot

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Application of Taguchi Methodology for Optimization of Parameters of CVD Influencing Formation of a Desired Optical Band Gap of Carbon Film

  • Mishra, D.K.;Bejoy, N.;Sharon, Maheshwar.
    • Carbon letters
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    • v.6 no.2
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    • pp.96-100
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    • 2005
  • Taguchi methodology has been applied to get an idea about the parameters related to the chemical vapour deposition technique, which influences the formation of semiconducting carbon thin film of a desired band gap. L9 orthogonal array was used for this purpose. The analysis based on Taguchi methodology suggests that amongst the parameters selected, the temperature of pyrolysis significantly controls the magnitude of band gap (46%). Sintering time has a small influence (30%) on the band gap formation and other factors have almost no influence on the band gap formation. Moreover this analysis suggests that lower temperature of pyrolysis (${\leq}$ $750^{\circ}C$) and lower time of sintering (${\leq}$ 1 h) should be preferred to get carbon thin film with the desired band gap of 1.2eV.

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Development of Test Method for Flat Panel Display Life Time Prediction during Atmospheric Particle Exposure (평판디스플레이의 대기중 분진농도에 따른 수명예측 시험방법 개발)

  • Yoo, Dong-Hyun;Lee, Gun-Ho;Choi, Jung-Uk;Ahn, Kang-Ho
    • Journal of the Semiconductor & Display Technology
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    • v.12 no.4
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    • pp.45-48
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    • 2013
  • The electronic device, such as flat panel display (FPD), is very important in our life as a means of communication between humans. Liquid crystal display (LCD), which is categorized as a flat panel display, has been used in many display products, especially in TV industry. An LED TV is composed of several electrical components, such as liquid critical module (LCM), analog to digital convertor (AD), power supplier, and inverter board. These modules are very vulnerable to particulate contamination, and causing malfunction or visibility degradation. In this study, we developed a test method for prediction of LCM's lifetime. The test system consists of carbon particle generation flame, dilution system, test chamber, and particle concentration monitoring instrument. Since the carbon particles are the most abundant in the atmosphere and easily absorb light, soot particles are used as a challenging material for this test. The concentration of generated soot particles is set around 4,000,000 #/cc, which is 400 times higher than that of usual atmospheric particles. Through this experiment, we deduced the relationship between the dust concentration and life time of the test specimen.

A Fire Computer Simulation of Inner Space with Fire Shutters and Refuge Stairs (방화셔터와 피난계단이 존재하는 실내 환경의 화재 컴퓨터 시뮬레이션)

  • Yoo, Doo-Yul;Yang, Jung-Min
    • The Journal of the Korea institute of electronic communication sciences
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    • v.8 no.11
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    • pp.1617-1624
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    • 2013
  • This paper analyzes the relation between fire shutters and fire spread by conducting fire simulation on inner space with fire shutters. Using Fire Dynamics Simulator (FDS), a commercial fire simulation software, the simulation is done on an ideal inner robby, where fire size and the open/close of fire shutters are varied. Our simulation environment can derive significant fire parameters such as temperature variation of fire room walls and entrances of refuge stairs, variation of carbon dioxide, and soot spread. According to the simulation results, temperature and carbon dioxide distribution in refuge stairs have little dependence on vent open or close, but the part close of fire shutters blocks soot inflow to refuge stairs.

Bias-enhanced Nucleation of Diamond in Hot Filament CVD (열필라멘트 CVD에서 전압 인가에 의한 다이아몬드의 핵생성 촉진)

  • Choi, Kyoon;Kang, Suk-Joong L.;Hwang, Nong-M.
    • Journal of the Korean Ceramic Society
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    • v.34 no.6
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    • pp.636-644
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    • 1997
  • The effect of various processing parameters, in particular the substrate and filament temperature, on the nucleation of diamond has been studied for the hot filament CVD process with a negative bias on the substrate. As far as the substrate temperature was maintained around the critical temperature of 73$0^{\circ}C$, the nucleation of diamond increased with increasing filament temperature. The maximum nucleation density of ~ 2$\times$109/$\textrm{cm}^2$ was obtained under the condition of filament temperature of 230$0^{\circ}C$, substrate temperature of 75$0^{\circ}C$, bias voltage of 300V, methane concentration of 20%, and deposition time of 2 hours. This nucleation density is about the same as those obtained in previous investigations. For fixed substrate temperatures, the nucleation density varies up to about 103 times depending on experimental conditions. This result is different from that of Reinke, et al. When the substrate temperature was above 80$0^{\circ}C$, a silkworm~shaped carbon phase was co-deposited with hemispherical microcrystalline diamond, and its amount increased with increasing substrate temperature. The Raman spectrum of the silkworm-shaped carbon was the same as that of graphitic soot. The silkworm-shaped carbon was etched and disappeared under the same as that of graphitic soot. The silkworm-shaped carbon was etched and disappeared under the deposition condition of diamond, implying that it did not affect the nucleation of diamond.

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Modeling of Solid Particle-Slag Interactions in Entrained Gasification Reactor (분류층 가스화기에서의 고체 입자-슬래그 간 상호 작용에 대한 모델링)

  • Chi, Jun-Hwa;Kim, Ki-Tae;Kim, Sung-Chul;Chung, Jae-Hwa;Ju, Ji-Sun;Kim, Ui-Sik
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.5
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    • pp.686-698
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    • 2011
  • Mathematical models for char-slag interaction and near-wall particle segregation developed by Montagnaro et. al. were applied to predict various aspects of coal gasification in an up-flow entrained gasifier of commercial scale. For this purpose, some computer simulations were performed using gPROMS as the numerical solver. Typical design parameters and operating conditions of the commercial gasifiers were used as input values for the simulation. Development of a densely dispersed phase of solid carbon was found to have a critical effect on both carbon conversion and ash flow behavior. In general, such a slow-moving phase was turned out to enhance carbon conversion by lengthening the residence time of char or soot particles. Furthermore, it was also found that guiding the transfer of char or soot into the closer part of the wall to coal burner is favorable in terms of gasification efficiency and vitrified ash collection. Finally, to a certain degree densely dispersed phase of carbon showed an yield-enhancing effect of syngas.

The Effect of Substrate surface Carbon on Synthesis of Diamond Film by Combustion Flame Method (연소 화염법에 의한 다이아몬드 합성에 미치는 기판표면탄소의 효과)

  • Kim, Seong-Yeong;Lee, Jae-Seong
    • Korean Journal of Materials Research
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    • v.6 no.2
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    • pp.153-157
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    • 1996
  • 연소화염법을 이용한 다이아몬드 박막합성은 기판의 표면상태에 크게 의존한다. 특히 탄소결합상이 기판에 조재하는 경우 다이아몬드 핵생성과 성장은 크게 영향을 받는다. 본 연구에서는 일정한 흡입가스비율(R=O2/C2H2)과 기판온도 조건의 연소화염법을 이용하여 몰리브덴 기판위에 다리아몬드박막을 합성하는 과정에서 박막의 핵생성에 미치는 기판 탄소화합물의 영향을 조사하였다. Mb 금속기판표면에 형성된 탄화물로는 Mo2C상과 soot를 택하여 박막합성 전에 Mo기판상에 형성시켰다. Mo 금속기판표면에 형성된 탄화물(Mo2C)상에는 다이아몬드 핵생성과 입자성장이 촉진되어 가장 조대한 양질의 다이아몬드 입자가 형성되었다. 이것은 탄화물상이 반응가스중의 탄소의 확산을 저지함과 동시에 핵생성의 필요한 잠복기간을 감소키켰기 때문이다. 그러나 soot를 구성하는 미세한 탄소결합상들이 다이아몬드 핵생성 장소로 작용하여 결과적으로 다이아몬드 수밀도가 가장 크게 관찰된 반면, 입자성장은 Mo2C기판에 비해 작았다.

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A Study on Combustion Characteristics of Gasoline and Diesel Fuels in a Compression Ignition Engine (압축착화 엔진에서 가솔린과 디젤연료의 연소 특성에 관한 연구)

  • Kim, Kihyun
    • Journal of Power System Engineering
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    • v.21 no.1
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    • pp.63-69
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    • 2017
  • The combustion characteristics of gasoline and diesel were tested in a compression ignition engine. Both fuels were used with same common rail injection system. Combustion experiment showed that low load condition of 0.45 MPa IMEP (indicated mean effective pressure) was tested in metal and optical engines. The gasoline combustion showed higher hydrocarbon and carbon monoxide emissions but lower soot emission compared with diesel combustion. NOx emissions were very high at late injection timing but significantly decreased at early injection timing due to the lean combustion resulted from vigorous mixing process. Direct combustion visualization showed that the diesel combustion was dominated by diffusion combustion exhibiting soot incandescence and the gasoline combustion was mostly consisted of premixed combustion showing blue chemiluminescence.

Simultaneous Application of Platinum-Supported Alumina Catalyst and Ozone Oxidant for Low-temperature Oxidation of Soot (백금담지 알루미나 촉매와 오존 산화제 동시 적용에 의한 탄소 입자상 물질의 저온 산화반응)

  • Lee, Jin Soo;Lee, Dae-Won
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.752-760
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    • 2018
  • The lowering of temperature for combustion of diesel particulate matters (or diesel soot) is one of the important tasks in automotive industry that is searching for a way to meet up "high-fuel efficiency, low-emission" standard. In this study, it was discussed how the use of ozone over platinum-based catalyst promotes a low-temperature soot oxidation occurred at $150^{\circ}C$. The use of platinum catalyst did not increase oxidation rate largely but was very effective in improving the selectivity of carbon dioxide. The pre-oxidation of NO into $NO_2$ using ozone was rather crucial in improving the oxidation rate of soot at $150^{\circ}C$.

INVESTIGATION OF SOOT OXIDATION CHARACTERISTICS IN A SIMULATED DIESEL PARTICULATE FILTER

  • Lee, H.S.;Chun, K.M.
    • International Journal of Automotive Technology
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    • v.7 no.3
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    • pp.261-267
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    • 2006
  • Understanding the mechanism of carbon oxidation is important for the successful modeling of diesel particulate filter regeneration. Carbon oxidation characteristics were investigated by temperature programmed oxidation(TPO) method as well as constant temperature oxidation(CTO) with a flow reactor including porous bed. The activation energy of carbon oxidation was increasing with temperature and had two different constant values in the early and the later stage of the oxidation process respectively in TPO experiment. Kinetic constants were derived and the reaction mechanisms were assumed from the experimental results and a simple reaction scheme was proposed, which approximately predicted the overall oxidation process in TPO as well as CTO.